Influence of particle size on the phase behavior associated with the thermal spin transition of the Prussian blue analogue K0.4Co1.3[Fe(CN)6]·4.4H2O

Polyhedron ◽  
2013 ◽  
Vol 64 ◽  
pp. 289-293 ◽  
Author(s):  
Matthew J. Andrus ◽  
Yitzi M. Calm ◽  
Elisabeth S. Knowles ◽  
Matthieu F. Dumont ◽  
Khalil A. Abboud ◽  
...  
Keyword(s):  
Particle Size ◽  
Phase Behavior ◽  
Prussian Blue ◽  
Spin Transition ◽  
Prussian Blue Analogue

scholarly journals Charge transfer driven by ultrafast spin transition in a CoFe Prussian blue analogue

2020 ◽  
Vol 13 (1) ◽  
pp. 10-14
Author(s):  
Marco Cammarata ◽  
Serhane Zerdane ◽  
Lodovico Balducci ◽  
Giovanni Azzolina ◽  
Sandra Mazerat ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Prussian Blue ◽  
Spin Transition ◽  
Prussian Blue Analogue

scholarly journals Preparation of Prussian Blue Analogue Ce[Co(CN)6]·nH2O Nanoparticles

2021 ◽  
Vol 3 (6) ◽  
pp. 1-6
Author(s):  
Yajie Guo
Keyword(s):  
Particle Size ◽  
Prussian Blue ◽  
High Efficiency ◽  
Preparation Method ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Prussian Blue Analogue ◽  
Simple Preparation ◽  
Metal Organic ◽  
First Time

Prussian blue analogue Ce[Co(CN)6]·nH2O nanoparticles were prepared by water bath coprecipitation for the first time. The effects of reaction parameters on the morphology and particle size of the synthesized products were revealed by controlling the variable method. The synthetic product has the characteristics of simple preparation method, low cost, small particle size and MOF (Metal organic framework). The cerium and cobalt elements contained in it are common catalytic active elements, which provides ideas and reference for the design and preparation of high-efficiency and low-cost catalysts.

High-temperature Electron transfer Coupled Spin Transition (ETCST) with Hysteresis in a Discrete [Fe2Co2] Prussian Blue Analogue

2021 ◽  
Author(s):  
Jyoti Yadav ◽  
Dibya Jyoti Mondal ◽  
Sanjit Konar
Keyword(s):  
Electron Transfer ◽  
High Temperature ◽  
Prussian Blue ◽  
General Formula ◽  
Spin Transition ◽  
Prussian Blue Analogue ◽  
Temperature Electron

A thermoresponsive Fe-Co based discrete Prussian Blue Analogue (PBA) with general formula [Fe(Tp)(CN)3]2[Co{en(Bn)py}]2(ClO4)2 •4MeOH•4H2O i.e. [1•4MeOH•4H2O] is reported, which discloses a sharp and high temperature ETCST along with the wide...

Interplay between core and shell in a RbCoFe@RbNiCo Prussian blue analogue spin transition heterostructure

2021 ◽  
Author(s):  
Wanhong He ◽  
John M. Cain ◽  
Mark W. Meisel ◽  
Daniel R. Talham
Keyword(s):  
Prussian Blue ◽  
Spin Transition ◽  
Core Shell ◽  
Prussian Blue Analogue ◽  
Shell Particles ◽  
Spin Transitions

Core–shell particles with a Prussian blue analogue RbaCob[Fe(CN)6]c·mH2O core and different shell thicknesses are studied as the cores undergo both thermal and light-induced spin transitions, revealing different mechanisms for accommodating strain.

scholarly journals Collective Magnetic Behavior of 11 nm Photo-Switchable CsCoFe Prussian Blue Analogue Nanocrystals: Effect of Dilution and Light Intensity

2021 ◽  
Vol 7 (7) ◽  
pp. 99
Author(s):  
Linh Trinh ◽  
Eric Rivière ◽  
Sandra Mazerat ◽  
Laure Catala ◽  
Talal Mallah
Keyword(s):  
Magnetic Susceptibility ◽  
Light Intensity ◽  
Prussian Blue ◽  
Magnetic Behavior ◽  
Magnetic Interaction ◽  
Light Irradiation ◽  
Prussian Blue Analogue ◽  
Magnetic Susceptibility Data ◽  
Susceptibility Data

The collective magnetic behavior of photoswitchable 11 nm cyanide-bridged nanoparticles based of the Prussian blue analogue CsCoFe were investigated when embedded in two different matrices with different concentrations. The effect of the intensity of light irradiation was studied in the less concentrated sample. Magnetization studies and alternating magnetic susceptibility data are consistent with a collective magnetic behavior due to interparticle dipolar magnetic interaction for the two compounds, even though the objects have a size that place them in the superparamagnetic regime.

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