The series of carbon-chain complexes {Ru(dppe)Cp∗}2{μ-(C C) } (x= 4–8, 11): Synthesis, structures, properties and some reactions

Polyhedron ◽  
2015 ◽  
Vol 86 ◽  
pp. 43-56 ◽  
Author(s):  
Michael I. Bruce ◽  
Marcus L. Cole ◽  
Benjamin G. Ellis ◽  
Maryka Gaudio ◽  
Brian K. Nicholson ◽  
...  
Keyword(s):  
Carbon Chain ◽  
Chain Complexes

Synthesis and redox chemistry of cycloheptatrienyl molybdenum carbon-chain complexes featuring diimine support ligands: [Mo{(CC)nCCR}(R′NCH–CHNR′)(η-C7H7)], (n = 0 or 1)

2013 ◽  
Vol 745-746 ◽  
pp. 251-257 ◽  
Author(s):  
Huriyyah A. Alturaifi ◽  
James Faulkner ◽  
James Raftery ◽  
Floriana Tuna ◽  
David Collison ◽  
...  
Keyword(s):  
Redox Chemistry ◽  
Carbon Chain ◽  
Chain Complexes

Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+:  Computational Analyses of the Effect of the Metal

2003 ◽  
Vol 125 (31) ◽  
pp. 9511-9522 ◽  
Author(s):  
Haijun Jiao ◽  
Karine Costuas ◽  
John A. Gladysz ◽  
Jean-François Halet ◽  
Maud Guillemot ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Carbon Chain ◽  
Chain Complexes ◽  
Computational Analyses

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

TRIGLYCERIDE COMPOSITION OF SIXTEEN STRAINS OF MARINE DIATOM

2013 ◽  
Vol 5 (1) ◽  
Author(s):  
Lily M.G. Panggabean ◽  
Abdullah Rasyid ◽  
Zarrah Duniani ◽  
Yana Meliana ◽  
Indah Kurniasih
Keyword(s):  
Mass Spectrometry ◽  
Fatty Acid ◽  
Double Bond ◽  
Unsaturated Fatty Acid ◽  
Ion Trap ◽  
Carbon Chain ◽  
Highly Unsaturated Fatty Acid ◽  
Marine Diatom ◽  
Ion Trap Mass Spectrometry ◽  
Spectra Analysis

Trigliceride or triacylglicerol (TAG) composition in crude oil of sixteen strain of marine diatom has been detected by spectra analyses on an Electrospray - Ion Trap – Mass Spectrometry (ESI-IT-MS) HCT Bruker-Daltonic GmbH instrument with AgNO3 used as coordination ionization agent. Biomass samples of each microalga strain were taken from early and late stationary cultures in f/2 enriched seawater and algal oils were extracted according to Bligh and Dyer. Results from spectra analysis showed that P-Pt-P (C16:0-C16:1-C16:0) were distinguished in TAG from diatom strains Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.1, Thalasiossira sp.2, Thalasiossira sp.3, Navicula sp. 1, Navicula sp. 2, Navicula sp. 3, Navicula sp. 4, Nitzschia sp. 2 and Amphora sp. In contrast, TAGs in Melosira sp. included P-P-P (C16:0-C16:0-C16:0) and P-P-O (C16:0-C16:0-C18:1) were identified. TAGs from Chaetoceros sp. were the most varies among samples, i.e. P-Pt-P (C16:0-C16:1-C16:0), A-P-M (C20:4-C16:0-C14:0), P-Pt-Lt (C16:0-C16:1-C18:3), P-Pt-A (C16:0-C16:1-C20:4), D-P-P (C22:6-C16:0-C16:0), A-Ln-P (C20:4-C18:2-C16:0). Various TAGs were also detected in Nitzschia sp.2, i.e. P-Pt-M (C16:0-C16:1-C14:0), P-Pt-P (C16:0-C16:1-C16:0), P-Pt-S (C16:0-C16:1-C18:0), P-Pt-A (C16:0-C16:1-C20:4). TAGs composition in Skeletonema strains that similar to those in Nitzschia sp.1 has longer carbon, i.e. P-P-O (C16:0-C16:0-C18:1), P-O-O (C16:0-C18:1-C18:1) and O-O-O (C18:1-C18:1-C18:1). TAGs with longer carbon chain and more double bond including highly unsaturated fatty acid C20:4 were increased with culture age in diatoms Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.2, Navicula sp.1 and Nitzschia sp. 2.Keywords: diatom, TAG, ESI-IT-MS, f/2, early and late stationary

