Syntheses and characterization of various supramolecular compounds from the self-assembly of nickel(II) hexaaza macrocyclic complex with carboxylic acid derivatives

Polyhedron ◽  
2016 ◽  
Vol 105 ◽  
pp. 62-70 ◽  
Author(s):  
Jong Won Shin ◽  
Dae-Woong Kim ◽  
Dohyun Moon
Keyword(s):  
Carboxylic Acid ◽  
Self Assembly ◽  
Macrocyclic Complex ◽  
The Self ◽  
Supramolecular Compounds

Estimating the shape and size of supramolecular assemblies by variable temperature diffusion ordered spectroscopy

2014 ◽  
Vol 12 (40) ◽  
pp. 7932-7936 ◽  
Author(s):  
Benjamin M. Schulze ◽  
Davita L. Watkins ◽  
Jing Zhang ◽  
Ion Ghiviriga ◽  
Ronald K. Castellano
Keyword(s):  
Self Assembly ◽  
Variable Temperature ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Conjugated Oligomers ◽  
Photovoltaic Devices ◽  
Temperature Diffusion ◽  
Shape And Size

Reported is characterization of the self-assembly of π-conjugated oligomers, molecules studied recently in photovoltaic devices, using variable temperature diffusion ordered spectroscopy; the approach has allowed estimation of assembly size, shape, and molecularity.

The Self-assembly, Characterization of Hepatocytes on Nano-sized Gold Colloid and Construction of Cellular Biosensor

2003 ◽  
Vol 32 (10) ◽  
pp. 934-935 ◽  
Author(s):  
Hai-Ying Gu ◽  
Rong-Xiao Sa ◽  
Su-Su Yuan ◽  
Hong-Yuan Chen ◽  
Ai-Min Yu
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Gold Colloid

The self-assembly and photophysical characterization of tri(cyclopenta[def]phenanthrene)-derived nanoparticles: a template free synthesis of hollow colloidosomes.

2010 ◽  
Vol 20 (43) ◽  
pp. 9684 ◽  
Author(s):  
Shanmugam Easwaramoorthi ◽  
Pyosang Kim ◽  
Jong Min Lim ◽  
Suhee Song ◽  
Honsuk Suh ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Template Free

scholarly journals Self-assembly of nucleopeptides to interact with DNAs

2017 ◽  
Vol 7 (6) ◽  
pp. 20160116 ◽  
Author(s):  
Xuewen Du ◽  
Jie Zhou ◽  
Xinming Li ◽  
Bing Xu
Keyword(s):  
Hydrogen Bonds ◽  
Plasmid Dna ◽  
Self Assembly ◽  
Unique Property ◽  
The Self ◽  
Proteinase K ◽  
Rational Approach ◽  
Proteolytic Resistance ◽  
Soft Biomaterials

As a novel class of biomaterials, nucleopeptides, via the conjugation of nucleobases and peptides, usually self-assemble to form nanofibres driven mainly by hydrogen bonds. Containing nucleobase(s), nucleopeptides have a unique property—interacting with nucleic acids. Here we report the design and characterization of nucleopeptides that self-assemble in water and are able to interact with single-stranded DNAs (ssDNAs). Containing nucleobases on their side chains, these nucleopeptides bind with the ssDNAs, and the ssDNAs reciprocally affect the self-assembly of nucleopeptides. In addition, the interactions between nucleopeptides and ssDNAs also decrease their proteolytic resistance against proteinase K, which further demonstrates the binding with ssDNAs. The nucleopeptides also interact with plasmid DNA and deliver hairpin DNA into cells. This work illustrates a new and rational approach to create soft biomaterials by the integration of nucleobases and peptides to bind with DNA, which may lead to the development of nucleopeptides for controlling DNA in cells.

Dumbbell-shaped dendrimers — Synthesis and self-assembly

2008 ◽  
Vol 86 (6) ◽  
pp. 540-547 ◽  
Author(s):  
Tatiana Vassilieff ◽  
Ashok Kakkar
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Layer By Layer ◽  
Acid Base ◽  
Detailed Characterization ◽  
Generation Number ◽  
Backbone Structure

We report on the synthesis and detailed characterization of dendrimers that evolve symmetrically from a linear core of 2-butyne-1,4-diol with 3,5-dihydroxybenzyl alcohol based dendron arms. The divergent layer-by-layer build-up of the dumbbell-shaped dendrimers is based on simple acid–base hydrolytic chemistry of bis(dimethylamino)dimethylsilane with OH-terminated molecules. The self-assembly of these dendrimers in THF and water is significantly influenced by their generation number, the backbone structure, and the solvent.Key words: dendrimers, divergent synthesis, macromolecules, self-assembly

