Polymeric nanoparticles with tunable architecture formed by biocompatible star shaped block copolymer

Polymer ◽  
2012 ◽  
Vol 53 (21) ◽  
pp. 4569-4578 ◽  
Author(s):  
P. Alonso-Cristobal ◽  
M. Laurenti ◽  
F.J. Sanchez-Muniz ◽  
E. López-Cabarcos ◽  
J. Rubio-Retama
2016 ◽  
Vol 120 (20) ◽  
pp. 4635-4643 ◽  
Author(s):  
Qilu Zhang ◽  
Lenny Voorhaar ◽  
Sergey K. Filippov ◽  
Berin Fatma Yeşil ◽  
Richard Hoogenboom

2020 ◽  
Vol 1000 ◽  
pp. 324-330
Author(s):  
Sri Agustina ◽  
Masayoshi Tokuda ◽  
Hideto Minami ◽  
Cyrille Boyer ◽  
Per B. Zetterlund

The self-assembly of block copolymers has attracted attention for many decades because it can yield polymeric nanoobjects with a wide range of morphologies. Membrane emulsification is a fairly novel technique for preparation of various types of emulsions, which relies on the dispersed phase passing through a membrane in order to effect droplet formation. In this study, we have prepared polymeric nanoparticles of different morphologies using self-assembly of asymmetric block copolymers in connection with membrane emulsification. Shirasu Porous Glass (SPG) membranes has been employed as the membrane emulsification equipment, and poly (oligoethylene glycol acrylate)-block-poly (styrene) (POEGA-b-PSt) copolymers prepared via RAFT polymerization. It has been found that a number of different morphologies can be achieved using this novel technique, including spheres, rods, and vesicles. Interestingly, the results have shown that the morphology can be controlled not only by adjusting experimental parameters specific to the membrane emulsification step such as membrane pore size and pressure, but also by changing the nature of organic solvent. As such, this method provides a novel route to these interesting nanoobjects, with interesting prospects in terms of exercising morphology control without altering the nature of the block copolymer itself.


Langmuir ◽  
2020 ◽  
Author(s):  
Mengmeng Zhang ◽  
Zaiyan Hou ◽  
Huiying Wang ◽  
Lianbin Zhang ◽  
Jiangping Xu ◽  
...  

2012 ◽  
Vol 35 (8) ◽  
pp. 1306-1313 ◽  
Author(s):  
Tomoya Araki ◽  
Yusuke Kono ◽  
Ken-ichi Ogawara ◽  
Takaichi Watanabe ◽  
Tsutomu Ono ◽  
...  

2010 ◽  
Vol 27 (3) ◽  
pp. 731-740 ◽  
Author(s):  
Heui Kyoung Cho ◽  
In Woo Cheong ◽  
Jung Min Lee ◽  
Jung Hyun Kim

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 105
Author(s):  
Lakshmeesha Upadhyaya ◽  
Mona Semsarilar ◽  
Damien Quemener ◽  
Rodrigo Fernández-Pacheco ◽  
Gema Martinez ◽  
...  

In this study, we report the impact of the magnetic field on protein permeability through magnetic-responsive, block copolymer, nanocomposite membranes with hydrophilic and hydrophobic characters. The hydrophilic nanocomposite membranes were composed of spherical polymeric nanoparticles (NPs) synthesized through polymerization-induced self-assembly (PISA) with iron oxide NPs coated with quaternized poly(2-dimethylamino)ethyl methacrylate. The hydrophobic nanocomposite membranes were prepared via nonsolvent-induced phase separation (NIPS) containing poly (methacrylic acid) and meso-2,3-dimercaptosuccinic acid-coated superparamagnetic nanoparticles (SPNPs). The permeation experiments were carried out using bovine serum albumin (BSA) as the model solute, in the absence of the magnetic field and under permanent and cyclic magnetic field conditions OFF/ON (strategy 1) and ON/OFF (strategy 2). It was observed that the magnetic field led to a lower reduction in the permeate fluxes of magnetic-responsive membranes during BSA permeation, regardless of the magnetic field strategy used, than that obtained in the absence of the magnetic field. Nevertheless, a comparative analysis of the effect caused by the two cyclic magnetic field strategies showed that strategy 2 allowed for a lower reduction of the original permeate fluxes during BSA permeation and higher protein sieving coefficients. Overall, these novel magneto-responsive block copolymer nanocomposite membranes proved to be competent in mitigating biofouling phenomena in bioseparation processes.


2019 ◽  
Vol 14 (13) ◽  
pp. 1312-1316 ◽  
Author(s):  
Alsaeed M. Abualsayed ◽  
Sara A. Abouelmagd ◽  
Mohamed Abdelgawad

1971 ◽  
Vol 32 (C5) ◽  
pp. C5a-295-C5a-300
Author(s):  
A. KELLER ◽  
J. DLUGOSZ ◽  
M. J. FOLKES ◽  
E. PEDEMONTE ◽  
F. P. SCALISI ◽  
...  

2015 ◽  
Vol 30 (2) ◽  
pp. 171 ◽  
Author(s):  
CHEN Tao-Tao ◽  
LI Dan ◽  
JING Wen-Heng ◽  
FAN Yi-Qun ◽  
XING Wei-Hong

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