Oximato bridged dinuclear copper(II) complexes: Synthesis, crystal structure, magnetic, thermal, electrochemical aspects and BVS analysis

Polyhedron ◽  
2012 ◽  
Vol 43 (1) ◽  
pp. 89-96 ◽  
Author(s):  
Jnan Prakash Naskar ◽  
Bhargab Guhathakurta ◽  
Liping Lu ◽  
Miaoli Zhu
Author(s):  
Bernhard Eberhard Christian Bugenhagen ◽  
Marc Heinrich Prosenc

The structure of the title compound, [Cu4(CH3O)4(C11H13O2)4], consists of dimeric dinuclear copper(II) complexes oriented around a centre of inversion. Within each dinuclear fragment, the two CuIIatoms are in a distorted square-planar coordination sphere. Two neighbouring fragments are linked by four apical Cu—O contacts, yielding an overall square-pyramidal coordination environment for each of the four CuIIatoms. The molecules are arranged in layers parallel to (101). Non-classical C—H...O hydrogen-bonding interactions are observed between the layers.


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