Homoleptic, di- and trivalent transition metal complexes with monoanionic N,N,O-heteroscorpionate ligands: Potential redox mediators for dye-sensitized solar cells?

Polyhedron ◽  
2017 ◽  
Vol 125 ◽  
pp. 34-43 ◽  
Author(s):  
Stephan Pflock ◽  
Andreas Beyer ◽  
Lisa Müller ◽  
Nicolai Burzlaff
Keyword(s):  
Solar Cells ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dye Sensitized Solar Cells ◽  
Redox Mediators ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

scholarly journals Intriguing C–H⋯Cu interactions in bis-(phenanthroline)Cu(i) redox mediators for dye-sensitized solar cells

2018 ◽  
Vol 47 (4) ◽  
pp. 1018-1022 ◽  
Author(s):  
Alessia Colombo ◽  
Rachele Ossola ◽  
Mirko Magni ◽  
Dominique Roberto ◽  
Denis Jacquemin ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Redox Mediators ◽  
Methyl Group ◽  
Dye Sensitized ◽  
Copper Site ◽  
First Time ◽  
Sensitized Solar Cells

For the first time, an anagostic interaction is found between a H atom of a methyl group and a copper site in the bis-2-tertbutyl(phenanthroline)Cu(i) complex.

Methoxy-Substituted Copper Complexes as possible Redox Mediators in Dye-Sensitized Solar Cells

2021 ◽  
Author(s):  
Marco Giordano ◽  
Giorgio Volpi ◽  
Matteo Bonomo ◽  
Paolo Mariani ◽  
Claudio Garino ◽  
...  
Keyword(s):  
Solar Cells ◽  
Copper Complexes ◽  
Dye Sensitized Solar Cells ◽  
Redox Mediators ◽  
Dye Sensitized ◽  
Diimine Ligands ◽  
Sensitized Solar Cells

Three aromatic diimine ligands and the corresponding homoleptic copper(I) and copper(II) complexes have been synthetized and characterized. The copper(II) derivatives are stabilized by an ancillary chlorido ligand. The nature of...

Improving the mass transport of copper-complex redox mediators in dye-sensitized solar cells by reducing the inter-electrode distance

2017 ◽  
Vol 19 (47) ◽  
pp. 32132-32142 ◽  
Author(s):  
Rodrigo García-Rodríguez ◽  
Roger Jiang ◽  
Esdras J. Canto-Aguilar ◽  
Gerko Oskam ◽  
Gerrit Boschloo
Keyword(s):  
Solar Cells ◽  
Mass Transport ◽  
Copper Complex ◽  
Fill Factor ◽  
Dye Sensitized Solar Cells ◽  
Redox Mediators ◽  
Dye Sensitized ◽  
Electrode Distance ◽  
Sensitized Solar Cells ◽  
Internal Transport

Reduction of inter-electrode distance in DSCs with copper-based electrolyte increases the photocurrent and fill factor by improving internal transport.

Correlating cobalt redox couples to photovoltage in the dye-sensitized solar cell

2018 ◽  
Vol 47 (34) ◽  
pp. 11942-11952 ◽  
Author(s):  
Kitty Y. Chen ◽  
Phil A. Schauer ◽  
Brian O. Patrick ◽  
Curtis P. Berlinguette
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Redox Potential ◽  
Linear Correlation ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Redox Mediators ◽  
Dye Sensitized ◽  
Redox Couples ◽  
Sensitized Solar Cells

Two sets of structurally analogous Co(iii/ii)-based redox mediators were incorporated in the dye-sensitized solar cells and a linear correlation was demonstrated between redox potential and photovoltage.

N,N′-Bis((6-methoxylpyridin-2-yl)methylene)-p-phenylenediimine based d10 transition metal complexes and their utilization in co-sensitized solar cells

2014 ◽  
Vol 43 (29) ◽  
pp. 11361-11370 ◽  
Author(s):  
Liguo Wei ◽  
Yulin Yang ◽  
Ruiqing Fan ◽  
Yong Na ◽  
Ping Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Sensitized Solar Cells

New d10 transition metal complexes of ZnL, CdL and HgL enhanced the performance of DSSCs by co-sensitization with N719.

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