Hepta-coordinated heteroleptic derivatives of zirconium(IV): Synthesis, structural characterization and ring opening polymerization of ε-caprolactone

Polyhedron ◽  
2016 ◽  
Vol 107 ◽  
pp. 163-171 ◽  
Author(s):  
Giri Prasanth Vuppalapati ◽  
Ravindranath S. Rathore ◽  
Madhvesh Pathak ◽  
Sathiyanarayanan Kulathu Iyer
Keyword(s):  
Structural Characterization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Derivatives Of

Group 4 metal complexes of Trost's semi-crown ligand: synthesis, structural characterization and studies on the ring-opening polymerization of lactides and ε-caprolactone

2015 ◽  
Vol 44 (37) ◽  
pp. 16280-16293 ◽  
Author(s):  
Bijja Rajashekhar ◽  
Sagnik K. Roymuhury ◽  
Debashis Chakraborty ◽  
Venkatachalam Ramkumar
Keyword(s):  
Metal Complexes ◽  
Structural Characterization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Group 4 ◽  
Crown Ligand ◽  
Ligand Synthesis ◽  
Group 4 Metal

The synthesis of titanium(iv), zirconium(iv) and hafnium(iv) complexes of Trost's semi-crown ligand is described.

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