Nanostructured thermosets from epoxy and poly(2,2,2-trifluoroethyl acrylate)-block-poly(glycidyl methacrylate) diblock copolymer: Demixing of reactive blocks and thermomechanical properties

Polymer ◽  
2011 ◽  
Vol 52 (24) ◽  
pp. 5669-5680 ◽  
Author(s):  
Fangping Yi ◽  
Rentong Yu ◽  
Sixun Zheng ◽  
Xiuhong Li
Keyword(s):  
Diblock Copolymer ◽  
Glycidyl Methacrylate ◽  
Thermomechanical Properties

scholarly journals Aqueous one-pot synthesis of epoxy-functional diblock copolymer worms from a single monomer: new anisotropic scaffolds for potential charge storage applications

2019 ◽  
Vol 10 (2) ◽  
pp. 194-200 ◽  
Author(s):  
Fiona L. Hatton ◽  
Albert M. Park ◽  
Yiren Zhang ◽  
Gregory D. Fuchs ◽  
Christopher K. Ober ◽  
...  
Keyword(s):  
Diblock Copolymer ◽  
Glycidyl Methacrylate ◽  
Charge Storage ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One

The one-pot synthesis of highly anisotropic epoxy-functional diblock copolymer worms is achieved directly in water using a single monomer (glycidyl methacrylate).

scholarly journals Functionalization of Partially Bio-Based Poly(Ethylene Terephthalate) by Blending with Fully Bio-Based Poly(Amide) 10,10 and a Glycidyl Methacrylate-Based Compatibilizer

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1331 ◽  
Author(s):  
Maria Jorda ◽  
Sergi Montava-Jorda ◽  
Rafael Balart ◽  
Diego Lascano ◽  
Nestor Montanes ◽  
...  
Keyword(s):  
Glycidyl Methacrylate ◽  
Ethylene Terephthalate ◽  
Thermomechanical Properties ◽  
Interesting Aspect ◽  
Binary Blends ◽  
Poly Ethylene Terephthalate ◽  
Scanning Electron Microcopy ◽  
Poly Ethylene ◽  
Methacrylate Copolymer ◽  
Intrinsic Stiffness

This work shows the potential of binary blends composed of partially bio-based poly(ethyelene terephthalate) (bioPET) and fully bio-based poly(amide) 10,10 (bioPA1010). These blends are manufactured by extrusion and subsequent injection moulding and characterized in terms of mechanical, thermal and thermomechanical properties. To overcome or minimize the immiscibility, a glycidyl methacrylate copolymer, namely poly(styrene-ran-glycidyl methacrylate) (PS-GMA; Xibond™ 920) was used. The addition of 30 wt % bioPA provides increased renewable content up to 50 wt %, but the most interesting aspect is that bioPA contributes to improved toughness and other ductile properties such as elongation at yield. The morphology study revealed a typical immiscible droplet-like structure and the effectiveness of the PS-GMA copolymer was assessed by field emission scanning electron microcopy (FESEM) with a clear decrease in the droplet size due to compatibilization. It is possible to conclude that bioPA1010 can positively contribute to reduce the intrinsic stiffness of bioPET and, in addition, it increases the renewable content of the developed materials.

Nanostructures and thermomechanical properties of epoxy thermosets containing reactive diblock copolymer

2010 ◽  
Vol 115 (4) ◽  
pp. 2110-2118 ◽  
Author(s):  
Zhiguang Xu ◽  
Nishar Hameed ◽  
Qipeng Guo ◽  
Yiu-Wing Mai
Keyword(s):  
Diblock Copolymer ◽  
Thermomechanical Properties

scholarly journals RAFT dispersion polymerization of glycidyl methacrylate for the synthesis of epoxy-functional block copolymer nanoparticles in mineral oil

2019 ◽  
Vol 10 (5) ◽  
pp. 603-611 ◽  
Author(s):  
Philip J. Docherty ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Block Copolymer ◽  
Diblock Copolymer ◽  
Glycidyl Methacrylate ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Mineral Oil ◽  
Functional Block ◽  
Reversible Addition ◽  
Stearyl Methacrylate

Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) (PSMA-PGlyMA) diblock copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization of glycidyl methacrylate (GlyMA) in mineral oil at 70 °C.

scholarly journals Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil

2020 ◽  
Vol 11 (19) ◽  
pp. 3332-3339
Author(s):  
Philip J. Docherty ◽  
Chloé Girou ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Glycidyl Methacrylate ◽  
Dispersion Polymerization ◽  
Mineral Oil ◽  
Stearyl Methacrylate

Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) spheres, worms or vesicles can be prepared by RAFT dispersion polymerization of glycidyl methacrylate in mineral oil at 70 °C.

scholarly journals Rational synthesis of epoxy-functional spheres, worms and vesicles by RAFT aqueous emulsion polymerisation of glycidyl methacrylate

2020 ◽  
Vol 11 (39) ◽  
pp. 6343-6355
Author(s):  
Fiona L. Hatton ◽  
Matthew J. Derry ◽  
Steven P. Armes
Keyword(s):  
Diblock Copolymer ◽  
Glycidyl Methacrylate ◽  
Aqueous Emulsion ◽  
Mild Conditions ◽  
Emulsion Polymerisation ◽  
Epoxy Groups

The rational synthesis of epoxy-functional diblock copolymer nano-objects has been achieved by RAFT aqueous emulsion polymerisation of glycidyl methacrylate under mild conditions (50 °C, pH 7) to preserve the epoxy groups.

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