Uranyl ion complexes with aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands

Polyhedron ◽  
2006 ◽  
Vol 25 (5) ◽  
pp. 1223-1232 ◽  
Author(s):  
Harri Sopo ◽  
Jukka Sviili ◽  
Arto Valkonen ◽  
Reijo Sillanpää
Keyword(s):  
Uranyl Ion ◽  
Donor Ligands

Uranyl ion complexes with long chain aminoalcoholbis(phenolate) [O,N,O,O′] donor ligands

Polyhedron ◽  
2007 ◽  
Vol 26 (1) ◽  
pp. 184-196 ◽  
Author(s):  
Harri Sopo ◽  
Ari Väisänen ◽  
Reijo Sillanpää
Keyword(s):  
Uranyl Ion ◽  
Donor Ligands ◽  
Long Chain

The Preparation of p(acrylonitrile-co-acrylamide) hydrogels for uranyl ion recovery from aqueous environments

2014 ◽  
Vol 1 (42) ◽  
pp. 89-89 ◽  
Author(s):  
Duygu Alpaslan ◽  
Nahit Aktas ◽  
Selehattin Yilmaz ◽  
Nurettin Sahiner
Keyword(s):  
Uranyl Ion ◽  
Aqueous Environments

Xenon Trioxide Adducts of O-Donor Ligands; [(CH3)2CO]3XeO3, [(CH3)2SO]3(XeO3)2, (C5H5NO)3(XeO3)2, and [(C6H5)3PO]2XeO3

2018 ◽  
Author(s):  
Katherine Marczenko ◽  
James Goettel ◽  
Gary Schrobilgen
Keyword(s):  
Room Temperature ◽  
Triphenylphosphine Oxide ◽  
Donor Ligands ◽  
Mechanical Shock ◽  
X Ray Diffraction ◽  
X Ray ◽  
Oxygen Coordination ◽  
Xenon Trioxide ◽  
Distorted Octahedra ◽  
Coordination Spheres

Oxygen coordination to the Xe(VI) atom of XeO<sub>3</sub> was observed in its adducts with triphenylphosphine oxide, dimethylsulfoxide, pyridine-N-oxide, and acetone. The crystalline adducts were characterized by low-temperature, single-crystal X-ray diffraction and Raman spectroscopy. Unlike solid XeO<sub>3</sub>, which detonates when mechanically or thermally shocked, the solid [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3</sub>, [(CH<sub>3</sub>)<sub>2</sub>SO]<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub>,<sub> </sub>and (C<sub>5</sub>H<sub>5</sub>NO)<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> adducts are insensitive to mechanical shock, but undergo rapid deflagration when ignited by a flame. Both [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3 </sub>and (C<sub>5</sub>H<sub>5</sub>NO)<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> are air-stable whereas [(CH<sub>3</sub>)<sub>2</sub>SO]<sub>3</sub>(XeO<sub>3</sub>)<sub>2</sub> slowly decomposes over several days and [(CH<sub>3</sub>)<sub>2</sub>CO]<sub>3</sub>XeO<sub>3</sub> undergoes adduct dissociation at room temperature. The xenon coordination sphere of [(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>PO]<sub>2</sub>XeO<sub>3</sub> is a distorted square pyramid which provides the first example of a five-coordinate XeO<sub>3</sub> adduct. The xenon coordination spheres of the remaining adducts are distorted octahedra comprised of three Xe---O secondary contacts that are approximately trans to the primary Xe–O bonds of XeO<sub>3</sub>. Quantum-chemical calculations were used to assess the Xe---O adduct bonds, which are predominantly electrostatic σ-hole bonds between the nucleophilic oxygen atoms of the bases and the σ-holes of the xenon atoms.

Preconcentration of Uranium(VI) on Modified and Unmodified Amberlite XAD 4 Sorbent

1993 ◽  
Vol 58 (8) ◽  
pp. 1813-1820 ◽  
Author(s):  
Jan Vácha ◽  
Lumír Sommer
Keyword(s):  
Spectrophotometric Determination ◽  
Uranyl Ion ◽  
Sodium Diethyldithiocarbamate ◽  
Uranyl Ions ◽  
Methanolic Solution

The sorption of uranyl ions on columns with the macrophorus hydrophobic sorbent Amberlite XAD 4 modified with 1-(2-pyridylazo)-2-naphthol and sodium diethyldithiocarbamate was examined. Following elution of the uranyl ion with HNO3 (2 - 4 mol l-1) or of the diethyldithiocarbamate UO22+-chelate with a methanolic solution of HCl (0.1 mol l-1), uranium was determined spectrophotometrically with 4-(2-pyridylazo)resorcinol or with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol. The preconcentration of uranium on Amberlite XAD 4 type sorbents is convenient for its spectrophotometric determination in waters.

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