Reconsideration on the mechanism of free-radical melt grafting of glycidyl methacrylate on polyolefin

Polymer ◽  
2012 ◽  
Vol 53 (11) ◽  
pp. 2197-2204 ◽  
Author(s):  
Jia-Lin Li ◽  
Xu-Ming Xie
Keyword(s):  
Free Radical ◽  
Glycidyl Methacrylate ◽  
Melt Grafting

Melt Grafting of Glycidyl Methacrylate onto Polyethylene

1998 ◽  
Vol 13 (2) ◽  
pp. 118-128 ◽  
Author(s):  
S. Hojabr ◽  
W. E. Baker ◽  
K. E. Russell ◽  
P. J. McLellan ◽  
M. A. Huneault
Keyword(s):  
Glycidyl Methacrylate ◽  
Melt Grafting

Melt grafting copolymerization of glycidyl methacrylate onto acrylonitrile-butadiene-styrene (ABS) terpolymer

2015 ◽  
Vol 22 (4) ◽  
Author(s):  
Huiju Shao ◽  
Shuhao Qin ◽  
Jianbing Guo ◽  
Bin Wu
Keyword(s):  
Ir Spectra ◽  
Glycidyl Methacrylate ◽  
Acrylonitrile Butadiene Styrene ◽  
Melt Grafting ◽  
Grafting Copolymerization ◽  
Butadiene Styrene

AbstractThe grafting copolymerization of glycidyl methacrylate (GMA) onto acrylonitrile-butadiene-styrene (ABS) terpolymer was carried out using the melt grafting process. Infrared (IR) spectra,

Free Radical Melt Grafting of Methacrylic ester onto Polyolefin Backbone: Model Compound Approach

2009 ◽  
Vol 275-276 (1) ◽  
pp. 275-281 ◽  
Author(s):  
T. Badel ◽  
E. Beyou ◽  
V. Bounor-Legaré ◽  
P. Chaumont ◽  
J.J. Flat ◽  
...  
Keyword(s):  
Free Radical ◽  
Model Compound ◽  
Melt Grafting

Diazonium salt-based photoiniferter as a new efficient pathway to clay–polymer nanocomposites

RSC Advances ◽  
2016 ◽  
Vol 6 (91) ◽  
pp. 88126-88134 ◽  
Author(s):  
Hanène Salmi-Mani ◽  
Zouhair Ait-Touchente ◽  
Aazdine Lamouri ◽  
Benjamin Carbonnier ◽  
Jean-François Caron ◽  
...  
Keyword(s):  
Free Radical ◽  
Polymer Nanocomposites ◽  
Glycidyl Methacrylate ◽  
Diazonium Salt ◽  
Diazonium Salts ◽  
Mass Loading ◽  
Organic Mass ◽  
Free Radical Photopolymerization

Diazonium salts were used to prepare clay–polymer nanocomposites by living free radical photopolymerization of glycidyl methacrylate. The resulting intercalated nanocomposites have an organic mass loading of ∼41 wt% and a polymer-rich surface.

scholarly journals The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Baihong Chi ◽  
Mengying Wei ◽  
Yong He
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Butyl Acrylate ◽  
Glycidyl Methacrylate ◽  
Fluorine Content ◽  
Uv Curing ◽  
Different Types ◽  
Active Diluent ◽  
Low Volume ◽  
Comprehensive Property

A series of fluorine-containing polyacrylic epoxy (FPAE) prepolymers with different fluorine content and molecular weight are synthesized by solution free radical polymerization of hexafluorobutyl methacrylate (HFBMA), butyl acrylate (BA), and glycidyl methacrylate (GMA). The synthesized prepolymers show high conversion and low volume shrinkage. The effect of different types of active diluent for the cationic UV curing of FPAE was investigated, among which oxetane exhibits better comprehensive property than epoxy and vinyl ether. The formulations with the optimal ratio of different functionality oxetane combination show good flexibility, adhesion, hydrophobicity, and antistain property.

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