Effect of ligand substituents on supramolecular self-assembly and electrochemical properties of copper(II) complexes with benzoylhydrazones: X-ray crystal structures and cyclic voltammetry

Polyhedron ◽  
2012 ◽  
Vol 36 (1) ◽  
pp. 120-126 ◽  
Author(s):  
Dariusz Matoga ◽  
Janusz Szklarzewicz ◽  
Wojciech Nitek
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Properties ◽  
Crystal Structures ◽  
Self Assembly ◽  
X Ray

Crystal structures of (S)- and (R,S)-2,2′-bipyridine-3,3′-dicarboxylic acid 1,1′-dioxides and of their barium salts: absolute configuration and molecular distortion enforced by supramolecular self-assembly

1997 ◽  
Vol 212 (3) ◽  
Author(s):  
P. Vojtíšek ◽  
I. Císařová ◽  
J. Podlaha ◽  
Z. Žák ◽  
S. Böhm ◽  
...  
Keyword(s):  
Single Crystal ◽  
Dicarboxylic Acid ◽  
Crystal Structures ◽  
Absolute Configuration ◽  
Self Assembly ◽  
Barium Salt ◽  
X Ray Diffraction ◽  
X Ray

AbstractCrystal structures of the title compounds were determined by single crystal X-ray diffraction. Absolute configuration of the barium salt of (+)-(

Synthesis, Cyclic Voltammetry, and x-ray Crystal Structures of Copper(I) and Copper(II) Complexes of Tris((6-phenyl-2-pyridyl)methyl)amine (TPPA)

1995 ◽  
Vol 34 (10) ◽  
pp. 2562-2568 ◽  
Author(s):  
Chang-lin Chuang ◽  
Kitae Lim ◽  
Qiu Chen ◽  
Jon Zubieta ◽  
James W. Canary
Keyword(s):  
Cyclic Voltammetry ◽  
Crystal Structures ◽  
X Ray ◽  
Methyl Amine

Self-Assembly of α-MnO2 Nanorods into Spheres: Synthesis and Electrochemical Properties

2008 ◽  
Vol 8 (3) ◽  
pp. 1494-1496 ◽  
Author(s):  
Xu Chun Song ◽  
Yi Fan Zheng ◽  
E. Yang ◽  
Yun Wang
Keyword(s):  
Cyclic Voltammetry ◽  
Sodium Dodecyl Sulfate ◽  
Electrochemical Properties ◽  
Electrode Material ◽  
Self Assembly ◽  
Sodium Dodecyl ◽  
Electrochemical Characterization ◽  
Dodecyl Sulfate ◽  
Hydrothermal Approach

The α-MnO2 spherical assemblies were prepared via a facile hydrothermal approach in the presence of sodium dodecyl sulfate (SDS). The assembled nanostructures were composed of the MnO2 nanorods with 150–200 nm in width and several micrometers in length. The products were characterized by SEM, TEM and XRD. The electrochemical characterization was carried out by cyclic voltammetry, which indicated that the α-MnO2 spherical assemblies were of an excellent electrode material for supercapacitor.

Syntheses, Crystal Structures and Electrochemical Properties of Acetylacetonato-Ruthenium Complexes Containing Substituted Pyridine Ligands

2013 ◽  
Vol 68 (9) ◽  
pp. 993-999 ◽  
Author(s):  
Xiuli Wu ◽  
Rufei Ye ◽  
Ai-Quan Jia ◽  
Qun Chen ◽  
Qian-Feng Zhang
Keyword(s):  
Electrochemical Properties ◽  
Crystal Structures ◽  
Zinc Dust ◽  
Ruthenium Complexes ◽  
Reducing Agent ◽  
Molecular Structures ◽  
X Ray ◽  
X Ray Crystallography ◽  
Crystal And Molecular Structures ◽  
Pyridine Ligands

Treatment of Ru(acac)3 with 2-cyano-pyridine and 3,5-dimethyl-pyridine in the presence of zinc dust as reducing agent in refluxing THF afforded the ruthenium(II) complexes cis-[RuII(acac)2(2- CN-py)2] (1) and cis-[RuII(acac)2(3,5-Me2-py)2] (2), respectively. Interaction of Ru(acac)3 with 3- Me-pyridine and 3,5-Me2-pyridine in the presence of Br2 in refluxing THF gave the ruthenium(III) complexes [RuIII(acac)Br2(3-Me-py)2] (3) and [RuIII(acac)Br2(3,5-Me2-py)2] (4), respectively. The four complexes have been spectroscopically and electrochemically characterized, and their crystal and molecular structures have been established by X-ray crystallography

