Construction and crystal structure of a pair of tetranuclear Zn(II) chiral clusters that exhibit ferroelectric behavior under a higher frequency electric field at room temperature

Polyhedron ◽  
2017 ◽  
Vol 137 ◽  
pp. 217-221 ◽  
Author(s):  
Haiyang Yu ◽  
Meiying Liu ◽  
Xuechuan Gao ◽  
Zhiliang Liu
Keyword(s):  
Crystal Structure ◽  
Electric Field ◽  
Room Temperature ◽  
Ferroelectric Behavior ◽  
Frequency Electric Field

Room temperature crystal structure and relaxor ferroelectric behavior of Pb0.5Ca0.5TiO3

1997 ◽  
Vol 70 (24) ◽  
pp. 3221-3223 ◽  
Author(s):  
Rajeev Ranjan ◽  
Neelam Singh ◽  
Dhananjai Pandey ◽  
V. Siruguri ◽  
P. S. R. Krishna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Room Temperature ◽  
Relaxor Ferroelectric ◽  
Ferroelectric Behavior

Development of a Low Frequency Electric Field Probe Integrating Data Acquisition and Storage

2020 ◽  
Vol E103.C (8) ◽  
pp. 345-352
Author(s):  
Zhongyuan ZHOU ◽  
Mingjie SHENG ◽  
Peng LI ◽  
Peng HU ◽  
Qi ZHOU
Keyword(s):  
Electric Field ◽  
Data Acquisition ◽  
Low Frequency ◽  
Frequency Electric Field ◽  
Electric Field Probe ◽  
And Storage

Single Crystal Growth of High-Pressure Phases of Ice and Salt Hydrate Far Below the Original Melting Point by Mixing Alcohol: Crystal Structure Determination of Magnesium Chloride Heptahydrate

2020 ◽  
Author(s):  
Keishiro Yamashita ◽  
Kazuki Komatsu ◽  
Hiroyuki Kagi
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Crystal Growth ◽  
Single Crystal ◽  
Room Temperature ◽  
Growth Technique ◽  
Salt Hydrate ◽  
X Ray

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl<sub>2</sub>·7H<sub>2</sub>O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

New requirements for power frequency electric field and induced current personal protective equipment

2020 ◽  
Vol 60 (11) ◽  
pp. 849-852
Author(s):  
Sergey Yu. Perov ◽  
Tatyana A. Konshina ◽  
Elena N. Makarova-Zemlyanskaya
Keyword(s):  
Electric Field ◽  
Personal Protective Equipment ◽  
Occupational Safety ◽  
Protective Equipment ◽  
Safety Standards ◽  
Emergency Situations ◽  
Step Voltage ◽  
Power Frequency ◽  
Staff Protection ◽  
Frequency Electric Field

In conditions of exceeding the maximum permissible levels of power frequency electric field, the staff must use personal protective equipment. Requirements for such means are regulated by the system of occupational safety standards. The goal of this work is analyzed new requirements for power frequency and induced personal protective equipment in the regulatory interstate standards GOST 12.4.172 and GOST 12.4.283. The personal protective equipment new requirements for various types of work are substantiated to electrical personnel health safety during the maintenance and operation of power grid facilities. Increasing requirements for personal protective equipment improves the staff protection at ground potential and at wire potential, including in emergency situations such as induced and step voltage.

scholarly journals Crystal structure of K[Hg(SCN)3] – a redetermination

2014 ◽  
Vol 70 (9) ◽  
pp. i46-i46 ◽  
Author(s):  
Matthias Weil ◽  
Thomas Häusler
Keyword(s):  
Crystal Structure ◽  
Room Temperature ◽  
Three Dimensional ◽  
Lattice Parameters ◽  
Bond Lengths ◽  
Dimensional Network ◽  
Anisotropic Displacement Parameters ◽  
Precision And Accuracy ◽  
Standard Deviations ◽  
Atomic Coordinates

The crystal structure of the room-temperature modification of K[Hg(SCN)3], potassium trithiocyanatomercurate(II), was redetermined based on modern CCD data. In comparison with the previous report [Zhdanov & Sanadze (1952).Zh. Fiz. Khim.26, 469–478], reliability factors, standard deviations of lattice parameters and atomic coordinates, as well as anisotropic displacement parameters, were revealed for all atoms. The higher precision and accuracy of the model is, for example, reflected by the Hg—S bond lengths of 2.3954 (11), 2.4481 (8) and 2.7653 (6) Å in comparison with values of 2.24, 2.43 and 2.77 Å. All atoms in the crystal structure are located on mirror planes. The Hg2+cation is surrounded by four S atoms in a seesaw shape [S—Hg—S angles range from 94.65 (2) to 154.06 (3)°]. The HgS4polyhedra share a common S atom, building up chains extending parallel to [010]. All S atoms of the resulting1∞[HgS2/1S2/2] chains are also part of SCN−anions that link these chains with the K+cations into a three-dimensional network. The K—N bond lengths of the distorted KN7polyhedra lie between 2.926 (2) and 3.051 (3) Å.

scholarly journals Exploring the Structural Chemistry of Pyrophosphoramides: N,N′,N″,N‴-Tetraisopropylpyrophosphoramide

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 149-163
Author(s):  
Duncan Micallef ◽  
Liana Vella-Zarb ◽  
Ulrich Baisch
Keyword(s):  
Crystal Structure ◽  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Hydrogen Bonding ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Room Temperature ◽  
Intermolecular Hydrogen Bonding ◽  
X Ray Diffraction ◽  
X Ray

N,N′,N″,N‴-Tetraisopropylpyrophosphoramide 1 is a pyrophosphoramide with documented butyrylcholinesterase inhibition, a property shared with the more widely studied octamethylphosphoramide (Schradan). Unlike Schradan, 1 is a solid at room temperature making it one of a few known pyrophosphoramide solids. The crystal structure of 1 was determined by single-crystal X-ray diffraction and compared with that of other previously described solid pyrophosphoramides. The pyrophosphoramide discussed in this study was synthesised by reacting iso-propyl amine with pyrophosphoryl tetrachloride under anhydrous conditions. A unique supramolecular motif was observed when compared with previously published pyrophosphoramide structures having two different intermolecular hydrogen bonding synthons. Furthermore, the potential of a wider variety of supramolecular structures in which similar pyrophosphoramides can crystallise was recognised. Proton (1H) and Phosphorus 31 (31P) Nuclear Magnetic Resonance (NMR) spectroscopy, infrared (IR) spectroscopy, mass spectrometry (MS) were carried out to complete the analysis of the compound.

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