XPS, single crystal X-ray diffraction and cyclic voltammetric studies on 1,10-phenanthroline and 2,2′-bipyridine adducts of bis(piperidinecarbodithioato-S,S′)cadmium(II) with CdS4N2 environment – A stereochemical and electronic distribution investigation

Polyhedron ◽  
2009 ◽  
Vol 28 (2) ◽  
pp. 263-268 ◽  
Author(s):  
S. Thirumaran ◽  
K. Ramalingam ◽  
G. Bocelli ◽  
L. Righi
Author(s):  
Leyla Tatar ◽  
Hasan Nazır ◽  
Mine Gümüşer ◽  
Cansen Kale ◽  
Orhan Atakol

AbstractFour water soluble Schiff bases were prepared from the reaction of salicylaldehyde and 2-hydroxy-1-naphtaldehyde with 2-amino-2-methyl-1,3-dihydroxy propane and 2-amino-2-methoxy-1,3-dihydroxy propane. Two of the Schiff bases were characterized using elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In addition cyclic voltammetric studies were performed. The Schiff bases C


Polyhedron ◽  
2011 ◽  
Vol 30 (3) ◽  
pp. 529-534 ◽  
Author(s):  
Sumita Naskar ◽  
Subhendu Naskar ◽  
Heike Mayer-Figge ◽  
William S. Sheldrick ◽  
Shyamal Kumar Chattopadhyay

2013 ◽  
Vol 678 ◽  
pp. 263-267 ◽  
Author(s):  
Paramasivam Rajakani ◽  
Chinnapiyan Vedhi

Aniline was polymerized with TiO2 by chemical oxidation method using Potassium perdisulphate. The solubility of the chemically prepared polymer–ceramic nanocomposite was ascertained and it showed good solubility in DMSO and DMF. The Pani–TiO2 nanocomposite was characterized by UV–Vis, FTIR spectral studies. Amine vibration observed at 1593 cm-1 was shifted to lower wave numbers when the polymer–ceramic nanocomposites were formed. The X-ray diffraction studies revealed the formation of nano sized (26 nm) crystalline polymer. SEM analysis showed mixed granular nature of the polymer–ceramic nanocomposite. EDAX analysis shows the presence of Ti, C and N. Cyclic Voltammetric studies exhibit good adherent behaviour on electrode surface at pH 1.0. It showed the presence of oxidation peaks at 0.271V and 0.623V and reduction peaks at 0.832 and 0.493V. CV, Chronoamperometric and chronocoulometric studies were also carried out at inert as well as oxidation atmosphere.


Sign in / Sign up

Export Citation Format

Share Document