Different dimensional and structural variations in coordination polymers of d10 metal ions constructed from a benzimidazole based carboxylate linker

Polyhedron ◽  
2013 ◽  
Vol 50 (1) ◽  
pp. 22-30 ◽  
Author(s):  
Rupali Mishra ◽  
Musheer Ahmad ◽  
Madhav Ram Tripathi
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
Structural Variations ◽  
D10 Metal

Two coordination polymers based on 2,2′-biimidazoles and d10 metal ions: syntheses, structures, and luminescence

2011 ◽  
Vol 64 (16) ◽  
pp. 2912-2922 ◽  
Author(s):  
Li-Ning Yang ◽  
Yan-Xiang Zhi ◽  
Jia-Hui Hei ◽  
Jun Li ◽  
Feng-Xing Zhang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
D10 Metal

Using alkaline-earth metal ions to tune structural variations of 1,3,5-benzenetricarboxylate coordination polymers

2013 ◽  
Vol 42 (6) ◽  
pp. 2294-2301 ◽  
Author(s):  
Xin Zhang ◽  
Yuan-Yuan Huang ◽  
Qi-Pu Lin ◽  
Jian Zhang ◽  
Yuan-Gen Yao
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Structural Variations ◽  
Alkaline Earth Metal Ions

Flexible coordination polymers based on zwitterion ligands and d10 metal ions for selective sensing of nitrobenzene, Fe3+ and HSO4−

2018 ◽  
Vol 98 ◽  
pp. 80-86 ◽  
Author(s):  
Xiao Wang ◽  
Jing Feng ◽  
Yi-Dan Zhao ◽  
Xiao-Feng Zhang ◽  
Tong Yan ◽  
...  
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
D10 Metal

Metal-organic Nanopharmaceuticals

2020 ◽  
Vol 8 (3) ◽  
pp. 163-190
Author(s):  
Benjamin Steinborn ◽  
Ulrich Lächelt
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
Active Agent ◽  
Lewis Base ◽  
High Loading ◽  
Active Components ◽  
Base Functions ◽  
Metal Organic ◽  
Theranostic Applications ◽  
Pharmacologically Active

: Coordinative interactions between multivalent metal ions and drug derivatives with Lewis base functions give rise to nanoscale coordination polymers (NCPs) as delivery systems. As the pharmacologically active agent constitutes a main building block of the nanomaterial, the resulting drug loadings are typically very high. By additionally selecting metal ions with favorable pharmacological or physicochemical properties, the obtained NCPs are predominantly composed of active components which serve individual purposes, such as pharmacotherapy, photosensitization, multimodal imaging, chemodynamic therapy or radiosensitization. By this approach, the assembly of drug molecules into NCPs modulates pharmacokinetics, combines pharmacological drug action with specific characteristics of metal components and provides a strategy to generate tailorable multifunctional nanoparticles. This article reviews different applications and recent examples of such highly functional nanopharmaceuticals with a high ‘material economy’. : Lay Summary: Nanoparticles, that are small enough to circulate in the bloodstream and can carry cargo molecules, such as drugs, imaging or contrast agents, are attractive materials for pharmaceutical applications. A high loading capacity is a generally aspired parameter of nanopharmaceuticals to minimize patient exposure to unnecessary nanomaterial. Pharmaceutical agents containing Lewis base functions in their molecular structure can directly be assembled into metal-organic nanopharmaceuticals by coordinative interaction with metal ions. Such coordination polymers generally feature extraordinarily high loading capacities and the flexibility to encapsulate different agents for a simultaneous delivery in combination therapy or ‘theranostic’ applications.

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