Polymorphs of spin-crossover iron(II) complex fac -[Fe II (HL n -Pr ) 3 ]Cl·PF 6 (HL n -Pr = 2-methylimidazol-4-yl-methylideneamino- n -propyl): Assembly structures and scan rate dependent spin-crossover properties with thermal hysteresis

Polyhedron ◽  
2017 ◽  
Vol 136 ◽  
pp. 13-22 ◽  
Author(s):  
Takahiro Ueno ◽  
Yuto Ii ◽  
Takeshi Fujinami ◽  
Naohide Matsumoto ◽  
Seiichiro Iijima ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Rate Dependent ◽  
Scan Rate

First-order reversal curves analysis of rate-dependent hysteresis: The example of light-induced thermal hysteresis in a spin-crossover solid

2005 ◽  
Vol 72 (5) ◽  
Author(s):  
Cristian Enachescu ◽  
Radu Tanasa ◽  
Alexandru Stancu ◽  
Francois Varret ◽  
Jorge Linares ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Thermal Hysteresis ◽  
First Order ◽  
Rate Dependent

Heating-rate dependence of spin-crossover hysteresis observed in an iron(ii) complex having tris(2-pyridyl)methanol

2015 ◽  
Vol 3 (30) ◽  
pp. 7784-7787 ◽  
Author(s):  
Masaru Yamasaki ◽  
Takayuki Ishida
Keyword(s):  
Heating Rate ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Rate Dependence ◽  
Scan Rate

Me4N[Fe(py3COH)(NCS)3](H2O) showed an abrupt spin-crossover with thermal hysteresis, and temperature-scan rate dependence was recorded upon heating.

Remarkable Scan Rate Dependence for a Highly Constrained Dinuclear Iron(II) Spin Crossover Complex with a Wide Thermal Hysteresis Loop

2014 ◽  
Vol 136 (3) ◽  
pp. 878-881 ◽  
Author(s):  
Rafal Kulmaczewski ◽  
Juan Olguín ◽  
Jonathan A. Kitchen ◽  
Humphrey L. C. Feltham ◽  
Guy N. L. Jameson ◽  
...  
Keyword(s):  
Hysteresis Loop ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Rate Dependence ◽  
Dinuclear Iron ◽  
Scan Rate ◽  
Thermal Hysteresis Loop

Scan Rate Dependent Spin Crossover Iron(II) Complex with Two Different Relaxations and Thermal Hysteresisfac-[FeII(HLn-Pr)3]Cl·PF6(HLn-Pr= 2-Methylimidazol-4-yl-methylideneamino-n-propyl)

2015 ◽  
Vol 54 (15) ◽  
pp. 7291-7300 ◽  
Author(s):  
Takeshi Fujinami ◽  
Koshiro Nishi ◽  
Daisuke Hamada ◽  
Keishiro Murakami ◽  
Naohide Matsumoto ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Rate Dependent ◽  
Scan Rate

Spatiotemporal Observation and Modeling of Remarkable Temperature Scan Rate Effects on the Thermal Hysteresis in a Spin-Crossover Single Crystal

2017 ◽  
Vol 121 (21) ◽  
pp. 11700-11708 ◽  
Author(s):  
Rachid Traiche ◽  
Mouhamadou Sy ◽  
Hassane Oubouchou ◽  
Guillaume Bouchez ◽  
François Varret ◽  
...  
Keyword(s):  
Single Crystal ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Rate Effects ◽  
Scan Rate

Spin crossover with thermal hysteresis in cobalt(ii) complexes and the importance of scan rate

2014 ◽  
Vol 38 (5) ◽  
pp. 1932 ◽  
Author(s):  
Reece G. Miller ◽  
Suresh Narayanaswamy ◽  
Jeffery L. Tallon ◽  
Sally Brooker
Keyword(s):  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Scan Rate

ChemInform Abstract: Spin Crossover with Thermal Hysteresis in Cobalt(II) Complexes and the Importance of Scan Rate

ChemInform ◽  
2014 ◽  
Vol 45 (26) ◽  
pp. no-no
Author(s):  
Reece G. Miller ◽  
Suresh Narayanaswamy ◽  
Jeffery L. Tallon ◽  
Sally Brooker
Keyword(s):  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Scan Rate

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

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