Crystal structure and topological ferrimagnetic behavior of a new 2D metal–organic hybrid manganese complex [Mn3(N3)4(L)2(H2O)2]n·0.6(C2H5OH)·1.4(H2O) with the AF/AF/F alternating sequence (HL=N′-((pyridine-2-yl)methylene)isonicotinohydrazide)

Polyhedron ◽  
2013 ◽  
Vol 49 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Behrouz Shaabani ◽  
Ali Akbar Khandar ◽  
Saeedeh Sadat Kazemi ◽  
Zohreh Shaghaghi ◽  
Athanassios K. Boudalis ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 46030-46036 ◽  
Author(s):  
Amarjit Kamath ◽  
Dipu Kumar Mishra ◽  
Dhiraj Brahman ◽  
Guillaume Pilet ◽  
Biswajit Sinha ◽  
...  

Of late, hydrothermal synthesis has gained much interest in the synthesis of metal–organic hybrid complexes with fascinating architectures and topologies.


2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.


2020 ◽  
Vol 75 (4) ◽  
pp. 365-369
Author(s):  
Long Tang ◽  
Yu Pei Fu ◽  
Na Cui ◽  
Ji Jiang Wang ◽  
Xiang Yang Hou ◽  
...  

AbstractA new metal-organic framework, [Pb(hmpcaH)2]n (1), has been hydrothermally synthesized from Pb(OAc)2 · 3H2O and 2-hydroxy-6-methylpyridine-4-carboxylic acid (hmpcaH2; 2), and characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In complex 1, each hmpcaH− ligand represents a three-connected node to combine with the hexacoordinated Pb(II) ions, generating a 3D binodal (3,6)-connected ant network. The crystal structure of 2 was determined. The solid-state fluorescence properties of 1 and 2 were investigated.


2012 ◽  
Vol 48 (33) ◽  
pp. 3966 ◽  
Author(s):  
Yuling Hu ◽  
Yifeng Fan ◽  
Zelin Huang ◽  
Chaoyong Song ◽  
Gongke Li

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