Drude weight in quasi-two-dimensional organic conductors close to the Mott transition: Optical studies of the bandwidth, filling and temperature dependence

2007 ◽  
Vol 460-462 ◽  
pp. 125-128 ◽  
Author(s):  
Natalia Drichko ◽  
Michael Dumm ◽  
Daniel Faltermeier ◽  
Martin Dressel ◽  
Jaime Merino ◽  
...  
2010 ◽  
Vol 200 (1) ◽  
pp. 012029
Author(s):  
M Dressel ◽  
M Dumm ◽  
N Drichko ◽  
C Méziere ◽  
P Batail

Author(s):  
Shiwei Wang ◽  
Anton Chavez ◽  
Simil Thomas ◽  
Hong Li ◽  
Nathan C. Flanders ◽  
...  

This work reports on the assembly of imine-linked macrocycles that serve as models of two-dimensional covalent organic frameworks (2D COFs). Interlayer interactions play an important role in the formation of 2D COFs, yet the effect of monomer structure on COF formation, crystallinity, and susceptibility to exfoliation are not well understood. For example, monomers with both electron-rich and electron-poor π-electron systems have been proposed to strengthen interlayer inter-actions and improve crystallinity. Here we probe these effects by studying the stacking behavior of imine-linked macrocycles that represent discrete models of 2D COFs. <div><br></div><div>Specifically, macrocycles based on terephthaldehyde (PDA) or 2,5-dimethoxyterephthaldehyde (DMPDA) stack upon cooling molecularly dissolved solutions. Both macrocycles assemble cooperatively with similar ΔHe values of -97 kJ/mol and -101 kJ/mol, respectively, although the DMPDA macrocycle assembly process showed a more straightforward temperature dependence. Circular dichroism spectroscopy performed on macrocycles bearing chiral side chains revealed a helix reversion process for the PDA macrocycles that was not observed for the DMPDA macrocycles. <br></div><div><br></div><div>Given the structural similarity of these monomers, these findings demonstrate that the stacking processes associated with nanotubes derived from these macrocycles, as well as for the corresponding COFs, are complex and susceptible to kinetic traps, casting doubt on the relevance of thermodynamic arguments for improving materials quality. <br></div>


1973 ◽  
Vol 43 (1) ◽  
pp. 39-41 ◽  
Author(s):  
Le Dang Khoi ◽  
P. Veillet ◽  
J-P. Renard ◽  
C. Jacoboni

2009 ◽  
Vol 79 (19) ◽  
Author(s):  
Michael Dumm ◽  
Daniel Faltermeier ◽  
Natalia Drichko ◽  
Martin Dressel ◽  
Cécile Mézière ◽  
...  

2010 ◽  
Vol 248 (2) ◽  
pp. 486-490
Author(s):  
Kenji Yonemitsu ◽  
Yasuhiro Tanaka ◽  
Satoshi Miyashita ◽  
Nobuya Maeshima

2014 ◽  
Vol 89 (12) ◽  
Author(s):  
G. M. Gusev ◽  
Z. D. Kvon ◽  
E. B. Olshanetsky ◽  
A. D. Levin ◽  
Y. Krupko ◽  
...  

1995 ◽  
Vol 52 (2) ◽  
pp. 1550-1557 ◽  
Author(s):  
Jong-Rim Lee ◽  
Sung Jong Lee ◽  
Bongsoo Kim

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