Synthesis, structures, and magnetic properties of iron(II) complexes, [FeII(HLMe)2](ClO4)2 and its ethanol adduct [FeII(HLMe)2](ClO4)2·EtOH (HLMe=2-methylimidazol-4-yl-methylideneamino-2-ethylpyridine): Their structural distortion and spin states

Polyhedron ◽  
2012 ◽  
Vol 48 (1) ◽  
pp. 110-116 ◽  
Author(s):  
Hiroaki Hagiwara ◽  
Suguru Yamauchi ◽  
Naohide Matsumoto ◽  
Yukinari Sunatsuki
2016 ◽  
Vol 683 ◽  
pp. 495-500 ◽  
Author(s):  
M. Niyaifar ◽  
H. Mohammadpour ◽  
A. Behmanesh

2014 ◽  
Vol 104 (2) ◽  
pp. 022407 ◽  
Author(s):  
J. Y. Yu ◽  
K. Huang ◽  
H. Y. Wu ◽  
Y. Feng ◽  
L. Wang ◽  
...  

1998 ◽  
Vol 37 (20) ◽  
pp. 5102-5108 ◽  
Author(s):  
Rita Hernández-Molina ◽  
Alfredo Mederos ◽  
Sixto Dominguez ◽  
Pedro Gili ◽  
Catalina Ruiz-Pérez ◽  
...  

2006 ◽  
Vol 18 (12) ◽  
pp. 2855-2866 ◽  
Author(s):  
Edmund J. Cussen ◽  
Danny R. Lynham ◽  
Joseph Rogers

2014 ◽  
Vol 70 (a1) ◽  
pp. C1231-C1231
Author(s):  
Stuart Batten

We have synthesised large (2.7 nm) spherical metallosupramolecules (`nanoballs') with interesting properties [1-3]. Metal ions can be varied with retention of overall structure and crystal packing. The molecular packing creates cavities within the solid state, and the crystals readily absorb solvents such as methanol, acetonitrile or acetone (which also changes the magnetic properties), and absorb significant amounts of hydrogen and carbon dioxide (but not methane), pointing to a new class of porous materials. Other properties include switching between two magnetic spin states (spin crossover) upon change in temperature or irradiation of light, and size-selective catalysis. New packing arrangements of the nanoballs can then be achieved through variation of the counteranions or nitrile solvent, leading to new phases with different physical properties.


2016 ◽  
Vol 688 ◽  
pp. 357-362 ◽  
Author(s):  
M. Niyaifar ◽  
H. Mohammadpour ◽  
N. Khalafi

ChemInform ◽  
2006 ◽  
Vol 37 (34) ◽  
Author(s):  
Edmund J. Cussen ◽  
Danny R. Lynham ◽  
Joseph Rogers

ChemInform ◽  
2008 ◽  
Vol 39 (42) ◽  
Author(s):  
Michael W. Lufaso ◽  
William R. Gemmill ◽  
Samuel J. III Mugavero ◽  
Seung-Joo Kim ◽  
Yongjae Lee ◽  
...  

2018 ◽  
Author(s):  
Yoji Horii ◽  
Yuki Kanegae ◽  
Kiyonori Takahashi ◽  
Akira Fuyuhiro ◽  
Hal Suzuki ◽  
...  

<div>Two crystal polymorphs of Ni(cyclam)I<sub>2</sub> (cyclam = 1,4,8,11-</div><div>tetraazacyclotetradecane) were identified by X-ray structural analysis and their magnetic properties were investigated. Gradual spin-crossover behaviors were found in both polymorphs. Entropy differences between high- and low-spin states obtained by assuming the spin equilibrium model reflected subtle difference of the coordination environment of nickel(II) ion in two polymorphs.</div>


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