Syntheses, characterization, X-ray crystal structures and emission properties of copper(II), zinc(II) and cadmium(II) complexes of pyridyl–pyrazole derived Schiff base ligand – Metal selective ligand binding modes

Polyhedron ◽  
2010 ◽  
Vol 29 (15) ◽  
pp. 2892-2899 ◽  
Author(s):  
Kinsuk Das ◽  
Tarak Nath Mandal ◽  
Somnath Roy ◽  
Samik Gupta ◽  
Anil Kumar Barik ◽  
...  
Polyhedron ◽  
2003 ◽  
Vol 22 (10) ◽  
pp. 1335-1340 ◽  
Author(s):  
D.A. Garnovskii ◽  
M.F.C. Guedes da Silva ◽  
M.N. Kopylovich ◽  
A.D. Garnovskii ◽  
J.J.R. Fraústo da Silva ◽  
...  

2011 ◽  
Vol 66 (3) ◽  
pp. 324-328 ◽  
Author(s):  
Yan Li ◽  
Qing Ma ◽  
Hua-Tian Shi ◽  
Qun Chen ◽  
Qian-Feng Zhang

Treatment of [Ru(PPh3)3Cl2] with the Schiff base ligand H2salen in THF at reflux afforded a neutral RuIIIsalen complex [RuIII(salen)(PPh3)Cl] (1). Interaction of [RuHCl(CO)(PPh3)3] with H2salen under similar conditions gave a neutral RuII-salen complex [RuII(salen- NH)(PPh3)(CO)] (2). In its formation one of the imine bonds was nucleophilically attacked by hydride to give a mixed imine-amine ligand. The two complexes have been spectroscopically characterized, and the crystal structures of 1 · 2CH2Cl2 and 2 · CH2Cl2 have been established by X-ray crystallography.


Sign in / Sign up

Export Citation Format

Share Document