Fullerene-C 60 and crown ether doped on C 60 sensors for high sensitive detection of alkali and alkaline earth cations

2017 ◽  
Vol 87 ◽  
pp. 51-58 ◽  
Author(s):  
Fatemeh Alipour Zaghmarzi ◽  
Mansour Zahedi ◽  
Adeleh Mola ◽  
Saboora Abedini ◽  
Sattar Arshadi ◽  
...  
Keyword(s):  
Crown Ether ◽  
Alkaline Earth ◽  
Sensitive Detection ◽  
Alkaline Earth Cations

Transport of alkali and alkaline earth cations by a crown ether-alkylphosphoric acid system

1993 ◽  
Vol 2 (4) ◽  
pp. 295-299 ◽  
Author(s):  
Toshio Takahashi ◽  
Yoichi Habata ◽  
Tetsuyuki Okumachi
Keyword(s):  
Crown Ether ◽  
Alkaline Earth ◽  
Acid System ◽  
Alkylphosphoric Acid ◽  
Alkaline Earth Cations

Micelle formation as a factor influencing the mode(s) of metal ion partitioning into N-alkylpyridinium-based ionic liquids (ILs): implications for the design of IL-based extraction systems

2017 ◽  
Vol 19 (23) ◽  
pp. 5674-5682 ◽  
Author(s):  
James L. Wankowski ◽  
Michael J. Kaul ◽  
Mark L. Dietz
Keyword(s):  
Ionic Liquids ◽  
Crown Ether ◽  
Metal Ion ◽  
Alkaline Earth ◽  
Micelle Formation ◽  
Ion Pair ◽  
Neutral Complex ◽  
Ion Partitioning ◽  
Alkaline Earth Cations ◽  
Complex Ion

In the extraction of alkali and alkaline earth cations by a crown ether into certain N-alkylpyridinium-based ILs, the balance between neutral complex/ion-pair partitioning and ion exchange is significantly altered by the formation of micelles in the aqueous phase involving the IL cation.

Driving force for the hydration of the swelling clays: Case of montmorillonites saturated with alkaline-earth cations

2013 ◽  
Vol 395 ◽  
pp. 269-276 ◽  
Author(s):  
Fabrice Salles ◽  
Jean-Marc Douillard ◽  
Olivier Bildstein ◽  
Cedric Gaudin ◽  
Benedicte Prelot ◽  
...  
Keyword(s):  
Driving Force ◽  
Alkaline Earth ◽  
Swelling Clays ◽  
Alkaline Earth Cations

Topotactic route to synthesis of novel hydroxylated phases: I. Trioctahedral Micas

Clay Minerals ◽  
1986 ◽  
Vol 21 (2) ◽  
pp. 125-131 ◽  
Author(s):  
S. Komarneni ◽  
R. Roy
Keyword(s):  
Ion Exchange ◽  
Alkaline Earth ◽  
Water Molecules ◽  
Hydration Energy ◽  
Hydrothermal Conditions ◽  
Potential Applications ◽  
Clay Layers ◽  
First Time ◽  
Hydrolysis Of ◽  
Alkaline Earth Cations

AbstractK-depleted phlogopite mica was used as a topotactic precursor and treated with alkali (Li+, K+, , Rb+, Cs+), alkaline-earth (Mg2+, Ca2+, Sr2+, Ba2+) and trivalent (Al3+) cations under hydrothermal conditions of 200°C and 30 MPa pressure. K-, NH4-, Rb- and Cs-aluminosilicate micas were synthesised at 200°C in one day. The synthesis of Cs-aluminosilicate mica, with potential applications in the management of nuclear wastes, has been achieved for the first time by this approach. Ion exchange by Li+, Na+ and alkaline-earth cations under hydrothermal conditions did not produce anhydrous mica phases but resulted in hydrous phases with one or two layers of water molecules between the clay layers. The formation of hydrous phases may be attributed to the high hydration energy of the above cations compared to K+, , RB+ and Cs+. Ion exchange with Al3+ produced a chlorite-like phase because of the hydrolysis of Al3+ under these hydrothermal conditions. These studies are of relevance in the immobilization of wastes where hazardous ions can be fixed in highly stable insoluble phases like mica or chlorite.

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