Self-assembled elastomer nanocomposites utilizing C 60 and poly(styrene-b-butadiene-b-styrene) via thermally reversible Diels-Alder reaction with self-healing and remolding abilities

Polymer ◽  
2017 ◽  
Vol 116 ◽  
pp. 268-277 ◽  
Author(s):  
Jing Bai ◽  
Qing He ◽  
Zixing Shi ◽  
Ming Tian ◽  
Hongjie Xu ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Self Assembled

Self-Healing Hydrophobic POSS-functionalized Fluorinated Copolymer via RAFT Polymerization and dynamic Diels-Alder Reaction

2021 ◽  
Author(s):  
Siva Ponnupandian ◽  
Prantik Mondal ◽  
Thomas Becker ◽  
Richard Hoogenboom ◽  
Andrew B Lowe ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Alder Reaction ◽  
Diels Alder ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Reversible Addition

This investigation reports the preparation of a tailor-made copolymer of furfuryl methacrylate (FMA) and trifluoroethyl methacrylate (TFEMA) via reversible addition-fragmentation chain transfer (RAFT) polymerization. The furfuryl groups of the copolymer...

New Chain Extenders for Self-Healing Polymers

2021 ◽  
Vol 899 ◽  
pp. 628-637
Author(s):  
Daria V. Zakharova ◽  
Zalina A. Lok’yaeva ◽  
Alexander A. Pavlov ◽  
Alexander V. Polezhaev
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Hydroxyl Groups ◽  
Structural Fragment ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Small Series ◽  
Chain Extenders ◽  
Reversible Covalent ◽  
Thermochemical Parameters

We present here a small series of compounds designed to modify the polymer chain of various polyurethanes in order to introduce a structural fragment with the ability of thermally-triggered reversible covalent interactions. Bismaleimides (2a-2e) were synthesized from commercially available aromatic and aliphatic symmetric diamines (1a-1e) and were further introduced into the Diels-Alder reaction with furfuryl alcohol as dienophiles. The Diels-Alder adducts (3a-3e) were obtained as a mixture of endo- and exo-isomer. The presence of symmetrical hydroxyl groups in the structure of the obtained compounds makes them suitable as chain extenders of low molecular weight diisocyanate prepolymers. The presence of a thermally reversible Diels-Alder reaction adduct in the structure of potential chain-extenders opens a possibility to create unique materials with self-healing properties. All compounds obtained were characterized by 1H, 13C NMR, ESI-HRMS, and IR spectroscopy. The thermochemical parameters of the reverse Diels-Alder reaction were established using DSC analysis.

scholarly journals A K+-promoted Diels–Alder reaction by using a self-assembled macrocyclic boronic ester containing two crown ether moieties

2019 ◽  
Vol 10 (32) ◽  
pp. 7627-7632 ◽  
Author(s):  
Kosuke Ono ◽  
Morikazu Niibe ◽  
Nobuharu Iwasawa
Keyword(s):  
Crown Ether ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Boronic Ester ◽  
Self Assembled

A K+-promoted Diels–Alder reaction of 1,4,9,10-anthradiquinone with various dienes is achieved in the presence of a self-assembled macrocyclic boronic ester.

Bio-based self-healing coatings based on thermo-reversible Diels-Alder reaction

2017 ◽  
Vol 111 ◽  
pp. 38-46 ◽  
Author(s):  
Daniel H. Turkenburg ◽  
Yvon Durant ◽  
Hartmut R. Fischer
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Self Healing ◽  
Diels Alder Reaction

Self-healing behavior of polyurethanes based on dual actions of thermo-reversible Diels-Alder reaction and thermal movement of molecular chains

Polymer ◽  
2017 ◽  
Vol 124 ◽  
pp. 48-59 ◽  
Author(s):  
Libang Feng ◽  
Zhengyang Yu ◽  
Yaohui Bian ◽  
Junshan Lu ◽  
Xueting Shi ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Thermal Movement

Mechanistic Insight on the Diels–Alder Reaction Catalyzed by a Self-Assembled Molecular Capsule

2013 ◽  
Vol 78 (8) ◽  
pp. 3577-3582 ◽  
Author(s):  
Lina Xu ◽  
Weijie Hua ◽  
Shugui Hua ◽  
Jun Li ◽  
Shuhua Li
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Mechanistic Insight ◽  
Molecular Capsule ◽  
Self Assembled
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