Synthesis and structural characterization of novel three carbon atom bridged ansa-bis(indenyl)zirconocene complexes: Applications in ethylene polymerization

Polyhedron ◽  
2014 ◽  
Vol 80 ◽  
pp. 129-133 ◽  
Author(s):  
Dorian Polo-Cerón ◽  
Santiago Gómez-Ruiz ◽  
Jesús Ceballos-Torres ◽  
Sanjiv Prashar ◽  
Mariano Fajardo ◽  
...  
2018 ◽  
Vol 42 (2) ◽  
pp. 1477-1483 ◽  
Author(s):  
A. C. Pinheiro ◽  
S. M. da Silva ◽  
T. Roisnel ◽  
E. Kirillov ◽  
J.-F. Carpentier ◽  
...  

Zirconium complexes supported by pyrrolide-imino ligands been synthesized and their catalytic behavior in ethylene polymerization has been investigated.


2021 ◽  
Author(s):  
H.D.A. Chathumal Jayaweera ◽  
Md. Mamdudur Rahman ◽  
Perry J. Pellechia ◽  
Mark D. Smith ◽  
Dmitry V. Peryshkov

Carbon atom functionalization via generation of carbanions is the cornerstone of carborane chemistry. In this work, we report the synthesis and structural characterization of free ortho-carboranyl [C2B10H11]−, a three-dimensional inorganic...


2015 ◽  
Vol 44 (19) ◽  
pp. 9091-9102 ◽  
Author(s):  
Tapas Guchhait ◽  
Bhagyasree Barua ◽  
Aritra Biswas ◽  
Biswanath Basak ◽  
Ganesan Mani

A striking difference in the structures of silver complexes was observed because of the different substituents at the meso carbon atom of the dipyrrolylmethane-based ligand.


Author(s):  
S. F. Hayes ◽  
M. D. Corwin ◽  
T. G. Schwan ◽  
D. W. Dorward ◽  
W. Burgdorfer

Characterization of Borrelia burgdorferi strains by means of negative staining EM has become an integral part of many studies related to the biology of the Lyme disease organism. However, relying solely upon negative staining to compare new isolates with prototype B31 or other borreliae is often unsatisfactory. To obtain more satisfactory results, we have relied upon a correlative approach encompassing a variety EM techniques, i.e., scanning for topographical features and cryotomy, negative staining and thin sectioning to provide a more complete structural characterization of B. burgdorferi.For characterization, isolates of B. burgdorferi were cultured in BSK II media from which they were removed by low speed centrifugation. The sedimented borrelia were carefully resuspended in stabilizing buffer so as to preserve their features for scanning and negative staining. Alternatively, others were prepared for conventional thin sectioning and for cryotomy using modified procedures. For thin sectioning, the fixative described by Ito, et al.


2011 ◽  
Vol 44 (06) ◽  
Author(s):  
A Bracher ◽  
C Kozany ◽  
AK Thost ◽  
F Hausch

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