Employing Schiff-base macrocycles to probe the effect of ligand field on the relaxation dynamics of a family of DyIII SMMs

Polyhedron ◽  
2016 ◽  
Vol 108 ◽  
pp. 122-130 ◽  
Author(s):  
Emma L. Gavey ◽  
Melanie Pilkington
Keyword(s):  
Schiff Base ◽  
Ligand Field ◽  
Relaxation Dynamics ◽  
Schiff Base Macrocycles

Carbazole-based N4-donor Schiff base macrocycles: obtained metal free and as Cu(ii) and Ni(ii) complexes

2017 ◽  
Vol 46 (10) ◽  
pp. 3141-3149 ◽  
Author(s):  
Stuart J. Malthus ◽  
Rajni K. Wilson ◽  
A. Vikas Aggarwal ◽  
Scott A. Cameron ◽  
David S. Larsen ◽  
...  
Keyword(s):  
Schiff Base ◽  
Ligand Field ◽  
Metal Free ◽  
Schiff Base Macrocycles

Practical multi-step routes to 1,8-diformylcarbazole head units, and the first examples of Schiff base macrocycles derived from them, are reported. Like porphyrins, both macrocycles are shown to impose a strong ligand field.

Synthesis of homodinuclear lanthanide(III) complexes of 24-membered tetraaza and 34-membered octaaza Schiff base macrocycles

Polyhedron ◽  
1999 ◽  
Vol 18 (24) ◽  
pp. 3123-3128 ◽  
Author(s):  
D.Suresh Kumar ◽  
V.Arul Joseph Aruna ◽  
V. Alexander
Keyword(s):  
Schiff Base ◽  
Schiff Base Macrocycles

scholarly journals Structural studies of Schiff-base [2 + 2] macrocycles derived from 2,2′-oxydianiline and the ROP capability of their organoaluminium complexes

2016 ◽  
Vol 45 (30) ◽  
pp. 11990-12005 ◽  
Author(s):  
Wenxue Yang ◽  
Ke-Qing Zhao ◽  
Timothy J. Prior ◽  
David L. Hughes ◽  
Abdessamad Arbaoui ◽  
...  
Keyword(s):  
Schiff Base ◽  
Structural Studies ◽  
Schiff Base Macrocycles

Structures of [2 + 2] Schiff base macrocycles and aluminium complexes thereof, together with ROP studies using the latter are reported.

Solvent Effects on Nonradiative Relaxation Dynamics of Low-Energy Ligand-Field Excited States: A CuCl42– Complex

2017 ◽  
Vol 121 (17) ◽  
pp. 4562-4568 ◽  
Author(s):  
Andrey S. Mereshchenko ◽  
Olesya S. Myasnikova ◽  
Maxim S. Panov ◽  
Vladimir A. Kochemirovsky ◽  
Mikhail Yu. Skripkin ◽  
...  
Keyword(s):  
Excited States ◽  
Solvent Effects ◽  
Low Energy ◽  
Ligand Field ◽  
Relaxation Dynamics ◽  
Nonradiative Relaxation
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