Crystal structure and spin crossover behavior of the [Fe(5-Cl-qsal)2][Ni(dmit)2]·2CH3CN complex

Polyhedron ◽  
2015 ◽  
Vol 85 ◽  
pp. 643-651 ◽  
Author(s):  
Bruno J.C. Vieira ◽  
Joana T. Coutinho ◽  
João C. Dias ◽  
José C. Nunes ◽  
Isabel C. Santos ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Spin Crossover ◽  
Crossover Behavior

Crystal Structure and Spin-crossover Behavior of Iron(III) Complex with Nitroprusside

2013 ◽  
Vol 42 (12) ◽  
pp. 1542-1544 ◽  
Author(s):  
Takahiro Togo ◽  
Saliu Alao Amolegbe ◽  
Ryotaro Yamaguchi ◽  
Takayoshi Kuroda-Sowa ◽  
Manabu Nakaya ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Spin Crossover ◽  
Crossover Behavior

57Fe Mössbauer Spectra, Crystal Structure, and Spin-Crossover Behavior of [Fe(mbpN)(lut)]BPh4

1992 ◽  
Vol 65 (7) ◽  
pp. 1825-1831 ◽  
Author(s):  
Yonezo Maeda ◽  
Yosuke Noda ◽  
Hiroki Oshio ◽  
Yoshimasa Takashima
Keyword(s):  
Crystal Structure ◽  
Mössbauer Spectra ◽  
Spin Crossover ◽  
57Fe Mössbauer ◽  
Mossbauer Spectra ◽  
Crossover Behavior

A five-coordinate iron(III) porphyrin complex including a neutral axial pyridine N-oxide ligand

2019 ◽  
Vol 75 (6) ◽  
pp. 717-722
Author(s):  
Melanie A. Short ◽  
Roger D. Sommer ◽  
Alec J. Falzone ◽  
Tao Huang ◽  
Walter W. Weare ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Bond Length ◽  
Spin Crossover ◽  
Bond Angle ◽  
Organic Ligand ◽  
Binding Mode ◽  
Porphyrin Complex ◽  
Axial Ligands ◽  
Crossover Behavior ◽  
Porphyrin Core

While six-coordinate iron(III) porphyrin complexes with pyridine N-oxides as axial ligands have been studied as they exhibit rare spin-crossover behavior, studies of five-coordinate iron(III) porphyrin complexes including neutral axial ligands are rare. A five-coordinate pyridine N-oxide–5,10,15,20-tetraphenylporphyrinate–iron(III) complex, namely (pyridine N-oxide-κO)(5,10,15,20-tetraphenylporphinato-κ4 N,N′,N′′,N′′′)iron(III) hexafluoroantimonate(V) dichloromethane disolvate, [Fe(C44H28N4)(C5H5NO)][SbF6]·2CH2Cl2, was isolated and its crystal structure determined in the space group P\overline{1}. The porphyrin core is moderately saddled and the Fe—O—N bond angle is 122.08 (13)°. The average Fe—N bond length is 2.03 Å and the Fe—ONC5H5 bond length is 1.9500 (14) Å. This complex provides a rare example of a five-coordinate iron(III) porphyrin complex that is coordinated to a neutral organic ligand through an O-monodentate binding mode.

Effect of metal dilution on the spin-crossover behavior in [FexM1-x(phen)2(NCS)2] (M = Mn, Co, Ni, Zn)

1982 ◽  
Vol 21 (9) ◽  
pp. 3429-3433 ◽  
Author(s):  
P. Ganguli ◽  
P. Guetlich ◽  
E. W. Mueller
Keyword(s):  
Spin Crossover ◽  
Crossover Behavior

Modification of Spin Crossover Behavior through Solvent Assisted Formation and Solvent Inclusion in a Triply Interpenetrating Three-Dimensional Network

2007 ◽  
Vol 46 (10) ◽  
pp. 4220-4229 ◽  
Author(s):  
Matthias Bartel ◽  
Alina Absmeier ◽  
Guy N. L. Jameson ◽  
Franz Werner ◽  
Kenichi Kato ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Three Dimensional ◽  
Dimensional Network ◽  
Crossover Behavior

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks

2009 ◽  
Vol 48 (8) ◽  
pp. 3371-3381 ◽  
Author(s):  
Gloria Agustí ◽  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
José A. Real
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crossover Behavior ◽  
Metal Organic

Reversible on-off switching of spin-crossover behavior via photochemical [2+2] cycloaddition reaction

2021 ◽  
Author(s):  
Long-Fei Wang ◽  
Bang-Heng Lv ◽  
Feng-Tai Wu ◽  
Guo-Zhang Huang ◽  
Ze-Yu Ruan ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Cycloaddition Reaction ◽  
Crossover Behavior

[FeIII(bztpen)(OCH3)](PF6)2: Stable Methoxide-Iron(III) Complex Exhibiting Spin Crossover Behavior in the Solid State

2010 ◽  
Vol 2010 (35) ◽  
pp. 5563-5567 ◽  
Author(s):  
Norma A. Ortega-Villar ◽  
M. Carmen Muñoz ◽  
José A. Real
Keyword(s):  
Solid State ◽  
Spin Crossover ◽  
Crossover Behavior

scholarly journals Crystal Structures and Spin-Crossover Behavior of Iron(II) Complexes with Chiral and Racemic Ligands

2017 ◽  
Vol 2017 (7) ◽  
pp. 1048-1048 ◽  
Author(s):  
Yusuke Sekimoto ◽  
Mohammad Razaul Karim ◽  
Naoto Saigo ◽  
Ryo Ohtani ◽  
Masaaki Nakamura ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Spin Crossover ◽  
Crossover Behavior
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