Early transition metal derivatives stabilised by the phenylenediamido 1,2-C6H4(NCH2tBu)2 ligand: Synthesis, characterisation and reactivity studies: Crystal structures of [Ta{1,2-C6H4(NCH2tBu)2}2Cl] and [Zr{(1,2-C6H4(NCH2tBu)2}(NMe2)(μ-NMe2)]2

Polyhedron ◽  
2009 ◽  
Vol 28 (13) ◽  
pp. 2545-2554 ◽  
Author(s):  
Vanessa Tabernero ◽  
Tomás Cuenca ◽  
Marta E.G. Mosquera ◽  
Carmen Ramírez de Arellano
2019 ◽  
Vol 48 (26) ◽  
pp. 9617-9624 ◽  
Author(s):  
Dae Young Bae ◽  
Gyeong Su Park ◽  
Nakeun Ko ◽  
Kyung-sun Son ◽  
Eunsung Lee

A highly sterically demanding amino triphenolate ligand was successfully synthesized, and early transition metal complexes (Ti, V, Cr, and Mn) supported by the ligand were also obtained and fully characterized.


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