New reactive poly(ionic liquid)s synthesized by polymer analogous conversion of maleic anhydride containing polymers

Polymer ◽  
2016 ◽  
Vol 96 ◽  
pp. 20-25 ◽  
Author(s):  
Marcus Suckow ◽  
Stephan Zschoche ◽  
Gert Heinrich ◽  
Brigitte Voit ◽  
Frank Böhme
Keyword(s):  
Ionic Liquid ◽  
Maleic Anhydride ◽  
Poly Ionic Liquid

scholarly journals Synthesis of New Hybrid Structured Magnetite Crosslinked Poly Ionic Liquid for Efficient Removal of Coomassie Brilliant Blue R-250 Dye in Aqueous Medium

Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 441
Author(s):  
Abdelrahman O. Ezzat ◽  
Ahmed M. Tawfeek ◽  
Jothi Ramalingam Rajabathar ◽  
Hamad A. Al-Lohedan
Keyword(s):  
Ionic Liquid ◽  
Maleic Anhydride ◽  
Aqueous Solutions ◽  
Brilliant Blue ◽  
Order Kinetic ◽  
Coomassie Brilliant Blue ◽  
Chemical Structures ◽  
Vinyl Pyridine ◽  
Poly Ionic Liquid ◽  
Coomassie Brilliant

In this work, new crosslinked pyridinium poly ionic liquid and its magnetite hybrid structured composite were prepared and applied to remove the toxic dye Coomassie Brilliant Blue (CBB-R250) from aqueous solutions. In this respect, vinyl pyridine, maleic anhydride, and dibromo nonane were used to prepare crosslinked quaternized vinyl pyridinium/maleic anhydride ionic liquid (CQVP-MA). Furthermore, a linear copolymer was prepared by the reaction of vinyl pyridine with bromo nonane followed by its copolymerization with maleic anhydride in order to use it as a capping agent for magnetite nanoparticles. The monodisperse MNPs were incorporated into the crosslinked PIL (CQVP-MA) by ultrasonication to prepare CQVP-MA/Fe3O4 composite to facilitate its recovery using an external magnetic field and enhance its adsorption capacity. The chemical structures, thermal stabilities, zeta potential, particle size, EDS, and SEM of the prepared CQVP-MA and CQVP-MA/Fe3O4 were investigated. Adsorption kinetics, isotherms, and mechanisms of CB-R250 elimination from aqueous solutions using CQVP-MA and CQVP-MA/Fe3O4 were also studied, and the results revealed that the pseudo second-order kinetic model and the Langmuir isotherm model were the most suitable to describe the CBB adsorption from an aqueous solution. The adsorption capacities of CQVP-MA and CQVP-MA/Fe3O4 were found to be 1040 and 1198, respectively, which are more than those for previously reported material in the literature with reasonable stability for five cycles.

A Novel Poly(Ionic Liquid) as the Thermal Insulating Material

2020 ◽  
Vol 13 (3) ◽  
pp. 241-247
Author(s):  
Wenxin Wei ◽  
Guifeng Ma ◽  
Hongtao Wang ◽  
Jun Li
Keyword(s):  
Thermal Conductivity ◽  
Ionic Liquid ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Flame Resistance ◽  
Insulating Material ◽  
Low Thermal Conductivity ◽  
Thermal Insulating ◽  
Poly Ionic Liquid

Objective: A new poly(ionic liquid)(PIL), poly(p-vinylbenzyltriphenylphosphine hexafluorophosphate) (P[VBTPP][PF6]), was synthesized by quaternization, anion exchange reaction, and free radical polymerization. Then a series of the PIL were synthesized at different conditions. Methods: The specific heat capacity, glass-transition temperature and melting temperature of the synthesized PILs were measured by differential scanning calorimeter. The thermal conductivities of the PILs were measured by the laser flash analysis method. Results: Results showed that, under optimized synthesis conditions, P[VBTPP][PF6] as the thermal insulator had a high glass-transition temperature of 210.1°C, high melting point of 421.6°C, and a low thermal conductivity of 0.0920 W m-1 K-1 at 40.0°C (it was 0.105 W m-1 K-1 even at 180.0°C). The foamed sample exhibited much low thermal conductivity λ=0.0340 W m-1 K-1 at room temperature, which was comparable to a commercial polyurethane thermal insulating material although the latter had a much lower density. Conclusion: In addition, mixing the P[VBTPP][PF6] sample into polypropylene could obviously increase the Oxygen Index, revealing its efficient flame resistance. Therefore, P[VBTPP][PF6] is a potential thermal insulating material.

Modular Platform for Synthesis of Poly(Ionic Liquid) Electrolytes for Electrochemical Applications in Supercapacitors

2021 ◽  
Vol 6 (15) ◽  
pp. 3795-3801
Author(s):  
Radostina Kalinova ◽  
Ivaylo Dimitrov ◽  
Christo Novakov ◽  
Svetlana Veleva ◽  
Antonia Stoyanova
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolytes ◽  
Electrochemical Applications ◽  
Modular Platform ◽  
Poly Ionic Liquid

Facile fabrication of self-reporting micellar and vesicular structures based on etching-ion exchange strategy of photonic composite spheres of poly(ionic liquid)

Nanoscale ◽  
2021 ◽  
Author(s):  
Ning Gao ◽  
Kang Zhou ◽  
Kai Feng ◽  
Wanlin Zhang ◽  
Jiecheng Cui ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Exchange ◽  
Chemical Environment ◽  
Facile Fabrication ◽  
Poly Ionic Liquid

Micellar and vesicular structures capable of sensing and reporting the chemical environment as well as facilely introducing user-defined functions make a vital contribution to constructing versatile compartmentalized systems. Herein, combing...

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