This work illustrates syntheses, structures, redox and magnetic properties as well as catalase activities of rare μ3-oxo bridged mixed-valent trinuclear MnIIMnIII complexes (1 and 2) and a μ4-oxo bridged tetranuclear MnII4 complex (3) supported with nitrogen donor ligands.
Rhenium tricarbonyl complexes are one of the most important classes of coordination compounds in inorganic chemistry. Exploring their luminescent excited states, lowest singlet (S1), and the lowest triplet (T1), is...