Facile intramolecular silicon–carbon bond activation at Pt0 and PtII centers

Polyhedron ◽  
2013 ◽  
Vol 52 ◽  
pp. 750-754 ◽  
Author(s):  
Samuel J. Mitton ◽  
Robert McDonald ◽  
Laura Turculet
Keyword(s):  
Bond Activation ◽  
Carbon Bond ◽  
Silicon Carbon

Reactivity of a Dimethylplatinum(II) Complex with the Bis(2-pyridyl)dimethylsilane Ligand: Easy Silicon–Carbon Bond Activation

2012 ◽  
Vol 31 (9) ◽  
pp. 3539-3550 ◽  
Author(s):  
Muhieddine Safa ◽  
Michael C. Jennings ◽  
Richard J. Puddephatt
Keyword(s):  
Bond Activation ◽  
Carbon Bond ◽  
Silicon Carbon

Easy oxidatively induced silicon–carbon bond activation in organoplatinum chemistry

2010 ◽  
Vol 46 (16) ◽  
pp. 2811 ◽  
Author(s):  
Muhieddine Safa ◽  
Michael C. Jennings ◽  
Richard J. Puddephatt
Keyword(s):  
Bond Activation ◽  
Carbon Bond ◽  
Silicon Carbon

Thermal and Photochemical Silicon−Carbon Bond Activation in Donor-Stabilized Platinum(0)−Alkyne Complexes

2002 ◽  
Vol 21 (6) ◽  
pp. 1190-1196 ◽  
Author(s):  
Christian Müller ◽  
Rene J. Lachicotte ◽  
William D. Jones
Keyword(s):  
Bond Activation ◽  
Carbon Bond ◽  
Silicon Carbon ◽  
Alkyne Complexes

Carbon Dioxide-Mediated C(sp2)–H Arylation of Primary and Secondary Benzylamines

2018 ◽  
Author(s):  
Mohit Kapoor ◽  
Pratibha Chand-Thakuri ◽  
Michael Young
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Carbon Bond ◽  
Chelate Effect ◽  
Free Amine ◽  
Carbon Carbon Bond ◽  
New Strategy ◽  
Metal Catalyzed

Carbon-carbon bond formation by transition metal-catalyzed C–H activation has become an important strategy to fabricate new bonds in a rapid fashion. Despite the pharmacological importance of <i>ortho</i>-arylbenzylamines, however, effective <i>ortho</i>-C–C bond formation from C–H bond activation of free primary and secondary benzylamines using Pd<sup>II</sup> remains an outstanding challenge. Presented herein is a new strategy for constructing <i>ortho</i>-arylated primary and secondary benzylamines mediated by carbon dioxide (CO<sub>2</sub>). The use of CO<sub>2</sub> is critical to allowing this transformation to proceed under milder conditions than previously reported, and that are necessary to furnish free amine products that can be directly used or elaborated without the need for deprotection. In cases where diarylation is possible, a chelate effect is demonstrated to facilitate selective monoarylation.

scholarly journals Carbon–carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Bao-Sheng Li ◽  
Yuhuang Wang ◽  
Zhichao Jin ◽  
Pengcheng Zheng ◽  
Rakesh Ganguly ◽  
...  
Keyword(s):  
Bond Activation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

scholarly journals Silicon–Carbon Bond Inversions Driven by 60-keV Electrons in Graphene

2014 ◽  
Vol 113 (11) ◽  
Author(s):  
Toma Susi ◽  
Jani Kotakoski ◽  
Demie Kepaptsoglou ◽  
Clemens Mangler ◽  
Tracy C. Lovejoy ◽  
...  
Keyword(s):  
Carbon Bond ◽  
Silicon Carbon
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