Laboratory Detection of a New Carbon Chain Radical: H2CCCCN

1998 ◽  
Vol 492 (2) ◽  
pp. 849-853 ◽  
Author(s):  
Wei Chen ◽  
M. C. McCarthy ◽  
M. J. Travers ◽  
E. W. Gottlieb ◽  
Michaeleen R. Munrow ◽  
...  
Keyword(s):  
Carbon Chain

scholarly journals ON THE ORIGIN OF THE CARBON CHAIN OF CYSTEINE IN THE RAT

1950 ◽  
Vol 185 (1) ◽  
pp. 271-274
Author(s):  
Jakob A. Stekol ◽  
Kathryn. Weiss ◽  
Sidney. Weiss
Keyword(s):  
Carbon Chain

Ionic liquid-biosurfactant blends as effective dispersants for oil spills: Effect of carbon chain length and degree of saturation

2021 ◽  
pp. 117119
Author(s):  
Mansoor Ul Hassan Shah ◽  
Ambavaram Vijaya Bhaskar Reddy ◽  
Suzana Yusup ◽  
Masahiro Goto ◽  
Muhammad Moniruzzaman
Keyword(s):  
Ionic Liquid ◽  
Chain Length ◽  
Oil Spills ◽  
Carbon Chain ◽  
Degree Of Saturation ◽  
Carbon Chain Length

scholarly journals Activity of the first interstellar comet 2I/Borisov around perihelion: results from Indian observatories

2021 ◽  
Vol 502 (3) ◽  
pp. 3491-3499
Author(s):  
K Aravind ◽  
Shashikiran Ganesh ◽  
Kumar Venkataramani ◽  
Devendra Sahu ◽  
Dorje Angchuk ◽  
...  
Keyword(s):  
Solar System ◽  
Production Rate ◽  
Rate Ratio ◽  
Carbon Chain ◽  
Astronomical Observatory ◽  
Nucleus Size ◽  
Chain Molecules ◽  
Molecular Emission ◽  
Imaging And Spectroscopy ◽  
Gas Ratio

ABSTRACT Comet 2I/Borisov is the first true interstellar comet discovered. Here, we present results from observational programs at two Indian observatories, 2 m Himalayan Chandra Telescope at the Indian Astronomical Observatory, Hanle (HCT) and 1.2 m telescope at the Mount Abu Infrared Observatory (MIRO). Two epochs of imaging and spectroscopy were carried out at the HCT and three epochs of imaging at MIRO. We found CN to be the dominant molecular emission on both epochs, 2019 November 30 and December 22, at distances of rH = 2.013 and 2.031 au, respectively. The comet was inferred to be relatively depleted in Carbon bearing molecules on the basis of low C2 and C3 abundances. We find the production rate ratio, Q(C2)/Q(CN) = 0.54 ± 0.18, pre-perihelion and Q(C2)/Q(CN) = 0.34 ± 0.12 post-perihelion. This classifies the comet as being moderately depleted in carbon chain molecules. Using the results from spectroscopic observations, we believe the comet to have a chemically heterogeneous surface having variation in abundance of carbon chain molecules. From imaging observations, we infer a dust-to-gas ratio similar to carbon chain depleted comets of the Solar system. We also compute the nucleus size to be in the range 0.18 km ≤ r ≤ 3.1 km. Our observations show that 2I/Borisov’s behaviour is analogous to that of the Solar system comets.

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