Four cadmium(II) coordination polymers with an N- and O-donor ligand: Structural characterization, in situ reaction and fluorescent property

Polyhedron ◽  
2013 ◽  
Vol 53 ◽  
pp. 113-121 ◽  
Author(s):  
Hai-Wei Kuai ◽  
Xiao-Chun Cheng ◽  
Xiao-Hong Zhu
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization ◽  
Fluorescent Property ◽  
Donor Ligand ◽  
In Situ Reaction

Four unexpected lanthanide coordination polymers involving in situ reaction of solvent N, N-Dimethylformamide

2015 ◽  
Vol 225 ◽  
pp. 216-221 ◽  
Author(s):  
Jun-Cheng Jin ◽  
Wen-Quan Tong ◽  
Ai-Yun Fu ◽  
Cheng-Gen Xie ◽  
Wen-Gui Chang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
In Situ Reaction ◽  
Lanthanide Coordination Polymers

Three ZnII Coordination Polymers Based on 1,2-Naphthalenedicarboxylate and Different 4,4′-Bipyridyl-like Bridging Co-ligands: Structural Regulation and Properties

2015 ◽  
Vol 68 (1) ◽  
pp. 113
Author(s):  
Min Chen ◽  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Chun-Sen Liu
Keyword(s):  
Hydrogen Bonding ◽  
Thermal Properties ◽  
Coordination Polymers ◽  
Stacking Interactions ◽  
In Situ Reaction ◽  
Aromatic Stacking ◽  
Hydrogen Bonding Interactions ◽  
Structural Regulation

Three new ZnII coordination polymers, namely [Zn(ndc)]n (1), {[Zn(ndc)(bpe)]·1.25H2O}n (2), and {[Zn(ndc)(bpee)]·1.25H2O}n (3), were prepared based on in situ reaction of 1,2-naphthalenedicarboxylic anhydride (ndca) with two different 4,4′-bipyridyl-like bridging co-ligands, bpe and bpee (ndc = 1,2-naphthalenedicarboxylate, bpe = 1,2-bis(4-pyridyl)ethane, and bpee = trans-1,2-bis(4-pyridyl)ethylene). In 1, the ZnII and ndc ligands are directly involved in the polymeric frameworks, forming a 2D (43.63) layered network. Complexes 2 and 3 similarly consist of Zn2(ndc)2 binuclear units that are linked by bpe and bpee ligands, respectively, into a 2D (44.62) sheet. However, further analysis indicates that 2 and 3 feature the similar 2-fold interpenetrating structure linked via hydrogen bonding interactions for 2 and aromatic stacking interactions for 3. In addition, the resultant 2D→3D supramolecular frameworks of 2 and 3 are both constructed via aromatic stacking interactions. Also, the fluorescent and thermal properties of the complexes were investigated.

New Zn2+ coordination polymers constructed from acylhydrazidate molecules: synthesis and structural characterization

2014 ◽  
Vol 43 (41) ◽  
pp. 15617-15627 ◽  
Author(s):  
Yan-Ning Wang ◽  
Guang-Hua Li ◽  
Fu-Quan Bai ◽  
Jie-Hui Yu ◽  
Ji-Qing Xu
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization

Two types of hydrothermal in situ ligand reactions were employed to obtain three new acylhydrazidate-extended Zn2+ coordination polymers.

Magnetic relaxation in two chain-like Zn2Dy2 Schiff base coordination polymers bridged by tetraoxolene and its one-electron reduced radical

2021 ◽  
Author(s):  
Cai-Ming Liu ◽  
Xiang Hao
Keyword(s):  
Schiff Base ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Magnetic Relaxation ◽  
One Dimensional ◽  
In Situ Reaction ◽  
Electron Reduction

In the process of solvothermal synthesis of one-dimensional (1D) Zn-Dy Schiff base coordination polymers, 25% of tetraoxolene anions (X2tetraox2−) underwent a one-electron reduction in situ reaction to form X2tetraox3•− radical...

Controlled in situ reaction for the assembly of Cu(ii) mixed-ligand coordination polymers: synthesis, structure, mechanistic insights, magnetism and catalysis

2015 ◽  
Vol 44 (24) ◽  
pp. 11013-11020 ◽  
Author(s):  
Xing-Po Wang ◽  
Ya-Qin Zhao ◽  
Zvonko Jagličić ◽  
Su-Na Wang ◽  
Shu-Jie Lin ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Nucleophilic Addition ◽  
Addition Reaction ◽  
Mixed Ligand ◽  
In Situ Reaction ◽  
Nucleophilic Addition Reaction ◽  
Ligand Coordination ◽  
One Step ◽  
The One

Controlled in situ nucleophilic addition reaction results in two Cu(ii) mixed-ligand coordination polymers, and the one-step nucleophilic addition for in situ reaction is proposed.

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