Three water soluble coordination polymers: Synthesis, crystal structure and luminescent sensing for Cr(VI) and MnO4− ions in the aqueous phase

Polyhedron ◽  
2019 ◽  
Vol 166 ◽  
pp. 60-64 ◽  
Author(s):  
Kehua Wang ◽  
Mingchang Zhu ◽  
Shuang Ma ◽  
Xin Li ◽  
Meng Zhang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Aqueous Phase ◽  
Coordination Polymers ◽  
Water Soluble ◽  
Luminescent Sensing

N,N,N′,N′-Tetra-Methyl-3-Oxy-Pentane-1,5-Diamide (TMPDA): A Promising Back Extractant for Ln(III) and Zr(IV)

2010 ◽  
Author(s):  
Meng Wei ◽  
Qian’ge He ◽  
Xuegang Liu ◽  
Jing Chen
Keyword(s):  
Crystal Structure ◽  
Aqueous Phase ◽  
Organic Phase ◽  
Extraction Efficiency ◽  
Phase Distribution ◽  
Decomposition Temperature ◽  
Water Soluble ◽  
Phase System ◽  
Acid System ◽  
Equilibrium Aqueous Phase

Water-soluble oxa-diamide ligand, N,N,N′,N′-tetra-methyl-3-oxy-pentane-1,5-diamid (TMPDA) has been synthesized and purified. Its crystal structure, melting point, decomposition temperature, solubilities in aqueous phase and organic phase, distribution ratio between aqueous and organic phase, etc. are reported. The effect of TMPDA concentration in aqueous phase and HNO3 concentration in the equilibrium aqueous phase on the extraction efficiency of La(III), Ce(III), Pr(III), Nd(III), Zr(IV), Fe(III), Y(III), Mo(VI), Ru(III) and Pd(II) by 30% TRPO/kerosene have been studied. The results indicate that TMPDA dissolve well in aqueous phase but almost insoluble in kerosene or 30%TRPO/kerosene in the bi-phase system. It can effectively reduce the extraction of Ln(III), Y(III) and Zr(IV) into 30%TRPO/kerosene at a moderate acid system (0.24mol/L∼0.27mol/L HNO3). TMPDA is a promising stripping agent for Ln(III), Y(III) and Zr(IV) from loaded TRPO.

New water soluble chelating phosphines for aqueous phase catalysis

1997 ◽  
Vol 124 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Hao Ding ◽  
Jianxing Kang ◽  
Brian E. Hanson ◽  
Christian W. Kohlpaintner
Keyword(s):  
Aqueous Phase ◽  
Water Soluble ◽  
Chelating Phosphines ◽  
Aqueous Phase Catalysis

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Synthesis, crystal structure and luminescence of Ag(I) coordination polymers based on a new sulfonate functionalized terpyridine derivative ligand

Polyhedron ◽  
2015 ◽  
Vol 91 ◽  
pp. 52-58 ◽  
Author(s):  
Sa-Sa Shen ◽  
Xiaofang Wang ◽  
Huai-Ming Hu ◽  
Fei Yuan ◽  
Fa-Xin Dong ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers
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