Based on a V-shaped In(III) metal–organic framework (MOF): Design, synthesis and characterization of diverse physical and chemical properties

Polyhedron ◽  
2017 ◽  
Vol 134 ◽  
pp. 207-214 ◽  
Author(s):  
Xu Zhang ◽  
Li-Xian Sun ◽  
Jian Song ◽  
Ning Du ◽  
Yong-Heng Xing ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Chemical Properties ◽  
Synthesis And Characterization ◽  
Physical And Chemical Properties ◽  
Design Synthesis ◽  
Metal Organic ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Organic Framework

Thiol Decorated Defective Metal-Organic Framework Embedded with Palladium Nanoparticles for Efficient Cr(VI) Reduction

2021 ◽  
Author(s):  
Sukhendu Mandal ◽  
Asha P. ◽  
R. K. Aparna ◽  
Balu P Ratheesh ◽  
Manju M Maman
Keyword(s):  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Metal Organic ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Organic Framework

Engineering defective UiO-66 with functionalized modulator may create functionality with promising physical and chemical properties. Herein, we use 2-mercaptobenzoic acid (2-MBA) as a modulator for the functionalization of defective UiO-66...

Metal Organic Framework Derived Porous Carbon Materials Excels as an Excellent Platform for High-performance Packaged Supercapacitors

Nanoscale ◽  
2021 ◽  
Author(s):  
Xianyu Chu ◽  
Fanling Meng ◽  
Ting Deng ◽  
Wei Zhang
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Metal Organic Framework ◽  
Chemical Properties ◽  
Porous Carbon Material ◽  
Metal Organic ◽  
Key Steps ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Organic Framework

Designing and synthesizing new materials with special physical and chemical properties are the key steps to assembling high performance supercapacitors. Metal organic framework (MOF) derived porous carbon material has drawn...

scholarly journals Recent Progress in the Synthesis and Characterization of Diarylethene-based MOFs

2014 ◽  
Vol 70 (a1) ◽  
pp. C1223-C1223
Author(s):  
Jason Benedict ◽  
Ian Walton ◽  
Dan Patel ◽  
Jordan Cox
Keyword(s):  
Chemical Properties ◽  
Building Blocks ◽  
Synthesis And Characterization ◽  
Next Generation ◽  
Design Synthesis ◽  
Thermally Induced ◽  
Potential Applications ◽  
External Stimuli ◽  
Physical And Chemical

Metal-organic Frameworks (MOFs) remain an extremely active area of research given the wide variety of potential applications and the enormous diversity of structures that can be created from their constituent building blocks. While MOFs are typically employed as passive materials, next-generation materials will exhibit structural and/or electronic changes in response to applied external stimuli including light, charge, and pH. Herein we present recent results in which advanced photochromic diarylethenes are combined with MOFs through covalent and non-covalent methods to create photo-responsive permanently porous crystalline materials. This presentation will describe the design, synthesis, and characterization of next-generation photo-switchable diarylethene based ligands which are subsequently used to photo-responsive MOFs. These UBMOF crystals are, by design, isostructural with previously reported non-photoresponsive frameworks which enables a systematic comparison of their physical and chemical properties. While the photoswitching of the isolated ligand in solution is fully reversible, the cycloreversion reaction is suppressed in the UBMOF single crystalline phase. Spectroscopic evidence for thermally induced cycloreversion will be presented, as well as a detailed analysis addressing the limits of X-ray diffraction techniques applied to these systems.

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