Ferrocenyl chalcones containing anthracenyl group: Synthesis, X-ray crystal structures and electrochemical properties

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 861-867 ◽  
Author(s):  
YounJung Jung ◽  
Kyung-In Son ◽  
Youl Eui Oh ◽  
Dong-Youn Noh
Keyword(s):  
Electrochemical Properties ◽  
Crystal Structures ◽  
X Ray ◽  
Ferrocenyl Chalcones

scholarly journals TTFs nonsymmetrically fused with alkylthiophenic moieties

2015 ◽  
Vol 11 ◽  
pp. 628-637 ◽  
Author(s):  
Rafaela A L Silva ◽  
Bruno J C Vieira ◽  
Marta M Andrade ◽  
Isabel C Santos ◽  
Sandra Rabaça ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Charge Transfer ◽  
Single Crystal ◽  
Electrochemical Properties ◽  
X Ray ◽  
Oxidation Processes ◽  
Ligand Precursors ◽  
A Charge

Two new dithiolene ligand precursors, containing fused TTF and alkyl thiophenic moieties 3,3'-{[2-(5-(tert-butyl)thieno[2,3-d][1,3]dithiol-2-ylidene)-1,3-dithiole-4,5-diyl]bis[sulfanediyl]}dipropanenitrile (α-tbtdt, 1), and 3,3'-{[2-(5-methylthieno[2,3-d][1,3]dithiol-2-ylidene)-1,3-dithiole-4,5-diyl]bis[sulfanediyl]}dipropanenitrile (α-mtdt, 2), were synthesized and characterized. The electrochemical properties of these electronic donors were studied by cyclic voltammetry (CV) in dichloromethane. Both compounds show two quasi-reversible oxidation processes, versus Ag/AgCl, typical of TTF donors at E 1 1/2 = 279 V and E 2 1/2 = 680 V for 1 and E 1 1/2 = 304 V and E 2 1/2 = 716 V in the case of 2. The single-crystal X-ray structure of 1 and of a charge transfer salt of 2, (α-mtdt)[Au(mnt)2] (3), are reported.

Syntheses, Structures and Electrochemical Properties of Two New Copper(II) Complexes Based on Isomeric Bis(pyridylformyl)piperazine Ligands and Rigid=Flexible Organic Dicarboxylates

2013 ◽  
Vol 68 (2) ◽  
pp. 138-146 ◽  
Author(s):  
Hong-Yan Lin ◽  
Peng Liu ◽  
Xiu-Li Wang ◽  
Chuang Xu ◽  
Guo-Cheng Liu
Keyword(s):  
Electrochemical Properties ◽  
Self Assembly ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Stacking Interactions ◽  
X Ray Diffraction ◽  
Pyridyl Nitrogen ◽  
X Ray ◽  
Network Complex ◽  
Polymeric Framework

Two new copper(II) complexes, [Cu2(3-bpfp)(2,6-PDA)2(H2O)2] (1) and [Cu(4-bpfp)0:5 (glu)]·H2O (2), have been hydrothermally synthesized by self-assembly of isomeric bis(pyridylformyl)piperazine ligands [3-bpfp=bis(3-pyridylformyl)piperazine, 4-bpfp=bis(4- pyridylformyl)piperazine], rigid pyridine-2,6-dicarboxylic acid (2,6-H2PDA) or flexible glutaric acid (H2glu), and copper(II) chloride. Single-crystal X-ray diffraction analysis reveals that two adjacent CuII ions are connected by the 3-bpfp ligand to build a dinuclear unit in complex 1, in which 2,6-PDA serves as a terminal chelating ligand. Adjacent dinuclear units are further linked by hydrogen bonding and π-π stacking interactions to form a three-dimensional (3D) supramolecular network. Complex 2 is a 3D coordination polymeric framework based on a layer polymer [Cu(glu)]n and bridging 4-bpfp ligands with 6-connected (44.610.8) topology. In 1 and 2, the ligands 3-bpfp and 4-bpfp adopt a μ2-bridging coordination mode (via ligation of pyridyl nitrogen atoms). The thermal stability and the electrochemical properties of the title complexes have been studied.

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