Assembly, structures, electrocatalytic and photocatalytic properties of a series of Anderson-type polyoxometalate-based metal–organic complexes based on flexible pyridyl-amide ligands

Polyhedron ◽  
2017 ◽  
Vol 124 ◽  
pp. 30-40 ◽  
Author(s):  
Xiu-Li Wang ◽  
Junjun Sun ◽  
Hongyan Lin ◽  
Zhihan Chang ◽  
Xue Bai ◽  
...  
Keyword(s):  
Photocatalytic Properties ◽  
Amide Ligands ◽  
Organic Complexes ◽  
Metal Organic

Assembly and Properties of Four New Metal–Organic Complexes Based on 1,4-Naphthalenedicarboxylate: Effect of Four Bis-pyridyl-bis-amide Ligands with Diverse Spacers in the Structures

2015 ◽  
Vol 68 (10) ◽  
pp. 1550 ◽  
Author(s):  
Hong-Yan Lin ◽  
Xun-Zhang Zhao ◽  
Ling Zeng ◽  
Qing-Lin Wang ◽  
Xiu-Li Wang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Photocatalytic Properties ◽  
Coordination Modes ◽  
Coordination Network ◽  
Amide Ligands ◽  
Hydrogen Bonding Interactions ◽  
Organic Complexes ◽  
3D Architecture ◽  
Metal Organic ◽  
Supramolecular Networks

Four new complexes based on 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) and four bis-pyridyl-bis-amide ligands with various spacers (3-bpye = N,N′-bis(3-pyridinecarboxamide)-1,2-ethane; 3-bpfp = bis(3-pyridylformyl)piperazine; 3-bpcd = N,N′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide; and 3-bpcb = N,N′-bis(3-pyridinecarboxamide)-1,4-benzene), namely [Cu2(1,4-NDC)2(3-bpye)(H2O)] (1), [Cu(1,4-NDC)(3-bpfp)0.5] (2), [Cu3(1,4-NDC)3(3-bpcd)3]·2H2O (3), and [Cu(1,4-NDC)(3-bpcb)] (4), have been hydrothermally synthesized. Complex 1 is a 3D coordination network and represents an 8-connected {420.68} topology. Complex 2 shows a 2-fold interpenetrating 3D architecture with a 6-connected {412.63} topology. Complexes 3 and 4 possess similar 2D sql layers with the {44.62} topology, but the coordination modes of 1,4-NDC ligands and the conformations of the two bis-pyridyl-bis-amide ligands are different. The adjacent layers for 3 and 4 are further linked by hydrogen bonding interactions to form 3D supramolecular networks. The successful assemblies of complexes 1–4 imply that by using the different bis-pyridyl-bis-amide ligands with diverse spacers can produce diverse metal–organic networks. Furthermore, the fluorescence and photocatalytic properties of complexes 1–4 have been investigated.

Novel Anderson-type [TeMo6O24]6−-based metal–organic complexes tuned by different species and their coordination modes: assembly, various architectures and properties

2016 ◽  
Vol 45 (6) ◽  
pp. 2709-2719 ◽  
Author(s):  
Xiuli Wang ◽  
Junjun Sun ◽  
Hongyan Lin ◽  
Zhihan Chang ◽  
Aixiang Tian ◽  
...  
Keyword(s):  
Photocatalytic Properties ◽  
Coordination Modes ◽  
Organic Complexes ◽  
Metal Organic

Four novel Anderson-type polyoxometalate [TeMo6O24]6−-based metal–organic complexes were hydrothermally synthesized and characterized, which show fluorescence, electrochemical and photocatalytic properties.

Two novel Anderson-type polyoxometalate-based metal–organic complexes with high-efficiency photocatalysis towards degradation of organic dyes under UV and visible light irradiation

RSC Advances ◽  
2015 ◽  
Vol 5 (18) ◽  
pp. 14020-14026 ◽  
Author(s):  
Xiuli Wang ◽  
Zhihan Chang ◽  
Hongyan Lin ◽  
Aixiang Tian ◽  
Guocheng Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
High Efficiency ◽  
Organic Dyes ◽  
Light Irradiation ◽  
Amide Ligands ◽  
Degradation Of Dyes ◽  
Organic Complexes ◽  
Photocatalytic Activities ◽  
Metal Organic

Two novel Anderson-type polyoxometalate-based metal–organic complexes constructed from two bis-pyridyl-bis-amide ligands have been hydrothermally synthesized, showing excellent photocatalytic activities toward the degradation of dyes.

Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xiuli Wang ◽  
Lei Li ◽  
Xiang Wang ◽  
Yuqing Zhang
Keyword(s):  
Electrochemical Sensors ◽  
Organic Ligands ◽  
Electrochemical Sensing ◽  
Photocatalytic Properties ◽  
Organic Complexes ◽  
Metal Organic

Five octamolybdate-based complexes with diverse architectures employing three new amide-derived organic ligands can be used as promising electrochemical sensors and photocatalysts.

Assembly, structures, photophysical properties and photocatalytic activities of a series of coordination polymers constructed from semi-rigid bis-pyridyl-bis-amide and benzenetricarboxylic acid

2015 ◽  
Vol 2 (4) ◽  
pp. 373-387 ◽  
Author(s):  
Xiuli Wang ◽  
Mao Le ◽  
Hong-Yan Lin ◽  
Jian Luan ◽  
Guo-Cheng Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Photophysical Properties ◽  
Photocatalytic Properties ◽  
Fluorescence Sensing ◽  
Amide Ligands ◽  
Photocatalytic Activities ◽  
Metal Organic ◽  
Benzenetricarboxylic Acid

Ten metal–organic coordination polymers 1–10 based on semi-rigid bis-pyridyl-bis-amide ligands have been synthesized. The fluorescence sensing and photocatalytic properties of 1–10 have been investigated.

Evans–Showell-type polyoxometalate-based metal–organic complexes with novel 3D structures constructed from flexible bis-pyrazine–bis-amide ligands and copper metals: syntheses, structures, and fluorescence and catalytic properties

2019 ◽  
Vol 48 (6) ◽  
pp. 2160-2169 ◽  
Author(s):  
Feng-Cai Li ◽  
Xi-Li Li ◽  
Li-Kun Tan ◽  
Jin-Tang Wang ◽  
Wei-Zhong Yao
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Catalytic Properties ◽  
3D Structures ◽  
Heterogeneous Catalytic ◽  
Amide Ligands ◽  
Oxidation Of Benzyl Alcohol ◽  
Organic Complexes ◽  
Metal Organic

Two 3D Evans–Showell-type POM-based copper–bis-pyrazine–bis-amide complexes show good heterogeneous catalytic activity for the oxidation of benzyl alcohol.

Effect of N-donor sites of bis-pyridyl-bis-amide ligands on the architectures of three Anderson-type polyoxometalate-based metal–organic complexes

2017 ◽  
Vol 42 (2) ◽  
pp. 145-152
Author(s):  
Xiu-Li Wang ◽  
Jun-Jun Sun ◽  
Hong-Yan Lin ◽  
Zhi-Han Chang ◽  
Xue Bai ◽  
...  
Keyword(s):  
Amide Ligands ◽  
Organic Complexes ◽  
Metal Organic
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