Synthesis, crystal structure, spectral properties and catalytic activity of a binuclear copper(II) complex containing a Schiff base ligand

Polyhedron ◽  
2013 ◽  
Vol 59 ◽  
pp. 23-28 ◽  
Author(s):  
Poulami Pattanayak ◽  
Jahar Lal Pratihar ◽  
Debprasad Patra ◽  
Paula Brandão ◽  
Dasarath Mal ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Catalytic Activity ◽  
Schiff Base Ligand ◽  
Spectral Properties ◽  
Binuclear Copper

Synthesis, crystal structure and magnetic properties of a new oxalato-bridged binuclear copper(II) complex with a tridentate Schiff base ligand

Polyhedron ◽  
2001 ◽  
Vol 20 (17) ◽  
pp. 2113-2116 ◽  
Author(s):  
Bappaditya Bag ◽  
Nijhuma Mondal ◽  
Samiran Mitra ◽  
Volker Gramlich ◽  
Joan Ribas ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Binuclear Copper ◽  
Tridentate Schiff Base

Crystal Structure of a Binuclear Copper(II) Complex with μ-Alkoxo and μ-Pyridonato Bridges. Effect of the Dihedral Angle on the Superexchange Interaction

1989 ◽  
Vol 44 (3) ◽  
pp. 307-311 ◽  
Author(s):  
Yuzo Nishida ◽  
Miyuki Masumoto ◽  
Yutaka Mori
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Dihedral Angle ◽  
Schiff Base Ligand ◽  
Superexchange Interaction ◽  
X Ray Diffraction ◽  
Binuclear Copper ◽  
Ferromagnetic Interaction ◽  
X Ray

The crystal structure of the binuclear copper(II) complex. [Cu2(L)(2-pyridonato)] was determined by X-ray diffraction, where H3(L) represents the Schiff base ligand derived from 1,3-diaminopropane-2-ol and acetylacetone. Two copper(II) ions are bridged by alkoxide and 2-pyridonate groups with a Cu-Cu separation of 3.249(2) Å . Ferromagnetic interaction is found to be operating in this complex, which is attributed to the small dihedral angle (121°) between the two planes containing the copper(II) ion.

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