scholarly journals Electronic properties of mesoscopic graphene structures: Charge confinement and control of spin and charge transport

2011 ◽  
Vol 503 (2-3) ◽  
pp. 77-114 ◽  
Author(s):  
A.V. Rozhkov ◽  
G. Giavaras ◽  
Yury P. Bliokh ◽  
Valentin Freilikher ◽  
Franco Nori
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jinshi Li ◽  
Pingchuan Shen ◽  
Shijie Zhen ◽  
Chun Tang ◽  
Yiling Ye ◽  
...  

AbstractMolecular potentiometers that can indicate displacement-conductance relationship, and predict and control molecular conductance are of significant importance but rarely developed. Herein, single-molecule potentiometers are designed based on ortho-pentaphenylene. The ortho-pentaphenylene derivatives with anchoring groups adopt multiple folded conformers and undergo conformational interconversion in solutions. Solvent-sensitive multiple conductance originating from different conformers is recorded by scanning tunneling microscopy break junction technique. These pseudo-elastic folded molecules can be stretched and compressed by mechanical force along with a variable conductance by up to two orders of magnitude, providing an impressively higher switching factor (114) than the reported values (ca. 1~25). The multichannel conductance governed by through-space and through-bond conducting pathways is rationalized as the charge transport mechanism for the folded ortho-pentaphenylene derivatives. These findings shed light on exploring robust single-molecule potentiometers based on helical structures, and are conducive to fundamental understanding of charge transport in higher-order helical molecules.


2018 ◽  
Vol 5 (11) ◽  
pp. 1748-1755 ◽  
Author(s):  
Angela Benito-Hernández ◽  
Mardia T. El-Sayed ◽  
Juan T. López Navarrete ◽  
M. Carmen Ruiz Delgado ◽  
Berta Gómez-Lor

A promising candidate for ambipolar charge transport: a disk-like platform, diazatruxenone, as a novel, compact and planar donor–acceptor molecule.


2022 ◽  
Author(s):  
Hui Jiang ◽  
Jun Ye ◽  
Peng Hu ◽  
Shengli Zhu ◽  
Yanqin Liang ◽  
...  

Co-crystallization is an efficient way of molecular crystal engineering to tune the electronic properties of organic semiconductors. In this work, we synthesized anthracene-4,8-bis(dicyanomethylene)4,8-dihydrobenzo[1,2-b:4,5-b’]-dithiophene (DTTCNQ) single crystals as a template to...


Polymers ◽  
2017 ◽  
Vol 9 (12) ◽  
pp. 86 ◽  
Author(s):  
Kan Sato ◽  
Ryusuke Mizukami ◽  
Takahiro Mizuma ◽  
Hiroyuki Nishide ◽  
Kenichi Oyaizu

2020 ◽  
Vol 8 (1) ◽  
pp. 401-411 ◽  
Author(s):  
Tong Xiao ◽  
Jiayu Wang ◽  
Shuting Yang ◽  
Yuanwei Zhu ◽  
Dongfan Li ◽  
...  

We realized simultaneously optimized optical and electronic properties in semitransparent organic solar cells by tuning the film-depth-dependent crystallinity distribution.


1990 ◽  
Vol 31 ◽  
pp. 53-58 ◽  
Author(s):  
J.M. Woodall ◽  
P.D. Kirchner ◽  
J.L. Freeouf ◽  
A.C. Warren

Author(s):  
Victor Dmitriev ◽  
Wagner Castro ◽  
Samara Matos ◽  
Francisco Nobre ◽  
Tiago Oliveira ◽  
...  

2012 ◽  
Vol 629 ◽  
pp. 224-228 ◽  
Author(s):  
Kwang Sik Kim ◽  
Young Wook Hwang ◽  
Tae Young Won

We report our finite element method (FEM) simulation study on the characteristic of the charge transport layer of the multi-layer structure for organic light emitting diodes (OLEDs). The physical model cover all the key physical processes in OLEDs, namely charge injection, transport and recombination, exciton diffusion, transfer and decay for electronic properties. We performed a numerical simulation on a multilayer structure comprising a hole transport layer (HTL), an emission layer (EML), and an electron transport layer (ETL) between both electrodes; anode and cathode. The materials of the HTL is TPD (N, N'-Bis (3- methylphenyl) - N, N'- bis (phenyl) benzidine), and the ETL includes Alq3 (Tris (8- hyroxyquinolinato) aluminium). Here, we investigated the parameters such as recombination rates which influence the efficiency of the charge transport between layers in bilayer OLEDs. We also analyzed a transient response during the turn on period and the carrier transport in accordance with the variation of the injection barrier and applied voltage. In addition, this paper revealed that the effect of the insertion of the EML in bilayer structure.


Sign in / Sign up

Export Citation Format

Share Document