Modeling of multicomponent mass transfer across polymer films using a thermodynamically consistent formulation of the Maxwell–Stefan equations in terms of volume fractions

Polymer ◽  
2011 ◽  
Vol 52 (18) ◽  
pp. 3970-3983 ◽  
Author(s):  
Cláudio P. Ribeiro ◽  
Benny D. Freeman ◽  
Donald R. Paul
1994 ◽  
Vol 356 ◽  
Author(s):  
S. Y. Tam ◽  
L. E. Scriven ◽  
H. K. Stolarski

AbstractA model is developed to predict the magnitude and pattern of stress due to drying of polymer films. This model combines diffusion-and-convection equation with large deformation elasto-viscoplasticity, utilizing concentration dependent elastic and viscoplastic material properties to better represent the behavior of drying thin films.The results show that the highest stress occurs at film surface where the concentration depletion is the highest. The magnitude of this stress is induced by increasing mass transfer across the film surface but reduced by increasing diffusion coefficient. The edge effect is significant but local, limited to about four film thicknesses. Similarly, change in substrate induces extra stress.


2019 ◽  
Vol 42 (4) ◽  
pp. 896-902
Author(s):  
Vladimir Kossov ◽  
Olga Fedorenko ◽  
Dauren Zhakebayev

AIChE Journal ◽  
1972 ◽  
Vol 18 (1) ◽  
pp. 25-30 ◽  
Author(s):  
G. L. von Behren ◽  
W. O. Jones ◽  
D. T. Wasan

Sign in / Sign up

Export Citation Format

Share Document