Synthesis of star-brush polymer architectures from end-reactive molecular bottlebrushes

Polymer ◽  
2016 ◽  
Vol 98 ◽  
pp. 487-494 ◽  
Author(s):  
Esra Altay ◽  
Javid Rzayev
Keyword(s):  
Polymer Architectures ◽  
Brush Polymer

Bio-mimicking hybrid polymer architectures as adhesion promoters for low and high surface energy substrates

2021 ◽  
Author(s):  
Monisha Baby ◽  
Vijayalakshmi K. Periya ◽  
Bhuvaneshwari Soundiraraju ◽  
Nisha Balachandran ◽  
Suchithra Cheriyan ◽  
...  
Keyword(s):  
Surface Energy ◽  
High Surface ◽  
Hybrid Polymer ◽  
Energy Substrates ◽  
Adhesion Promoters ◽  
Polymer Architectures ◽  
High Surface Energy

Skin-Inspired Hierarchical Polymer Architectures with Gradient Stiffness for Spacer-Free, Ultrathin, and Highly Sensitive Triboelectric Sensors

ACS Nano ◽  
2018 ◽  
Vol 12 (4) ◽  
pp. 3964-3974 ◽  
Author(s):  
Minjeong Ha ◽  
Seongdong Lim ◽  
Soowon Cho ◽  
Youngoh Lee ◽  
Sangyun Na ◽  
...  
Keyword(s):  
Highly Sensitive ◽  
Polymer Architectures

TiCp2Cl-Catalyzed Living Radical and Ring Opening Polymerizations Initiated from Epoxides and Aldehydes in the Synthesis of Linear, Graft and Branched Polymers

2004 ◽  
Vol 856 ◽  
Author(s):  
Alexandru D. Asandei ◽  
Isaac W. Moran ◽  
Gobinda Saha ◽  
Yanhui Chen
Keyword(s):  
Electron Transfer ◽  
Ring Opening ◽  
Glycidyl Methacrylate ◽  
Ring Opening Polymerization ◽  
Branched Polymers ◽  
Single Electron Transfer ◽  
Radical Ring ◽  
Polymer Architectures ◽  
Complex Polymer

ABSTRACTTi(III)Cp2Cl-catalyzed radical ring opening (RRO) of epoxides or single electron transfer (SET) reduction of aldehydes generates Ti alkoxides and carbon centered radicals which add to styrene, initiating a radical polymerization. This polymerization is mediate in a living fashion by the reversible termination of growing chains with the TiCp2Cl metalloradical. In addition, polymers or monomers containing pendant epoxide groups (glycidyl methacrylate) can be used as substrates for radical grafting or branching reactions by self condensing vinyl polymerization. In addition, Ti alkoxides generated in situ by both epoxide RRO and aldehyde SET initiate the living ring opening polymerization of ε-caprolactone. Thus, new initiators and catalysts are introduced for the synthesis of complex polymer architectures.

Well-defined degradable brush-coil block copolymers for intelligent release of insulin at physiological pH

RSC Advances ◽  
2016 ◽  
Vol 6 (26) ◽  
pp. 21486-21496 ◽  
Author(s):  
Xuan Zhang ◽  
Liyuan Zhao ◽  
Junjiao Yang ◽  
Jing Yang
Keyword(s):  
Block Copolymers ◽  
Delivery System ◽  
Side Effect ◽  
Insulin Delivery ◽  
Brush Polymer ◽  
Insulin Delivery System ◽  
Grafting From

To achieve an intelligent insulin delivery system with minimal long-term side effect, a kind of brush polymer was synthesized through poly[(2-phenylborate esters-1,3-dioxane-5-ethyl)methylacrylate] grafting from the backbone poly(ε-caprolactone).

scholarly journals A comparison of shockwave dynamics in stochastic and periodic porous polymer architectures

Polymer ◽  
2019 ◽  
Vol 160 ◽  
pp. 325-337 ◽  
Author(s):  
Brittany Branch ◽  
Axinte Ionita ◽  
Brian M. Patterson ◽  
Andrew Schmalzer ◽  
Bradford Clements ◽  
...  
Keyword(s):  
Porous Polymer ◽  
Polymer Architectures

Synthesis and X-ray structure study on new Au(I) polymer architectures based on multi-sulfur tentacles

2005 ◽  
Vol 690 (5) ◽  
pp. 1332-1339 ◽  
Author(s):  
Keiko Nunokawa ◽  
Kazuya Okazaki ◽  
Satoru Onaka ◽  
Mitsuhiro Ito ◽  
Tetsuya Sunahara ◽  
...  
Keyword(s):  
Structure Study ◽  
X Ray ◽  
Polymer Architectures

scholarly journals Efficient click-addition sequence for polymer–polymer couplings

2016 ◽  
Vol 7 (35) ◽  
pp. 5536-5543 ◽  
Author(s):  
Johannes C. Brendel ◽  
Guillaume Gody ◽  
Sébastien Perrier
Keyword(s):  
Click Chemistry ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Polymer Architectures ◽  
Complex Polymer

Controlled radical polymerization methods and click chemistry form a versatile toolbox for creating complex polymer architectures.

Palm Tree- and Dumbbell-Like Polymer Architectures Based on C60

1999 ◽  
Vol 32 (3) ◽  
pp. 554-558 ◽  
Author(s):  
Y. Ederlé ◽  
C. Mathis
Keyword(s):  
Palm Tree ◽  
Polymer Architectures
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