Synthesis and properties of crown ether functionalized coumarin substituted zinc phthalocyanine

Polyhedron ◽  
2011 ◽  
Vol 30 (12) ◽  
pp. 2067-2074 ◽  
Author(s):  
Aliye Aslı Esenpınar ◽  
Mahmut Durmuş ◽  
Mustafa Bulut
Keyword(s):  
Crown Ether ◽  
Zinc Phthalocyanine

Investigation of optical and electrochemical properties as well as metal ion sensitivities of different number of crown ether appended phthalocyanines

2013 ◽  
Vol 17 (08n09) ◽  
pp. 682-690 ◽  
Author(s):  
Sevinc Z. Topal ◽  
Devrim Atilla ◽  
Kadriye Ertekin ◽  
Jean B. Tommasino ◽  
Dominique Luneau ◽  
...  
Keyword(s):  
Crown Ether ◽  
Metal Ion ◽  
Fluorescence Emission ◽  
Emission Spectra ◽  
Zinc Phthalocyanine ◽  
Ion Binding ◽  
Metal Ion Binding ◽  
Binding Properties ◽  
Fluorescence Emission Spectra

We report herein, the synthesis, and spectral and electrochemical characterization of a series of phthalocyaninato zinc complexes where two biomedically potential structures; crown ether and phthalocyanine moities were gathered on the same molecule. The effect of number of crown ether moieties on metal ion binding properties, as well as proton sensitivity were investigated by using electronic absorption and fluorescence emission spectra. Spectral behaviors of the zinc phthalocyanine complexes fused with one crown ether; Zn [ Pc (15 C 5)( C 6 H 13)6] and four crown ether; Zn [ Pc (15 C 5)4] in presence of Na + and K + ions were investigated into detail because of host-guest interactions of subjective ions with crown ether moieties, and compared with the crown ether free phthalocyanine; Zn [ Pc ( C 6 H 13)8].

Probing Supramolecular Interactions between a Crown Ether Appended Zinc Phthalocyanine and an Ammonium Group Appended to a C60 Derivative

2016 ◽  
Vol 22 (6) ◽  
pp. 2051-2059 ◽  
Author(s):  
Marcus Lederer ◽  
Uwe Hahn ◽  
Jean-Marc Strub ◽  
Sarah Cianférani ◽  
Alain Van Dorsselaer ◽  
...  
Keyword(s):  
Crown Ether ◽  
Zinc Phthalocyanine ◽  
Supramolecular Interactions ◽  
Ammonium Group

Aggregation of a Crown Ether Decorated Zinc–Phthalocyanine by Collision-Induced Desolvation of Electrospray Droplets

2015 ◽  
Vol 119 (46) ◽  
pp. 11454-11460 ◽  
Author(s):  
Ina D. Kellner ◽  
Uwe Hahn ◽  
Maximilian Dürr ◽  
Tomás Torres ◽  
Ivana Ivanović-Burmazović ◽  
...  
Keyword(s):  
Crown Ether ◽  
Zinc Phthalocyanine ◽  
Electrospray Droplets

Synthesis and spectroscopic properties of a novel zinc phthalocyanine with four 17-membered crown ether voids

2010 ◽  
Vol 15 (5) ◽  
pp. 443-449
Author(s):  
Guo-Xiang Xiong ◽  
Shu-Yin Shen ◽  
Jian-Ping Ye ◽  
Qing-Fu Zhou ◽  
Hui-Jun Xu
Keyword(s):  
Crown Ether ◽  
Spectroscopic Properties ◽  
Zinc Phthalocyanine

Preparation and Gas Sensitivity of Crown Ether Metal Complex Film Gas Sensor

2020 ◽  
Vol 2 (1) ◽  
pp. 1-12
Author(s):  
Gulgina Mamtimin ◽  
Halisa Arkin ◽  
Patima Nizamidin ◽  
Erkin Tursun ◽  
Abliz Yimit
Keyword(s):  
Crown Ether ◽  
Metal Complex ◽  
Gas Sensor ◽  
Gas Sensitivity ◽  
Complex Film

Synthesis and Characterization of New Zinc Phthalocyanine - Dodecenyl Succinic Anhydride Benzoic Groups

2020 ◽  
Vol 17 (6) ◽  
pp. 488-495
Author(s):  
Hussein Ali Al-Bahrani ◽  
Mohanad Mousa Kareem ◽  
Abdul Amir Kadhum ◽  
Nour A. Alrazzak
Keyword(s):  
Salicylic Acid ◽  
Succinic Anhydride ◽  
Zinc Phthalocyanine ◽  
Central Metal ◽  
Target Compound ◽  
Compound I ◽  
Metal Phthalocyanines ◽  
Metal Atoms ◽  
Amino Salicylic Acid

Background: The phthalocyanines a series of compounds involves four iso-indole units linked by aza nitrogen atoms bonded with metal atoms that are normally located in the center a phthalocyanines ring. Some of the central metal-phthalocyanines can be excited by ultraviolet light and emit a fluorescence in far-red region. Objective: To synthesize a derivative of phthalocyanines namely 4,4',4' '-tri-(dodecenyl succinic anhydride)- 4' ' '-(5-amino salicylic acid) zinc phthalocyanine with a zinc central metal. Materials and Methods: The reaction of 4- nitro Phthalonitrile and 4- amino Phthalonitrile with ZnCl2 in the presence of dimethyl amino ethanol afforded 4,4',4' '-triamino-4' ' '-nitro zinc phthalocyanine. This product reacted with 5-amino salicylic acid to yield tetra-(5-amino salicylic acid) zinc phthalocyanine. A dodecenyl succinic anhydride was added on the amine group of benzoic rings to afford 4,4',4' '-tri-(dodecenyl succinic anhydride)-4' ' '-(5-amino salicylic acid) zinc phthalocyanine(I), the target compound. Results and Discussion: Compound I is successfully synthesized with a yield of 72% from tetra-(5-amino salicylic acid) zinc phthalocyanine with dodecenyl succinic anhydride. Conclusion: The newly synthesized molecule of 4,4',4' '-tri-(dodecenyl succinic anhydride)-4' ' '-(5-amino salicylic acid) zinc phthalocyanine (I), tetra-(5-amino salicylic acid) zinc phthalocyanine(E) and 4,4',4' '- triamino-4' ' '-nitro zinc phthalocyanine (S). The reaction of 4- nitro Phthalonitrile and 4- amino and the structure of compound I is confirmed and its formation was proven.

PEO-based electrolytes blended with star polymers with precisely imprinted polymeric pseudo-crown ether cavities for alkali metal ion batteries

2019 ◽  
Vol 576 ◽  
pp. 182-189 ◽  
Author(s):  
Zhuliu Xiao ◽  
Binghua Zhou ◽  
Jirong Wang ◽  
Cai Zuo ◽  
Dan He ◽  
...  
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Ion ◽  
Star Polymers ◽  
Alkali Metal Ion
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