Self-assembly of 1D coordination polymers from nickel(II) tetraaza macrocycle and carboxylate ligands

Polyhedron ◽  
2008 ◽  
Vol 27 (4) ◽  
pp. 1310-1316 ◽  
Author(s):  
Ki-Young Choi ◽  
Ki-Jeong Kim
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Tetraaza Macrocycle ◽  
Carboxylate Ligands

A series of helical coordination polymers based on two racemic bis(pyridylmethylene) propane-1,2-diamine ligands: relationship of conformations, structures and properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Metal Salts ◽  
Structures And Properties ◽  
Relationship Of ◽  
Diamine Ligands

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.

Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation

2010 ◽  
Vol 122 (21) ◽  
pp. 3709-3712 ◽  
Author(s):  
Liting Yu ◽  
Zheng Wang ◽  
Jiang Wu ◽  
Shujiang Tu ◽  
Kuiling Ding
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Enantioselective Hydrogenation

A new twofold interpenetrated two-dimensional cadmium(II) coordination polymer constructed from 2,2′-(benzene-1,4-dicarboxamido)dipropionate

2018 ◽  
Vol 74 (11) ◽  
pp. 1434-1439
Author(s):  
Hong-Tao Zhang ◽  
Xiao-Long Wang
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Fluorescence Emission ◽  
Functional Materials ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Groups ◽  
Potential Applications

In recent years, much initial interest and enthusiasm has focused on the self-assembly of coordination polymers due to the aesthetics of their crystalline architectures and their potential applications as new functional materials. As part of an exploration of chiral coordination polymers, a new twofold interpenetrated two-dimensional (2D) coordination polymer, namely, poly[[tetraaquabis[μ3-(2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionato-κ5 O,O′:O′′,O′′′:O′′]dicadmium(II)] trihydrate], {[Cd2(C14H14N2O6)2(H2O)4]·3H2O} n , has been synthesized by the reaction of Cd(CH3COO)2·2H2O with the designed ligand (2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionic acid (H2 L). The compound has been structurally characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analysis. In the crystal structure, each CdII cation binds to three carboxylate groups from two crystallographically independent L 2− dianions. Four carboxylate groups link two crystallographically independent cadmium cations into a 4,4-connected secondary building unit (SBU). The resulting SBUs are extended into a two-dimensional folding sheet via the terephthalamide moiety of the ligand as a spacer, which can be simplified as a (4,4)-connected 4,4L15 net with the point symbol (3.53.62)(32.52.62). In the lattice, two independent folding sheets interpenetrate each other to yield a double-sheet layer. The resulting 2D layers pack in parallel arrays through intermolecular hydrogen bonds and interlayer π–π interactions. The thermal stability and photoluminescence properties of the title compound have been investigated and it exhibits an enhanced fluorescence emission and a longer lifetime compared with free H2 L.

Self-Assembly of Manganese(II)-Phytate Coordination Polymers: Synthesis, Crystal Structure, and Physicochemical Properties

ChemPlusChem ◽  
2017 ◽  
Vol 82 (5) ◽  
pp. 721-731 ◽  
Author(s):  
Delfina Quiñone ◽  
Nicolás Veiga ◽  
Julia Torres ◽  
Carla Bazzicalupi ◽  
Antonio Bianchi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physicochemical Properties ◽  
Coordination Polymers ◽  
Self Assembly

Synthetic Strategy for Incorporating Carboxylate Ligands into Coordination Polymers under a Solvent-Free Reaction

2021 ◽  
Author(s):  
Akira Hinokimoto ◽  
Hitoshi Izu ◽  
Yong-Sheng Wei ◽  
Toshinobu Nakajo ◽  
Ryotaro Matsuda ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Solvent Free ◽  
Carboxylate Ligands ◽  
Synthetic Strategy ◽  
Solvent Free Reaction
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