A novel oxovanadate structural type – Synthesis, single crystal structure and magnetic properties of a mixed-valence polyoxovanadate formed by {V17O40(Cl)} and {V15O36(Cl)} clusters

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The relationship of magnetic properties and diamagnetic dilution has been studied for five-coordinate Co(ii) complex. It is found that the optimal dilution concentration to restrain dipole field can be given only by the single crystal structure.


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