A new coordination mode for tris(2-carboxyethyl)phosphine: Synthesis, crystal structure and characterization of the mixed-valence Co(III)/Co(II)/Co(III) complex [Co{P(CH2CH2COO)2(CH2CH2COOH)}2]2[Co(H2O)4][Na2(H2O)4]Cl2·6H2O

Polyhedron ◽  
2008 ◽  
Vol 27 (6) ◽  
pp. 1795-1801 ◽  
Author(s):  
D. Andrew Knight ◽  
Jeffrey R. Deschamps ◽  
Ray J. Butcher ◽  
Christa Simmers ◽  
Eddie L. Chang
Keyword(s):  
Crystal Structure ◽  
Coordination Mode ◽  
Mixed Valence

Reaction of 1,2-Bis(2-selenoxo-3-methyl-4-imidazolinyl)ethane (ebis) with TCNQ:  Crystal Structure and Characterization of the Mixed-Valence Compound [2(ebis)2+·ebis]·2[(TCNQ)32-]

1996 ◽  
Vol 35 (18) ◽  
pp. 5403-5406 ◽  
Author(s):  
Francesco Bigoli ◽  
Paola Deplano ◽  
Francesco A. Devillanova ◽  
Alberto Girlando ◽  
Vito Lippolis ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Mixed Valence ◽  
Mixed Valence Compound

Crystal Structure and Characterization of a New Mixed-valence Manganese(III/IV) Complex: [Mn2(cyclen)2(μ-O)2](ClO4)3·4H2O

2005 ◽  
Vol 23 (4) ◽  
pp. 418-420 ◽  
Author(s):  
Ren Yan-Wei ◽  
Li Jun ◽  
Zhang Feng-Xing ◽  
Zhang Jin-Hua ◽  
Guo Hui
Keyword(s):  
Crystal Structure ◽  
Mixed Valence

Crystal structure analysis of 4-R-phenyl-2,6-dimethyl-3,5-N-(dimethylcarbamoyl)-1,4-dihydropyridines [R=2-nitro (1), 4-methoxy (2) and 3,4-dichloro (3)]

1998 ◽  
Vol 213 (3) ◽  
Author(s):  
M. Bidya Sagar ◽  
K. Ravikumar ◽  
Y. S. Sadanandam
Keyword(s):  
Crystal Structure ◽  
Calcium Channel ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Calcium Channel Antagonists

AbstractThe crystallographic characterization of the following three calcium channel antagonists is reported here: 2,6-dimethyl-3,5-dicarbamoyl-4-[2-nitro]-1,4-dihydropyridine (

scholarly journals Heteroleptic [Cu(P^P)(N^N)][PF6] Complexes: Effects of Isomer Switching from 2,2′-biquinoline to 1,1′-biisoquinoline

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 185
Author(s):  
Nina Arnosti ◽  
Marco Meyer ◽  
Alessandro Prescimone ◽  
Edwin C. Constable ◽  
Catherine E. Housecroft
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Nmr Spectra ◽  
Phenyl Ether ◽  
Quantum Yields ◽  
Dynamic Processes ◽  
Electrochemical Behaviors ◽  
Ambient Temperatures ◽  
Π Stacking

The preparation and characterization of [Cu(POP)(biq)][PF6] and [Cu(xantphos)(biq)][PF6] are reported (biq = 1,1′-biisoquinoline, POP = bis(2-(diphenylphosphanyl)phenyl)ether, and xantphos = (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane). The single crystal structure of [Cu(POP)(biq)][PF6] 0.5Et2O was determined and compared to that in three salts of [Cu(POP)(bq)]+ in which bq = 2,2′-biquinoline. The P–C–P angle is 114.456(19)o in [Cu(POP)(biq)]+ compared to a range of 118.29(3)–119.60(3)o [Cu(POP)(bq)]+. There is a change from an intra-POP PPh2-phenyl/(C6H4)2O-arene π-stacking in [Cu(POP)(biq)]+ to a π-stacking contact between the POP and bq ligands in [Cu(POP)(bq)]+. In solution and at ambient temperatures, the [Cu(POP)(biq)][PF6]+ and [Cu(xantphos)(biq)]+ cations undergo several concurrent dynamic processes, as evidenced in their multinuclear NMR spectra. The photophysical and electrochemical behaviors of the heteroleptic copper (I) complexes were investigated, and the effects of changing from bq to biq are described. Short Cu···O distances within the [Cu(POP)(biq)]+ and [Cu(xantphos)(biq)]+ cations may contribute to their very low photoluminescent quantum yields.

scholarly journals Design, growth, and characterization of Y2Mo4O15 crystals for Raman laser applications

RSC Advances ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 1164-1171
Author(s):  
Xiangmei Wang ◽  
Zeliang Gao ◽  
Chunyan Wang ◽  
Xiaojie Guo ◽  
Youxuan Sun ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Raman Laser ◽  
Laser Applications ◽  
Potential Use

This work reports the crystal structure and physical properties of the Y2Mo4O15 crystal and its potential use in the Raman laser.

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