Synthesis and characterization of mercury(II) complexes with 2-styryl-1,3-benzothiazole (sb). Presence of two differently coordinated Hg(II) ions in the dinuclear complex Hg2Cl4(sb)3. Structural characterization of 2-styryl-1,3-benzothiazole and some of its derivatives

Polyhedron ◽  
2007 ◽  
Vol 26 (17) ◽  
pp. 5162-5170 ◽  
Author(s):  
Gordana Pavlović ◽  
Željka Soldin ◽  
Zora Popović ◽  
Vesna Tralić-Kulenović
Keyword(s):  
Structural Characterization ◽  
Dinuclear Complex ◽  
Synthesis And Characterization

Synthesis and characterization of bis(trifluoromethyl)gold .mu.-halide dimers: x-ray structural characterization of [Au(CF3)2(.mu.-I)]2

1990 ◽  
Vol 29 (17) ◽  
pp. 3252-3253 ◽  
Author(s):  
John L. Margrave ◽  
Kenton H. Whitmire ◽  
Robert H. Hauge ◽  
Nathan T. Norem
Keyword(s):  
Structural Characterization ◽  
Synthesis And Characterization ◽  
X Ray

Bismuth(iii)-thiophenedicarboxylates as host frameworks for lanthanide ions: synthesis, structural characterization, and photoluminescent behavior

2018 ◽  
Vol 47 (38) ◽  
pp. 13419-13433
Author(s):  
Alyssa K. Adcock ◽  
Bradley Gibbons ◽  
Jeffrey D. Einkauf ◽  
Jeffery A. Bertke ◽  
J. Faye Rubinson ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Structural Characterization ◽  
Lanthanide Ions ◽  
Synthesis And Characterization

The synthesis and characterization of three bismuth-organic compounds, two of which are lanthanide-doped, and two europium phases are reported.

Synthesis and Characterization of Ag Doped LaCoO3 Nanowire Sputter-Deposited Coatings as Heavy Hydrocarbon Sensors

2014 ◽  
Vol 605 ◽  
pp. 314-317 ◽  
Author(s):  
Amine Taguett ◽  
Mohammad Arab Pour Yazdi ◽  
Jean Baptiste Sanchez ◽  
Eric Monsifrot ◽  
Pascal Briois ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Magnetron Sputtering ◽  
Structural Characterization ◽  
Perovskite Structure ◽  
Short Description ◽  
Synthesis And Characterization ◽  
Reactive Magnetron ◽  
Post Heat Treatment ◽  
Sputter Deposited

In this paper, we investigate the feasibility of La1-xAgxCoO3-α nanowires by reactive magnetron sputtering. After a short description of the experimental and hydrocarbon sensing bench devices, a first part will be dedicated to the chemical, microstructural and structural characterization (SEM, XRD,...) of the coatings. As deposited coatings are amorphous and a post heat-treatment under air at 873 K is necessary to crystallise them in the perovskite structure. Finally, the performance as dodecane-sensors of these coatings with amorphous and crystalline structures will be discussed depending on dodecane concentrations and sensitive surfaces temperature and will be compared to those of La0.40Sr0.15Ag0.45CoO3-α nanowires.

Reaktion von DioxomoIybdän(VI)-Komplexen mit O-Methyl-thiocarbazat Darstellung und Charakterisierung von Schiffbase-, Hydrazido- und Diazenido-Komplexen des Molybdäns / Reaction of Dioxomolybdenum(VI) Complexes with O-Methylthiocarbazate Synthesis and Characterization of Schiffbase, Hydrazido and Diazenido Complexes of Molybdenum

1987 ◽  
Vol 42 (5) ◽  
pp. 599-604 ◽  
Author(s):  
Rainer Mattes ◽  
Heinz Scholand ◽  
Ulrich Mikloweit ◽  
Volker Schrenk
Keyword(s):  
Vibrational Spectroscopy ◽  
Mirror Symmetry ◽  
The Other ◽  
Dinuclear Complex ◽  
Synthesis And Characterization ◽  
Donor Ligand ◽  
Metal Atoms ◽  
Dimeric Complexes ◽  
Trigonal Prismatic

transThe reaction of NH2NHC(S)OR, (R = Me, Et) with MoO2(acac)2 yields the dimeric complexes MO2O3(MeC(O)CHC(Me)NNC(S)0R)2 (1) with the planar O = Mo - O - Mo = O group. The tetradentate O,N,S-donor ligand is formed through condensation of acetylacetone with the organohydrazine. The reactions of NH2NHC(S)OMe with MoO2(S2CNEt2)2 and MoO2(ONEt2)2 give the diazenido hydrazido complexes Mo(NNC(S)OMe)(NH2NC(S)OMe)(S2CNEt2)2·CH2Cl2(2) and Mo(NNC(S)OMe)(NH2NC(S)OMe)2(ONEt2) (4). The metal atoms in both compounds are seven coordinated and contain the approximately linear diazenido ligand NNC(S)OMe and one (2) or two (4) N,S-chelating hydrazido(1-) ligands NH2NC(S)OMe. 2 has crystallographically imposed mirror symmetry. Recrystallization of 2 from toluene in air gives the asymmetric dinuclear complex (Et2NCS2)(O)Mo(μ-NNC(S)OMe)2Mo(S2CNMe2) (3). The Mo-Mo distance is 267.0(2) pm. One Mo site has square pyramidal MoOS2N2 geometry, the other trigonal prismatic MoN2S4 geometry. The coordination of the bridging N atoms is slightly pyramidal. The compounds 1, 2 and 3 have been further characterized by vibrational spectroscopy.

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