Electro-optic properties of a side chain poly(norbornene-dicarboximide) system with an appended phenyl vinylene thiophene chromophore

Polymer ◽  
2017 ◽  
Vol 119 ◽  
pp. 13-27 ◽  
Author(s):  
Andrew M. Spring ◽  
Feng Qiu ◽  
Jianxun Hong ◽  
Alisa Bannaron ◽  
Shiyoshi Yokoyama
Keyword(s):  
Side Chain ◽  
Electro Optic

Side-chain maleimide based electro-optic polymer for second-order nonlinear optics

2006 ◽  
Vol 2 (6) ◽  
pp. 443-444 ◽  
Author(s):  
Jian-xun Hong ◽  
Jian-ping Chen ◽  
Xin-wan Li ◽  
Wei Chen ◽  
Tao Xie
Keyword(s):  
Nonlinear Optics ◽  
Second Order ◽  
Side Chain ◽  
Electro Optic

Polyquinolines: Multifunctional Polymers for Electro-Optic and Light-Emitting Applications

1999 ◽  
Vol 558 ◽  
Author(s):  
Alex K.-Y. Jen ◽  
Hong Ma
Keyword(s):  
Electrical Characterization ◽  
Bright Light ◽  
Side Chain ◽  
Light Emitting ◽  
Electro Optic ◽  
Film Forming ◽  
Hole Transporting ◽  
Broad Variation ◽  
Nlo Chromophores ◽  
Multifunctional Polymers

ABSTRACTA versatile, and generally applicable modular approach for making second-order nonlinear optical (NLO) side-chain aromatic polyquinolines has been developed. This approach emphasizes the ease of incorporating NLO chromophores onto the pendent phenyl moieties of parent polyquinolines at the final stage via mild Mitsunobu reaction. This method provides the synthesis of polyquinolines with a broad variation of the polymer backbones and great flexibility in the selection of NLO chromophores. These side-chain NLO polyquinolines demonstrate high electro-optic (E-O) activity (up to 35 pm/V at 830 nm and 22 pm/V at 1300 nm, respectively) and a good combination of thermal, optical, electrical and mechanical properties.Comparatively, two new electroluminescent (EL) polyquinolines have been prepared via the Friedlander condensation and nucleophilic reaction. The resulting polymers contain a bipolar property with both an efficient hole-transporting moiety, tetraphenyldiaminobiphenyl (TPD), and an electron affinitive light-emitting moiety, bis-quinoline. In addition, they possess high thermal stability, excellent electrochemical reversibility, good thin film-forming ability, and bright light-emitting property. Electrical characterization of two-layer diode devices based on the configurations of ITO/CuPc/TPD-PQ or TPD-PQE/Al showed excellent electroluminescence performance (a rectification ratio greater than 105 and a low turn-on voltage of less than 4 V).

New Host-Guest Polymeric System for Thermal Stability Enhancement of Electro Optic Effect

2002 ◽  
Vol 725 ◽  
Author(s):  
Seung Koo Park ◽  
Jung Yun Do ◽  
Jung-Jin Ju ◽  
Suntak Park ◽  
Myung-Hyun Lee
Keyword(s):  
Thermal Stability ◽  
Model Compound ◽  
Main Chain ◽  
Side Chain ◽  
Hydroxyl Groups ◽  
New Host ◽  
Polymer Main Chain ◽  
Electro Optic ◽  
Chromophore Concentration ◽  
Stability Enhancement

AbstractA new host-guest electro optic (EO) polymer, in which a chromophore can be reacted with the polymer main chain during poling to give the corresponding side-chain EO polymer, has been prepared for improving EO effect and its thermal stability. Polyisoimide (PII) synthesized from 2, 2-bis (4-aminophenyl) hexafluoropropane and oxydiphthalic anhydride and Disperse Red 1 (DR1) were used as a host and a guest, respectively. A model compound reaction and Infrared spectra of the host-guest film after annealing at various temperatures show that the reaction between the isoimide groups in PII and the hydroxyl groups in DR1 occurs around 140 °C. The glass transition temperatures of the resulting EO polyamic aicd ester-imide copolymer with 0, 10, 20 and 30 wt. % of chromophore concentration were 275, 219, 160, and 124 °C, respectively. The EO coefficient obtained at a wavelength of 1.55 νm was 5.3 and 10.5 pm/V from the EO polymer film with 20 and 30 wt. % DR1. The EO signals exhibited only a slight decay at high temperature due to the chemical reaction between the host and guest during poling.

Synthesis of nonlinear optical side-chain soluble polyimides for electro-optic applications

Polymer ◽  
2001 ◽  
Vol 42 (18) ◽  
pp. 7749-7754 ◽  
Author(s):  
W.N Leng ◽  
Y.M Zhou ◽  
Q.H Xu ◽  
J.Z Liu
Keyword(s):  
Nonlinear Optical ◽  
Side Chain ◽  
Electro Optic

Synthesis and Optical Nonlinearity of Thermally Stable Polyimides Incorporated with Electro-Optic Chromophore as Side Chain

2007 ◽  
Vol 249-250 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Hyun Kyung Ju ◽  
Jong Sun Lim ◽  
Sung Cheol Yoon ◽  
Changjin Lee ◽  
Dong Hoon Choi ◽  
...  
Keyword(s):  
Optical Nonlinearity ◽  
Side Chain ◽  
Thermally Stable ◽  
Electro Optic

ELECTRO-OPTIC POLYIMIDE WITH HYPER-BRANCHED CHROMOPHORE STRUCTURES

2004 ◽  
Vol 13 (03n04) ◽  
pp. 439-443
Author(s):  
JUNG YUN DO ◽  
SEUNG KOO PARK ◽  
SUNTAK PARK ◽  
JUNG JIN JU ◽  
MIN-SU KIM ◽  
...  
Keyword(s):  
Polymer Films ◽  
Side Chain ◽  
Poled Polymer ◽  
Electro Optic ◽  
Chromophore Concentration ◽  
Branched Structures

Hyper-branched chromophores were developed and attached to a polyimide backbone. The chromophore structures led to increasing chromophore concentration in polymers. Electro-optic coefficients were measured to investigate the effect of various chromophore concentrations in side chain polymers. Thermal and electric stabilities of poled polymer films were correlated with the hyper-branched structures.

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