Preparation and properties of poly(methylmethacrylate)–silica hybrid materials incorporating reactive silica nanoparticles

Polymer ◽  
2006 ◽  
Vol 47 (11) ◽  
pp. 3754-3759 ◽  
Author(s):  
Hideki Sugimoto ◽  
Kazuki Daimatsu ◽  
Eiji Nakanishi ◽  
Yutaka Ogasawara ◽  
Takashi Yasumura ◽  
...  
2015 ◽  
Vol 6 (18) ◽  
pp. 3529-3536 ◽  
Author(s):  
Feng Chen ◽  
Xiaoping Jiang ◽  
Tairong Kuang ◽  
Lingqian Chang ◽  
Dajiong Fu ◽  
...  

Mesoporous silica nanoparticles are modified by electrolyte polymer, giving significant ionic permselectivity under pH and/or temperature switches.


2008 ◽  
Vol 108 (3) ◽  
pp. 1629-1635 ◽  
Author(s):  
Kung-Chin Chang ◽  
Chang-Yu Lin ◽  
Hui-Fen Lin ◽  
Sheng-Che Chiou ◽  
Wan-Chun Huang ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6221-6233
Author(s):  
G. Eliad Benitez-Medina ◽  
Raúl Flores ◽  
Luis Vargas ◽  
Fernando Cuenú ◽  
Pankaj Sharma ◽  
...  

Ruthenium–silica hybrid materials were synthesized. The process was tracked by FT-IR, DRS-UV-Vis, DFT and deconvolution analyses, finding experimental–theoretical correlation.


2007 ◽  
Vol 56 (3) ◽  
pp. 343-349 ◽  
Author(s):  
Jui-Ming Yeh ◽  
Chi-Fa Hsieh ◽  
Chia-Wen Yeh ◽  
Mei-Jyun Wu ◽  
Hsing-Chung Yang

2016 ◽  
Vol 7 (32) ◽  
pp. 5157-5168 ◽  
Author(s):  
G. Bissadi ◽  
R. Weberskirch

The fabrication of silica hybrid nanoparticles by a surface-initiated cationic ring-opening polymerization of poly(2-methyl-2-oxazoline)s has been described.


Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1480 ◽  
Author(s):  
Grzegorzewski ◽  
Benhaim ◽  
Alkotzer ◽  
Zelinger ◽  
Yaakov ◽  
...  

A simple and effective way to prepare multi-walled carbon nanotubes (MWNT)//silica hybrid microcapsules (colloidosomes) is presented. These microcapsules have been generated by emulsion templating in a biphasic oil-in-water (o/w) system. Two trialkoxysilanes of complementary polarity, (3-aminopropyl)triethoxysilane (APTES) and dodecyltriethoxysilane (DTES), were used to chemically immobilize the silica nanoparticles at the o/w interface and stabilize the as-generated Pickering emulsions. The effects of varying the o/w ratio and the concentration of the added solids on the type of emulsion formed, the oil droplet size, as well as the emulsion stability have been investigated. The emulsion phase fraction was dependent on the silica content while the droplet size increased with increasing oil volume percentage. A solid shell emerged around the oil droplets from copolymerization between silane monomers. The thickness of the resulting shells was several hundreds of nm. Although MWNTs and silica nanoparticles both were co-assembled at the o/w interface, silica has shown to be the sole stabilizer, with APTES being crucial for the formation of the shell structure. Drop-casting of the emulsion and air-drying led to hierarchical open porous MWNT-silica nanocomposites. These new structures are promising as electrically conductive thin films for variety of applications, such as electro-optics, encapsulation, or chemical sensing.


2021 ◽  
Author(s):  
Hafezeh Nabipour ◽  
Hu Shi ◽  
Xin Wang ◽  
Xiangming Hu ◽  
Lei Song ◽  
...  

Abstract Wildfires have been recognized as a natural incident in some forests, however, fire season is now more severe and extensive, even in tropical rainforests in which fire could have damaging impacts. A hydrogel is a 3-D polymeric structure encompassing cross-linked and hydrophilic macromolecules. In comparison with water, hydrogels have shown some superiorities in terms of water-binding, cooling, and sealing, which make them be applied in forest fire prevention programs for improving fire-extinguishing performance. In this study, an environmentally friendly phosphorus-modified cellulose/silica hybrid hydrogel was prepared based on the modified methylcellulose by 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide–itaconic acid (DOPO-ITA) and silica nanoparticles. The storage (G') and loss (G") moduli increased with the increment of silica nanoparticles content, owing to the role of silica nanoparticles as crosslinking agent. In the fire prevention experiments, the grass treated with the methylcellulose@DOPO-ITA@silica hybrid hydrogel shows self-extinguishing behavior, whereas those treated with ordinary water or methylcellulose hydrogel can be easily ignited after one week. In the firefighting experiments, the methylcellulose@DOPO-ITA@silica hybrid hydrogel displays much shorter extinguishing time and lower consumption volume than ordinary water and the methylcellulose@DOPO-ITA hydrogel. This work presents an environmentally-friendly, non-toxic, and biodegradable cellulose-based hybrid hydrogel for fire prevention and firefighting of wildfires.


2010 ◽  
Vol 02 (02) ◽  
pp. 115-122 ◽  
Author(s):  
Ulrich Soltmann ◽  
Sabine Matys ◽  
Gunter Kieszig ◽  
Wolfgang Pompe ◽  
Horst Bottcher

2015 ◽  
Vol 1383 ◽  
pp. 70-78 ◽  
Author(s):  
Litao Wang ◽  
Shuqing Dong ◽  
Feng Han ◽  
Yingwei Zhao ◽  
Xia Zhang ◽  
...  

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