Self assembly of asymmetric tetranuclear Cu(II) [2×2] grid-like complexes and of a dinuclear Ni(II) complex from pyridyl-phenol Schiff base ligands

Polyhedron ◽  
2010 ◽  
Vol 29 (13) ◽  
pp. 2739-2746 ◽  
Author(s):  
François Robert ◽  
Bernard Tinant ◽  
Rodolphe Clérac ◽  
Pierre-Loïc Jacquemin ◽  
Yann Garcia
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Schiff Base Ligands

Self-assembly of NIR luminescent 30-metal drum-like and 12-metal rectangular d–f nanoclusters with long-chain Schiff base ligands

2014 ◽  
Vol 50 (98) ◽  
pp. 15569-15572 ◽  
Author(s):  
Xiaoping Yang ◽  
Zongping Li ◽  
Shiqing Wang ◽  
Shaoming Huang ◽  
Desmond Schipper ◽  
...  
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Schiff Base Ligands ◽  
Long Chain

Two classes of NIR luminescent heterobimetallic d–f nanoclusters [Ln6Cd24(L1)11(OAc)43(OH)] and [Ln4Zn8(L2)2(OAc)20(OH)4] (Ln = Nd and Yb) were prepared using flexible long-chain Schiff base ligands which have (CH2)6 backbones.

scholarly journals Self-Assembly of Antiferromagnetically-Coupled Copper(II) Supramolecular Architectures with Diverse Structural Complexities

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5549 ◽  
Author(s):  
Santokh S. Tandon ◽  
Scott D. Bunge ◽  
Neil Patel ◽  
Esther C. Wang ◽  
Laurence K. Thompson
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Three Dimensional ◽  
The Self ◽  
Basic Building Block ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Supramolecular Architectures ◽  
Hydroxy Groups ◽  
New Discovery

The self-assembly of 2,6-diformyl-4-methylphenol (DFMP) and 1-amino-2-propanol (AP)/2-amino-1,3-propanediol (APD) in the presence of copper(II) ions results in the formation of six new supramolecular architectures containing two versatile double Schiff base ligands (H3L and H5L1) with one-, two-, or three-dimensional structures involving diverse nuclearities: tetranuclear [Cu4(HL2−)2(N3)4]·4CH3OH·56H2O (1) and [Cu4(L3−)2(OH)2(H2O)2] (2), dinuclear [Cu2(H3L12−)(N3)(H2O)(NO3)] (3), polynuclear {[Cu2(H3L12−)(H2O)(BF4)(N3)]·H2O}n (4), heptanuclear [Cu7(H3L12−)2(O)2(C6H5CO2)6]·6CH3OH·44H2O (5), and decanuclear [Cu10(H3L12−)4(O)2(OH)2(C6H5CO2)4] (C6H5CO2)2·20H2O (6). X-ray studies have revealed that the basic building block in 1, 3, and 4 is comprised of two copper centers bridged through one μ-phenolate oxygen atom from HL2− or H3L12−, and one μ-1,1-azido (N3−) ion and in 2, 5, and 6 by μ-phenoxide oxygen of L3− or H3L12− and μ-O2− or μ3-O2− ions. H-bonding involving coordinated/uncoordinated hydroxy groups of the ligands generates fascinating supramolecular architectures with 1D-single chains (1 and 6), 2D-sheets (3), and 3D-structures (4). In 5, benzoate ions display four different coordination modes, which, in our opinion, is unprecedented and constitutes a new discovery. In 1, 3, and 5, Cu(II) ions in [Cu2] units are antiferromagnetically coupled, with J ranging from −177 to −278 cm−1.

Unsymmetrical exo-dentate IN− ligand for further self-assembly with the Zn–Nd Salen-type Schiff-base ligands

2009 ◽  
Vol 12 (3) ◽  
pp. 267-271 ◽  
Author(s):  
Wei-Yu Bi ◽  
Xing-Qiang Lü ◽  
Wen-Li Chai ◽  
Tao Wei ◽  
Ji-Rong Song ◽  
...  
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Schiff Base Ligands

The architecture of dinuclear Ni and Cu complexes: twisted and parallel forms controlled by the self-assembly of Schiff base ligands

2003 ◽  
Vol 27 (5) ◽  
pp. 886-889 ◽  
Author(s):  
Hirohiko Houjou ◽  
Atsushi Iwasaki ◽  
Tamako Ogihara ◽  
Masatoshi Kanesato ◽  
Sadatoshi Akabori ◽  
...  
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
The Self ◽  
Schiff Base Ligands ◽  
Parallel Forms ◽  
Cu Complexes

Self-Assembly of Nickel(II) Complexes of New Bis-Bidentate Schiff Base Ligands

2001 ◽  
Vol 2001 (2) ◽  
pp. 353-357 ◽  
Author(s):  
Laura Carbonaro ◽  
Mauro Isola ◽  
Vincenzo Liuzzo ◽  
Fabio Marchetti ◽  
Federica Balzano ◽  
...  
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Schiff Base Ligands

Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands

2004 ◽  
pp. 502 ◽  
Author(s):  
Zheng He ◽  
Cheng He ◽  
Zhe-Ming Wang ◽  
En-Qing Gao ◽  
Yuan Liu ◽  
...  
Keyword(s):  
Schiff Base ◽  
Self Assembly ◽  
Schiff Base Ligands ◽  
Molecular Squares
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