Synthesis, crystal structure and magnetic properties of one-dimensional coordination polymers

Polyhedron ◽  
2014 ◽  
Vol 81 ◽  
pp. 668-674 ◽  
Author(s):  
Q.R. Cheng ◽  
H. Zhou ◽  
Z.Q. Pan ◽  
G.Y. Liao ◽  
Z.G. Xu
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Coordination Polymers ◽  
One Dimensional

scholarly journals Heterobimetallic One-Dimensional Coordination Polymers MICuII (M = Li and K) Based on Ferromagnetically Coupled Di- and Tetracopper(II) Metallacyclophanes

2018 ◽  
Vol 4 (3) ◽  
pp. 38 ◽  
Author(s):  
Tamyris T. da Cunha ◽  
Willian X. C. Oliveira ◽  
Emerson F. Pedroso ◽  
Francesc Lloret ◽  
Miguel Julve ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Coordination Polymers ◽  
Complex Anion ◽  
Spin Hamiltonian ◽  
One Dimensional ◽  
Carboxylate Oxygen ◽  
Out Of Plane ◽  
Ferromagnetic Interactions ◽  
Oxygen Atoms

The synthesis, crystal structure and magnetic properties of the coordination polymers of formula [EDAP{Li6(H2O)8[(Cu2(μ-mpba)2)2(H2O)2]}]n (1) and [(EDAP)2{K(H2O)4[Cu2(μ-mpba)2(H2O)2]}Cl·2H2O]n (2), in which mpba = N,N′-1,3-phenylenebis(oxamate) and EDAP2+ = 1,1′-ethylenebis(4-aminopyridinium) are described. Both compounds have in common the presence of the [Cu2(mpba)2]4− tetraanionic unit which is a [3,3] metallacyclophane motif in which the copper(II) ions are five-coordinate in a distorted square pyramidal surrounding. The complex anion in 1 is dimerized through double out-of-plane copper to outer carboxylate-oxygen atoms resulting in the centrosymmetric tetracopper(II) fragment [Cu4(μ-mpba)4(H2O)2]8− which act as a ligand toward six hydrated lithium(I) cations leading to anionic ladder-like double chains whose charge is neutralized by the EDAP2+ cations. In the case of 2, each dicopper(II) entity acts as a ligand towards tetraquapotassium(I) units to afford anionic zig zag single chains of formula {K(H2O)4[Cu2(μ-mpba)2(H2O)2]}n3n− plus EDAP2+ cations and non-coordinate chloride anions. Cryomagnetic measurements on polycrystalline samples 1 and 2 show the occurrence of ferromagnetic interactions between the copper(II) ions across the –Namidate–(C–C–C)phenyl–Namidate– exchange pathway [J = +10.6 (1) and +8.22 cm−1 (2)] and antiferromagnetic ones through the double out-of-plane carboxylate-oxygen atoms [j = −0.68 cm−1 (1), the spin Hamiltonian being defined as H = − J ( S C u 1 · S C u 2 + S C u 2 i · S C u 1 i ) − j ( S C u 2 · S C u 2 i ) ].

Two new one-dimensional coordination polymers containing [N(CN)2]– — Syntheses, structures, and magnetic properties of [MII(3- Bzpy)2(N(CN)2)2] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine)

2012 ◽  
Vol 90 (4) ◽  
pp. 362-367
Author(s):  
Qianqian Bao ◽  
Yutao Ma ◽  
Qihua Zhao ◽  
Yanghui Luo ◽  
Baiwang Sun
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Metal Ions ◽  
Coordination Polymers ◽  
Magnetic Measurements ◽  
Coordination Complexes ◽  
Space Group ◽  
One Dimensional

The structures of two one-dimensional coordination complexes, [MII(3-Bzpy)2(N(CN)2)2] (M = Mn (1) and Co (2) and 3-Bzpy = 3-benzoylpyridine), have been determined in this work. The two structures are isomorphous, crystallize in a monoclinic P21/c space group, and show almost the same crystal structure. The magnetic measurements of the two compounds (2–300 K) indicate that antiferromagnetic exchanges exist between the metal ions of the two compounds.

Synthesis, structures, and magnetic properties of one-dimensional Fe–M (M=NiII, CuII) coordination polymers bridged by nitroprusside

2007 ◽  
Vol 360 (8) ◽  
pp. 2523-2531 ◽  
Author(s):  
Young Sin You ◽  
Jung Hee Yoon ◽  
Jeong Hak Lim ◽  
Hyoung Chan Kim ◽  
Chang Seop Hong
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
One Dimensional

Crystal structure and magnetic properties of the S =1 quasi one-dimensional ferromagnet [(CH3)3NH]NiCl3⋯2H2O

Physica B+C ◽  
1984 ◽  
Vol 125 (2) ◽  
pp. 135-149 ◽  
Author(s):  
R. Hoogerbeets ◽  
S.A.J. Wiegers ◽  
A.J. Van Duyneveldt ◽  
R.D. Willett ◽  
U. Geiser
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
One Dimensional

Synthesis, structural characterization and magnetic properties of one-dimensional Cu(II)-azido coordination polymers

Polyhedron ◽  
2017 ◽  
Vol 138 ◽  
pp. 177-184 ◽  
Author(s):  
Febee R. Louka ◽  
Salah S. Massoud ◽  
Tamim K. Haq ◽  
Masayuki Koikawa ◽  
Masahiro Mikuriya ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Structural Characterization ◽  
One Dimensional

A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties

2007 ◽  
Vol 180 (10) ◽  
pp. 2973-2977 ◽  
Author(s):  
Wei Li ◽  
Zongwei Li ◽  
Licun Li ◽  
Daizheng Liao ◽  
Zonghui Jiang
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Schiff Base ◽  
One Dimensional
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