Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re12CS17(OH)6]·4H2O and Na12Re12CS17(SO3)6·48.5H2O

Polyhedron ◽  
2010 ◽  
Vol 29 (18) ◽  
pp. 3283-3286 ◽  
Author(s):  
Yuri V. Mironov ◽  
Svetlana G. Kozlova ◽  
Sung-Jin Kim ◽  
William S. Sheldrick ◽  
Vladimir E. Fedorov
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Cluster Complexes ◽  
Structures And Properties ◽  
Rhenium Cluster ◽  
New Compounds ◽  
Interstitial Carbon Atom

[Re12CS17(CN)6]n− (n=6, 8): A Sulfido-Cyanide Rhenium Cluster with an Interstitial Carbon Atom

2005 ◽  
Vol 44 (42) ◽  
pp. 6867-6871 ◽  
Author(s):  
Yuri V. Mironov ◽  
Nikolai G. Naumov ◽  
Svetlana G. Kozlova ◽  
Sung-Jin Kim ◽  
Vladimir E. Fedorov
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Rhenium Cluster ◽  
Interstitial Carbon Atom

[Re12CS17(CN)6]n− (n=6, 8): A Sulfido-Cyanide Rhenium Cluster with an Interstitial Carbon Atom

2005 ◽  
Vol 117 (42) ◽  
pp. 7027-7031 ◽  
Author(s):  
Yuri V. Mironov ◽  
Nikolai G. Naumov ◽  
Svetlana G. Kozlova ◽  
Sung-Jin Kim ◽  
Vladimir E. Fedorov
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Rhenium Cluster ◽  
Interstitial Carbon Atom

[Re12CS17(CN)6]n- (n = 6, 8): A Sulfido—Cyanide Rhenium Cluster with an Interstitial Carbon Atom.

ChemInform ◽  
2006 ◽  
Vol 37 (2) ◽  
Author(s):  
Yuri V. Mironov ◽  
Nikolai G. Naumov ◽  
Svetlana G. Kozlova ◽  
Sung-Jin Kim ◽  
Vladimir E. Fedorov
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Rhenium Cluster ◽  
Interstitial Carbon Atom

scholarly journals The Fe–V Cofactor of Vanadium Nitrogenase Contains an Interstitial Carbon Atom

2015 ◽  
Vol 54 (45) ◽  
pp. 13249-13252 ◽  
Author(s):  
Julian A. Rees ◽  
Ragnar Bjornsson ◽  
Julia Schlesier ◽  
Daniel Sippel ◽  
Oliver Einsle ◽  
...  
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Vanadium Nitrogenase ◽  
Interstitial Carbon Atom

scholarly journals Radiation‐induced interstitial carbon atom in silicon: Effect of charge state on annealing characteristics

2017 ◽  
Vol 214 (7) ◽  
pp. 1700262 ◽  
Author(s):  
Stanislau B. Lastovskii ◽  
Vasilii E. Gusakov ◽  
Vladimir P. Markevich ◽  
Anthony R. Peaker ◽  
Hanna S. Yakushevich ◽  
...  
Keyword(s):  
Carbon Atom ◽  
Charge State ◽  
Interstitial Carbon ◽  
Radiation Induced ◽  
Interstitial Carbon Atom

scholarly journals The Fe–V Cofactor of Vanadium Nitrogenase Contains an Interstitial Carbon Atom

2015 ◽  
Vol 127 (45) ◽  
pp. 13447-13450 ◽  
Author(s):  
Julian A. Rees ◽  
Ragnar Bjornsson ◽  
Julia Schlesier ◽  
Daniel Sippel ◽  
Oliver Einsle ◽  
...  
Keyword(s):  
Carbon Atom ◽  
Interstitial Carbon ◽  
Vanadium Nitrogenase ◽  
Interstitial Carbon Atom

scholarly journals Thermally Controlled Synthesis of Octahedral Rhenium Clusters with 4,4′-Bipyridine and CN− Apical Ligands

Symmetry ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 2187
Author(s):  
Anton A. Ulantikov ◽  
Taisiya S. Sukhikh ◽  
Evgeniy N. Gribov ◽  
Natalia V. Maltseva ◽  
Konstantin A. Brylev ◽  
...  
Keyword(s):  
Functional Group ◽  
Weak Interactions ◽  
Molecular Compound ◽  
Cluster Complexes ◽  
Redox Active Ligand ◽  
Redox Active ◽  
Rhenium Cluster ◽  
Electron Reduction ◽  
Red Luminescence ◽  
New Compounds

The selective preparation, structural and spectroscopic study of two new rhenium cluster complexes trans-[Re6S8(bpy)4(CN)2] and trans-[Re6S8(bpy)2(CN)4]2− (bpy = 4,4′-bipyridine) obtained by reactions of corresponding hexarhenium cyanohalides with molten bpy are reported. The complexes were crystallized as solvates, displaying supramolecular structures based on cluster units linked by numerous weak interactions with bpy molecules. The molecular compound trans-[Re6S8(bpy)4(CN)2] (1) is insoluble in water and common organic solvents, while the ionic compound trans-Cs1.7K0.3[Re6S8(bpy)2(CN)4] (2) is somewhat soluble in DMSO, DMF and N-methylpyrrolidone. The presence of the redox-active ligand bpy leads to the occurrence of multi-electron reduction transitions in a solution of 2 at moderate potential values. The ambidentate CN− ligand is the secondary functional group, which has potential for the synthesis of coordination polymers based on the new cluster complexes. In addition, both new compounds show a weak red luminescence, which is characteristic of complexes with a {Re6S8}2+ cluster core.

New trans-[Re6S8(CN)4L2] n− Rhenium Cluster Complexes: Syntheses, Crystal Structures and Properties

2009 ◽  
Vol 20 (1) ◽  
pp. 225-239 ◽  
Author(s):  
Nikolay G. Naumov ◽  
Alexandra Y. Ledneva ◽  
Sung-Jin Kim ◽  
Vladimir E. Fedorov
Keyword(s):  
Crystal Structures ◽  
Cluster Complexes ◽  
Structures And Properties ◽  
Rhenium Cluster
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