Design and Characterization of Nanoarchitectures from Multifunctional Polyparaphenylenes

2003 ◽  
Vol 776 ◽  
Author(s):  
Renu Ravindranath ◽  
Suresh Valiyaveettil ◽  
Chinnapan Baskar ◽  
Ananda Putra ◽  
Fitri Fitrilawati ◽  
...  
Keyword(s):  
Thin Films ◽  
Conducting Polymers ◽  
Self Assembly ◽  
The Self ◽  
Morphological Properties ◽  
Synthesis And Characterization ◽  
Solution Properties ◽  
Wide Range ◽  
Modified Surfaces

AbstractConducting polymers are interesting materials due to their wide range of applications in electronics, sensing, photonics and display applications. The present paper delineates the synthesis and characterization of the three functionalized poly (p-phenylene)s (PPP) (A-C) and solution properties of the polymers. The self-assembly of the polymers were investigated on various substrates and the optical/morphological properties of thin films of these polymers were also studied. The spontaneous self assembly of the modified PPP's lead to the formation of thin films on both hydrophilic and modified surfaces.

Balancing Noncovalent Interactions in the Self-Assembly of Nonplanar Aromatic Carboxylic Acid MOF Linkers at the Solution/Solid Interface: HOPG vs Au(111)

Langmuir ◽  
2019 ◽  
Vol 35 (15) ◽  
pp. 5271-5280 ◽  
Author(s):  
Kristen N. Johnson ◽  
Matthew J. Hurlock ◽  
Qiang Zhang ◽  
K. W. Hipps ◽  
Ursula Mazur
Keyword(s):  
Carboxylic Acid ◽  
Self Assembly ◽  
Noncovalent Interactions ◽  
The Self ◽  
Aromatic Carboxylic Acid ◽  
Solid Interface

Characterization Of SnO2 Nanoparticles Deposited Via Layer-by-Layer Self Assembly And Investigation Of Their Sensing Properties

2002 ◽  
Vol 739 ◽  
Author(s):  
R. C. Ghan ◽  
Y. Lvov ◽  
R. S. Besser
Keyword(s):  
Self Assembly ◽  
High Selectivity ◽  
Sno2 Nanoparticles ◽  
Test Chamber ◽  
The Self ◽  
Layer By Layer ◽  
Product Analysis ◽  
Glass Substrates ◽  
Self Assembled

ABSTRACTA technique of Layer-by-Layer (LbL) self-assembly is used to deposit SnO2 nanoparticles on Quartz Crystal Microbalance (QCM) resonators, and on glass substrates which the authors believe has not been previously reported. Characterization of self-assembled SnO2 layers has been performed using QCM, Scanning Electron Microscopy (SEM), and Zeta Potential analysis.We have successfully deposited SnO2 nanoparticles on QCM resonator using self-assembly technique. LbL self-assembly is a method of organization of ultra-thin films by interlayer electrostatic attraction. The thickness and mass of the self-assembled layers can be characterized by the frequency shift obtained using the QCM and empirical equations relating change in frequency with mass and thickness of deposited layers. The deposition of SnO2 nanolayers exhibited a linear reproducibility and the process of self-assembly was independent of the residence time of QCM resonator in the SnO2 nanoparticle colloidal solution. High resolution SEM analysis reveals that the SnO2 nanoparticle layers are uniformly deposited across the entire substrate. Electrical characterization was performed on SnO2 nanoparticle layers self-assembled on glass substrates which were patterned for two point (current-voltage) IV characteristic measurements. Two classes of samples were used. One sample was self-assembled glass substrate patterned with electrical contacts and calcined (baked at 350°C for one hour) to eliminate interlayered polyions and the other sample was not calcined. Results revealed that the calcined samples demonstrated linear ohmic behavior but the uncalcined showed some spurious points which we believe are due to the polyion layers.Characterization of the self-assembled SnO2 nanoparticles is being carried out with the intention of fabricating a high-selectivity μ-gas sensor. A test chamber has been fabricated and results of resistance behavior of the sensor with variation in temperature have been presented.The sensor can find applications in high selectivity sensing of chemical, industrial, domestic, and hazardous environments. After further research and development, this μ-gas sensors could be made generic to sense a variety of gases and employed for integrated on-chip product analysis in multiple chemical microsystem applications.

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