A novel two-dimensional Ni(II) fumarato complex: Solvothermal synthesis, crystal structure and magnetic properties

Polyhedron ◽  
2009 ◽  
Vol 28 (14) ◽  
pp. 2893-2898 ◽  
Author(s):  
Juraj Černák ◽  
Anna Pavlová ◽  
Alžbeta Orendáčová ◽  
Marcela Kajňaková ◽  
Juraj Kuchár
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Solvothermal Synthesis ◽  
Two Dimensional

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Modulation of the Magnetic Properties of Two-Dimensional Compounds [NiX2(N–N)] by Tailoring Their Crystal Structure

2013 ◽  
Vol 52 (12) ◽  
pp. 7087-7093 ◽  
Author(s):  
Miguel Cortijo ◽  
Santiago Herrero ◽  
Reyes Jiménez-Aparicio ◽  
Emilio Matesanz
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Two Dimensional

scholarly journals Crystal structure of bis(azido-κN)bis(quinolin-8-amine-κ2N,N′)iron(II)

2016 ◽  
Vol 72 (10) ◽  
pp. 1488-1491
Author(s):  
Fatima Setifi ◽  
Dohyun Moon ◽  
Robeyns Koen ◽  
Zouaoui Setifi ◽  
Morad Lamsayah ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Structure Determination ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Two Dimensional ◽  
Azide Ion ◽  
Amine Ligands

The search for new molecular materials with interesting magnetic properties using the pseudohalide azide ion and quinolin-8-amine (aqin, C9H8N2) as a chelating ligand, led to the synthesis and structure determination of the title complex, [Fe(N3)2(C9H8N2)2]. The complex shows an octahedral geometry, with the FeIIatom surrounded by six N atoms; the two N3−anions coordinate in acisconfiguration, while the remaining N atoms originate from the two quinolin-8-amine ligands with the quinoline N atoms lying on opposite sides of the Fe atom. The crystal packing is dominated by layers of hydrophilic and aromatic regions parallel to theacplane, stabilized by a two-dimensional hydrogen-bonded network and π–π stacking.

All-cis-1,2,3,4,5,6-cyclohexanehexacarboxylate two-dimensional gadolinium(III) complexes: Synthesis, X-ray crystal structure and magnetic properties

Polyhedron ◽  
2010 ◽  
Vol 29 (1) ◽  
pp. 188-195 ◽  
Author(s):  
Laura Cañadillas-Delgado ◽  
Oscar Fabelo ◽  
Jorge Pasán ◽  
Miguel Julve ◽  
Francesc Lloret ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Two Dimensional ◽  
X Ray
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