Catalyzed oxidative polymerization to form poly(2,6-dimethyl-1,4-phenylene oxide) in water using water-soluble copper complex

Polymer ◽  
2006 ◽  
Vol 47 (19) ◽  
pp. 6581-6584 ◽  
Author(s):  
Kei Saito ◽  
Norikazu Kuwashiro ◽  
Hiroyuki Nishide
Keyword(s):  
Copper Complex ◽  
Oxidative Polymerization ◽  
Water Soluble ◽  
Phenylene Oxide

Synthesis of poly(2,6-dimethyl-1,4-phenylene oxide) derivatives in water using water-soluble copper complex catalyst with natural ligands

Polymer ◽  
2013 ◽  
Vol 54 (21) ◽  
pp. 5684-5690 ◽  
Author(s):  
Chi-Wei Chen ◽  
I-Hong Lin ◽  
Chung-Chang Lin ◽  
Jen-Lien Lin ◽  
Masaki Horie
Keyword(s):  
Copper Complex ◽  
Water Soluble ◽  
Complex Catalyst ◽  
Phenylene Oxide ◽  
Natural Ligands

1,4,7-Tricarboxymethyl-1,4,7-triazacyclononane Copper Catalyzed Oxidative Polymerization to Form Poly(2,6-dimethyl-1,4-phenylene oxide) in Water

2010 ◽  
Vol 63 (3) ◽  
pp. 502 ◽  
Author(s):  
Sweta Pant ◽  
Milton T. W. Hearn ◽  
Kei Saito
Keyword(s):  
Catalytic System ◽  
Oxidative Polymerization ◽  
Water Soluble ◽  
Polymerization Process ◽  
Alkaline Water ◽  
Phenylene Oxide ◽  
Soluble Ligand

The copper(II) complex of the water soluble ligand 1,4,7-tricarboxymethyl-1,4,7-triazacyclononane has been employed as a catalyst for the oxidative polymerization of 2,6-dimethylphenol using alkaline water as the solvent. With this catalytic system, the polymer, poly(2,6-dimethyl-1,4-phenylene oxide), was successfully obtained with suppression of the formation of the quinone by-product, 4-(3,5-dimethyl-4-oxo-2,5-cyclo-hexadienylidene)-2,6-dimethyl-2,5-cyclohexadienone, during the polymerization process.

Highly Conjugated, Water-Soluble Polymers via the Direct Oxidative Polymerization of Monosubstituted Bithiophenes

1998 ◽  
Vol 31 (3) ◽  
pp. 933-936 ◽  
Author(s):  
Seth C. Rasmussen ◽  
Jason C. Pickens ◽  
James E. Hutchison
Keyword(s):  
Oxidative Polymerization ◽  
Water Soluble ◽  
Water Soluble Polymers ◽  
Soluble Polymers

A water-soluble eumelanin polymer with typical polyelectrolyte behaviour by triethyleneglycol N-functionalization

2015 ◽  
Vol 3 (12) ◽  
pp. 2810-2816 ◽  
Author(s):  
Stefania R. Cicco ◽  
Marianna Ambrico ◽  
Paolo F. Ambrico ◽  
Maurizio Mastropasqua Talamo ◽  
Antonio Cardone ◽  
...  
Keyword(s):  
Oxidative Polymerization ◽  
Water Soluble

Oxidative polymerization of 5,6-dihydroxyindole N-functionalized with TEG chains as a new route to water-soluble eumelanin-like materials..

Catalytic Cu(II)−Amine Terminated Poly(amidoamine) Dendrimer Complexes for Aerobic Oxidative Polymerization To Form Poly(2,6-dimethyl-1,4-phenylene oxide) in Water

2010 ◽  
Vol 43 (4) ◽  
pp. 1695-1698 ◽  
Author(s):  
Cheng Gu ◽  
Ke Xiong ◽  
Baoqing Shentu ◽  
Wenli Zhang ◽  
Zhixue Weng
Keyword(s):  
Oxidative Polymerization ◽  
Phenylene Oxide
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