scholarly journals Low viscosity and high toughness epoxy resin modified by in situ radical polymerization method for improving mechanical properties of carbon fiber reinforced plastics

Polymer ◽  
2018 ◽  
Vol 156 ◽  
pp. 1-9 ◽  
Author(s):  
Jun Misumi ◽  
Toshiyuki Oyama
Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1866
Author(s):  
Chun Pei ◽  
Peiheng Guo ◽  
Ji-Hua Zhu

Preserving the integrity of carbon fibers when recycling carbon-fiber-reinforced plastics (CFRPs) has been unfeasible due to the harsh reaction conditions required to remove epoxy resin matrixes, which adversely affect the properties of carbon fibers. We establish a practicable and environmentally friendly reclamation strategy for carbon fibers. Carbon fibers are recycled from waste CFRPs by an electrochemical catalytic reaction with the assistance of phosphotungstic acid (PA), which promotes the depolymerization of diglycidyl ether of bisphenol A/ethylenediamine (DGEBA/EDA) epoxy resin. The removal rate, mechanical strength, and microstructure of the recycled carbon fibers are analyzed to explore the mechanism of the electrochemical treatment. The influence of three factors—current density, PA concentration, and reaction time—are studied via an orthogonal method. Range analysis and variance analysis are conducted to investigate the significance of the factors. The optimal conditions are determined accordingly. The underlying CFRP degradation mechanism is also investigated.


2011 ◽  
Vol 462-463 ◽  
pp. 207-212 ◽  
Author(s):  
Hideaki Katogi ◽  
Kenichi Takemura ◽  
Yoshinobu Shimamura

Water absorption behavior and flexural strength properties of carbon fiber reinforced plastics (CFRP) under hot-wet environment were examined. Those of epoxy resin were also examined for reference. Weight gains of CFRP and epoxy resin were measured after immersion in distilled water at temperatures under 90°C. Quasi-static flexural tests of CFRP and epoxy resin were conducted after immersion for 180 days. Weight gains of CFRP and epoxy resin increased with increasing water temperature. After immersion for 180 days at 90°C, weight gain of CFRP became 3.3times higher and that of epoxy resin was 2.3 times higher than that at RT, respectively. When CFRP and epoxy resin were immersed in distilled water at 90°C, weight gains of CFRP and epoxy resin increased and then decreased. Flexural strengths of CFRP and epoxy resin decreased in distilled water at temperatures less than 90°C. Flexural strengths of dried CFRP and epoxy resin after immersion recovered but were lower than that of virgin CFRP and epoxy resin. Debonding of fiber/resin interface and crack initiation in epoxy resin in distilled water resulted in the strength reduction.


2019 ◽  
Vol 3 (3) ◽  
pp. 85 ◽  
Author(s):  
El-Ghaoui ◽  
Chatelain ◽  
Ouellet-Plamondon ◽  
Mathieu

Carbon fiber reinforced plastics (CFRP) are appreciated for their high mechanical properties and lightness. Due to their heterogeneous nature, CFRP machining remains delicate. Damages are caused on the material and early tool wear occurs. The present study aims to evaluate the effects of fillers on CFRP machinability and mechanical behavior. CFRP laminates were fabricated by the vacuum assisted resin transfer molding (VARTM) process, using a modified epoxy resin. Three fillers (organoclay, hydrocarbon wax, and wetting agent) were mixed with the resin prior to the laminate infusion. Milling tests were performed with polycrystalline diamond (PCD) tools, equipped with thermocouples on their teeth. Machinability was then studied through the cutting temperatures and forces. Tensile, flexural, and short-beam tests were carried out on all samples to investigate the effects of fillers on mechanical properties. Fillers, especially wax, allowed us to observe an improvement in machinability. The best improvement was observed with 1% wax and 2% organoclay, which allowed a significant decrease in the cutting forces and the temperatures, and no deteriorations were seen on mechanical properties. These results demonstrate that upgrades to CFRP machining through the addition of nanoclays and wax is a path to explore.


2013 ◽  
Vol 577-578 ◽  
pp. 73-76 ◽  
Author(s):  
Hideaki Katogi ◽  
Kenichi Takemura

In this study, effect of Carbon Milled Fiber (CMF) addition on interlaminar fracture toughness of carbon fiber reinforced plastics (CFRP) was investigated. Plain woven carbon fiber was used as reinforcement. Epoxy resin was used as matrix. The addition amounts of CMF are 0.5wt%, 0.8wt%, 1.0wt% and 1.2wt% for the epoxy resin. Mode I and mode II interlaminar fracture toughness tests were conducted based on JIS K 7086. As a result, mode I and mode II interlaminar fracture toughness increased with an increase of addictive amount of CMF. But excess addition was not effective. Pull out of CMF in matrix was found after mode I and mode II interlaminar fracture toughness tests. The mode I and mode II interlaminar fracture toughness of CMF added CFRP can be improved by fiber bridging of CMF.


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