A novel Nb2S4 complex with a dithiophosphinate ligand: Synthesis, structure and redox properties

Polyhedron ◽  
2019 ◽  
Vol 158 ◽  
pp. 458-463 ◽  
Author(s):  
Artem L. Gushchin ◽  
Alexander V. Rogachev ◽  
Iakov S. Fomenko ◽  
Nikolay F. Romashev ◽  
Vladimir A. Nadolinny ◽  
...  
Keyword(s):  
Redox Properties ◽  
Ligand Synthesis

Pyridyldiimine macrocyclic ligands: Influences of template ion, linker length and imine substitution on ligand synthesis, structure and redox properties

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115044
Author(s):  
Laura M. Thierer ◽  
Qiuran Wang ◽  
Sam H. Brooks ◽  
Peng Cui ◽  
Jia Qi ◽  
...  
Keyword(s):  
Redox Properties ◽  
Macrocyclic Ligands ◽  
Linker Length ◽  
Ligand Synthesis

Unusual Coordination Mode of Thiosemicarbazone Ligand. Synthesis, Structure, and Redox Properties of Some Ruthenium and Osmium Complexes

1998 ◽  
Vol 37 (23) ◽  
pp. 6113-6116 ◽  
Author(s):  
Falguni Basuli ◽  
Michael Ruf ◽  
Cortlandt G. Pierpont ◽  
Samaresh Bhattacharya
Keyword(s):  
Coordination Mode ◽  
Redox Properties ◽  
Thiosemicarbazone Ligand ◽  
Osmium Complexes ◽  
Ligand Synthesis

New oxidovanadium(iv) complex with a BIAN ligand: synthesis, structure, redox properties and catalytic activity

2018 ◽  
Vol 42 (19) ◽  
pp. 16200-16210 ◽  
Author(s):  
Iakov S. Fomenko ◽  
Artem L. Gushchin ◽  
Lidia S. Shul’pina ◽  
Nikolay S. Ikonnikov ◽  
Pavel A. Abramov ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carboxylic Acid ◽  
Catalytic System ◽  
Redox Properties ◽  
Saturated Hydrocarbons ◽  
Ligand Synthesis

The combination of a new oxidovanadium(iv) complex1with pyrazine-2-carboxylic acid (PCA; a cocatalyst) affords a catalytic system for the efficient oxidation of saturated hydrocarbons.

Polymer oxidation catalyst containing acidic functional groups

1981 ◽  
Vol 46 (5) ◽  
pp. 1237-1247
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek
Keyword(s):  
Functional Groups ◽  
Elevated Temperatures ◽  
Redox Properties ◽  
Oxidation Catalyst ◽  
Carbon Clusters ◽  
Oxidation Activity ◽  
Redox Sites ◽  
Styrene Divinylbenzene ◽  
Proportional Decrease ◽  
Polymer Oxidation

The catalyst containing redox sites in addition to acid functional groups was prepared by sulphonation of a macroporous chloromethylated styrene-divinylbenzene copolymer with concentrated sulphuric acid at elevated temperatures. Its activity was tested for the oxidation of 2-propanol by molecular oxygen at 120 °C and was found to be comparable to that of the iridium on carbon catalyst.Neutralisation of acid functional groups by alkali metal led to proportional decrease in the oxidation activity. The results of EPR spectroscopic study of these catalysts show that the redox properties of the polymer are caused by carbon clusters which are capable of electron exchange.

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Influence of Metal Core Composition on Redox Properties and Photoreactivity of the Clusters [H4-xRu4-xRhx(CO)12] (x = 0, 2, 3, 4)

2001 ◽  
Vol 66 (7) ◽  
pp. 1062-1077 ◽  
Author(s):  
Maarten J. Bakker ◽  
Tapani A. Pakkanen ◽  
František Hartl
Keyword(s):  
Electrochemical Properties ◽  
Electrochemical Reduction ◽  
Redox Properties ◽  
Metal Core ◽  
Loss Product ◽  
Condensation Reactions ◽  
Core Composition ◽  
Co Dissociation ◽  
Major Reduction

Electrochemical properties of tetrahedral clusters [H2Ru2Rh2(CO)12], [HRuRh3(CO)12] and [Rh4(CO)12] were investigated in order to evaluate the influence of metal core composition in the series [H4-xRu4-xRhx(CO)12] (x = 0-4). The cluster [H3Ru3Rh(CO)12] was not available in sufficient quantities. As reported for [H4Ru4(CO)12], electrochemical reduction of the hydride-containing clusters [H2Ru2Rh2(CO)12] and [HRuRh3(CO)12] also results in (stepwise) loss of hydrogen, producing the anions [HRu2Rh2(CO)12]-, [Ru2Rh2(CO)12]2- and [RuRh3(CO)12]-. These anions can also be prepared from the neutral parent clusters via chemical routes. Electrochemical reduction of [Rh4(CO)12] does not result in the formation of any stable tetranuclear anion. Instead, [Rh5(CO)15]- and [Rh6(CO)15]2- are the major reduction products detected in the course of IR spectroelectrochemical experiments. Most likely, these cluster species are formed from the secondary CO-loss product [Rh4(CO)11]2- by fast redox condensation reactions. Their reoxidation regenerates parent [Rh4(CO)12], together with some [Rh6(CO)16]. Unlike [H4Ru4(CO)12] that undergoes photochemical CO-dissociation, [H2Ru2Rh2(CO)12] and [Rh4(CO)12] are completely photostable in neat hexane and dichloromethane as well as in the presence of oct-1-ene.

Sign in / Sign up

Export Citation Format

Share Document